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Bamforth, S.M. |
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Title |
Manganese removal from mine waters – investigating the occurrence and importance of manganese carbonates |
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Journal Article |
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Year |
2006 |
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Appl. Geochem. |
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21 |
Issue |
8 |
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1274-1287 |
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mine water treatment |
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Abstract |
Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month period in continuous-flow reactors. For all substrates except quartzite, Mn was removed from the mine water during this period, and Mn minerals precipitated in all cases. In addition, the plastic from which the reactor was made played a role in Mn removal. Manganese oxyhydroxides were formed in all the reactors; however, Mn carbonates (specifically kutnahorite) were only identified in the reactors containing quartzite and on the reactor plastic. Magnesium-rich calcites were identified in the dolomite and magnesite reactors, suggesting that the Mg from the substrate minerals may have inhibited Mn carbonate formation. Biofilm community development and composition on all the substrates was also monitored over the 3-month period using denaturing gradient gel electrophoresis (DGGE). The DGGE profiles in all reactors showed no change with time and no difference between substrate types, suggesting that any microbiological effects are independent of mineral substrate. The identification of Mn carbonates in these systems has important implications for the design of Mn treatment systems in that the provision of a carbonate-rich substrate may not be necessary for successful Mn precipitation. (c) 2006 Elsevier Ltd. All rights reserved. |
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Manganese removal from mine waters – investigating the occurrence and importance of manganese carbonates; Wos:000240297600004; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16916 |
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107 |
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Sibrell, P.L. |
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Limestone fluidized bed treatment of acid-impacted water at the Craig Brook National Fish Hatchery, Maine, USA |
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Journal Article |
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Year |
2006 |
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Aquacultural Engineering |
Abbreviated Journal |
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34 |
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2 |
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61-71 |
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mine water treatment |
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Decades of atmospheric acid deposition have resulted in widespread lake and river acidification in the northeastern U.S. Biological effects of acidification include increased mortality of sensitive aquatic species Such as the endangered Atlantic salmon (Salmo salar). The purpose of this paper is to describe the development of a limestone-based fluidized bed system for the treatment of acid-impacted waters. The treatment system was tested at the Craig Brook National Fish Hatchery in East Orland, Maine over a period of 3 years. The product water from the treatment system was diluted with hatchery water to prepare water supplies with three different levels of alkalinity for testing of fish health and Survival. Based on positive results from a prototype system used in the first year of the study, a larger demonstration system was used in the second and third years with the objective of decreasing operating costs. Carbon dioxide was used to accelerate limestone dissolution, and was the major factor in system performance, as evidenced by the model result: Alk = 72.84 X P(CO2)(1/2); R-2 = 0.975. No significant acidic incursions were noted for the control water over the course of the Study. Had these incursions occurred, survivability in the untreated water would likely have been much more severely impacted. Treated water consistently provided elevated alkalinity and pH above that of the hatchery source water. (C) 2005 Elsevier B.V. All rights reserved. |
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Limestone fluidized bed treatment of acid-impacted water at the Craig Brook National Fish Hatchery, Maine, USA; Wos:000235568800001; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16942 |
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113 |
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Canty, G.A.; Everett, J.W. |
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Injection of Fluidized Bed Combustion Ash into Mine Workings for Treatment of Acid Mine Drainage |
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Journal Article |
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2006 |
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Mine Water Env. |
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25 |
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1 |
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45-55 |
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acid mine drainage AMD alkaline injection technology fluidized bed combustion ash Oklahoma |
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A demonstration project was conducted to investigate treating acid mine water by alkaline injection technology (AIT). A total of 379 t of alkaline coal combustion byproduct was injected into in an eastern Oklahoma drift coal mine. AIT increased the pH and alkalinity, and reduced acidity and metal loading. Although large improvements in water quality were only observed for 15 months before the effluent water chemistry appeared to approach pre-injection conditions, a review of the data four years after injection identified statistically significant changes in the mine discharge compared to pre-injection conditions. Decreases in acidity (23%), iron (18%), and aluminium (47%) were observed, while an increase in pH (0.35 units) was noted. Presumably, the mine environment reached quasi-equilibrium with the alkalinity introduced to the system. |
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1025-9112 |
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Injection of Fluidized Bed Combustion Ash into Mine Workings for Treatment of Acid Mine Drainage; 1; FG 6 Abb., 1 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17319 |
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422 |
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Author |
Sasaki, K. |
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Title |
Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs |
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Journal Article |
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2006 |
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Mater. Trans. |
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47 |
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10 |
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2457-2461 |
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mine water treatment |
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A Mn-oxidizing fungus was isolated from a constructed wetland of Hokkaido (Japan), which is receiving the Mn-impacted drainage, and genetically and morphologically identified as Paraconiothyrium sp.-like strain. The optimum pHs were 6.45-6.64, where is more acidic than those of previously reported Mn-oxidizing fungi. Too much nutrient inhibited fungal Mn-oxidation, and too little nutrient also delayed Mn oxidation even at optimum pH. In order to achieve the oxidation of high concentrations of Mn like mine drainage containing several hundreds g-m(-3) of Mn, it is important to find the best mix ratio among the initial Mn concentrations, inocolumn size and nutrient concentration. The strain has still Mn-tolerance with more than 380 g-m(-3) of Mn, but high Mn(II) oxidation was limited by pH control and supplied nutrient amounts. The biogenic Mn deposit was poorly crystallized birnessite. The strain is an unique Mn-oxidizing fungus having a high Mn tolerance and weakly acidic tolerance, since there has been no record about the property of the strain. There is a potentiality to apply the strain to the environmental bioremediation. |
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Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs; Wos:000242429300002; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16940 |
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103 |
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Sheoran, A.S.; Sheoran, V. |
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Title |
Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review |
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Journal Article |
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2006 |
Publication |
Minerals Engineering |
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19 |
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2 |
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105-116 |
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Acid mine drainage Metal removal mechanism Wetlands |
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Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. Water infiltrating through the metal sulphide minerals, effluents of mineral processing plants and seepage from tailing dams becomes acidic and this acidic nature of the solution allows the metals to be transported in their most soluble form. The conventional treatment technologies used in the treatment of acid mine drainage are expensive both in terms of operating and capital costs. One of the methods of achieving compliance using passive treatment systems at low cost, producing treated water pollution free, and fostering a community responsibility for acid mine water treatment involves the use of wetland treatment system. These wetlands absorb and bind heavy metals and make them slowly concentrated in the sedimentary deposits to become part of the geological cycle. In this paper a critical review of the heavy metal removal mechanism involving various physical, chemical and biological processes, which govern wetland performance, have been made. This information is important for the siting and use of wetlands for remediation of heavy metals. |
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Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review; Science Direct |
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CBU @ c.wolke @ 17252 |
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41 |
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