Abstract: Environmental desulphurization is an attractive alternative for acid generating tailings management as demonstrated during the last few years. In fact, such process placed at the end of the primary treatment circuit allows to reduce greatly the amount of problematic tailings by concentrating the sulphidic fraction. Moreover, the desulphurized tailings (non-acid generating) have the geotechnical and environmental properties for being used as fine material in a cover with capillary barrier effects. To produce desulphurized tailings, non selective froth flotation is the most adapted method as shown in many previous works. Desulphurization level is fixed by tailings sulphur content (or sulphide content) and neutralization potential NP. The final residue should have enough NP to compensate for his acid generating potential AP. In this paper, the authors present the results of laboratory tests conducted in Denver cells for studying the sulphide flotation kinetics of four mine tailings which are characterized by a weak neutralization potential (under 37 kg CaCO (sub 3) /t). Tailings 1, 2, 3 and 4 contain respectively 5.27, 10, 4.25 and 16.9 sulphur Wt. %. Tailings 1 and 2 are cyanide free and are well floated at pH around 11 by using amyl xanthate as collector. Collector dosage was optimized for these tailings and the results show that Tailing 2 need more collector. However, Tailings 3 and 4, which come from a gold cyanidation process, could not provide good sulphide recovery with xanthate collector because of the pyrite depression. To overcome this problem, amine acetate was used successfully but induces important entrainment. The consumption of this collector was also optimized. The results of kinetic tests and collector dosage were combined and modeled to establish relationships which allow to estimate the desulphurization performances.

Abstract: Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell.

Abstract: An historic underground copper mine in Wyoming is discharging neutral but copper-laden water into a pristine creek. The EPA-deferred site qualifies for reclamation by the Wyoming Abandoned Mine Land (AML) program. The cleanup goal is to restore the discharge so that the creek can eventually support a trout fishery. Hydrological and geochemical investigations underground have suggested two sources of mine water: one clean and the other containing copper. Results of bench- and pilot-scale tests support the viability of using low-cost passive treatment techniques to reduce copper concentrations in the near-freezing mine discharge.