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Davies, G.J.; Holmes, M.; Wireman, M.; King, K.; Gertson, J.N.; Stefanic, J.M. |
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Title |
Water tracing at scales of hours to decades as an aid to estimating hydraulic characteristics of the Leadville Mine drainage tunnel |
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Journal Article |
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Year |
2001 |
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acid mine drainage Arkansas River Colorado drainage dye tracers field studies fluorescence ground water Lake County Colorado Leadville Mine Leadville mining district pH quantitative analysis recharge surveys tunnels United States water treatment 30 Engineering geology 21 Hydrogeology |
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Abstract |
The Leadville Mine Drainage Tunnel (LMDT) is a 3.3 kilometer structure that was constructed in the complicated geology of the Leadville mine district in the 1940's. Discharge from the LMDT is impacted by heavy metals and is treated at a plant built in 1992 operated by the United States Bureau of Reclamation. On the surface waste rock and other remnants of the mining operations litter the landscape and this material is exposed to precipitation. As a result of contact with this material, surface water often has pH of less than 3 and its containment and disposal is necessary before it impacts surface drainage and the nearby Arkansas River. Using a borehole drilled into the mine workings the U.S. EPA has devised a plan in which the impacted water is contained on the surface which then can be discharged into the mine workings to discharge from the LMDT and be treated. The percentage of water discharging from the mining district along the drainage tunnel is unknown, and since there is no access, information about the condition of the tunnel with regards to blockages is also relatively obscure. Application of quantitative water tracing using fluorescent dyes was used to model the flow parameters at the scale of hours in the tunnel and evaluate the likelihood of blockages. Because the tunnel has intersected several lithologies and faults, other locations such as discharging shafts, adits and surface streams that could be hydraulically connected to the LMDT were also monitored. An initial tracer experiment was done using an instantaneous injection, which was followed by additional injections of water. Another tracer injection was done when there was a continuous flow of impacted water into the workings. Analysis of the tracer concentration responses at water-filled shafts and at the portal were used to model the flow along the tunnel and estimate several hydraulic parameters. Waters in these settings are mixtures of components with different residence times, so, qualitative tritium data were used to evaluate residence times of decades. The combined injected tracer and tritium data as well as other geochemical data were used to infer the nature of flow and recharge into the tunnel. |
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Abstracts with Programs - Geological Society of America |
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Geological Society of America, 2001 annual meeting |
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2004-013418; Geological Society of America, 2001 annual meeting, Boston, MA, United States, Nov. 1-10, 2001; GeoRef; English |
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CBU @ c.wolke @ 16511 |
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408 |
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Author |
Kuyucak, N. |
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Title |
Acid mine drainage; treatment options for mining effluents |
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Journal Article |
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Year |
2001 |
Publication |
Mining Environmental Management |
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9 |
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2 |
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12-15 |
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acid mine drainage; alkalinity; cadmium; chemical reactions; copper; cyanides; decontamination; degradation; effluents; flotation; heavy metals; lead; lime; metals; mines; nickel; oxidation; pH; physicochemical properties; pollution; reagents; reduction; remediation; seepage; sludge; solid waste; solvents; stability; tailings; toxic materials; toxicity; waste disposal; water quality; zinc |
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0969-4218 |
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Acid mine drainage; treatment options for mining effluents; 2001-050827; References: 23; illus. United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 5723 |
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324 |
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Conca, J.L.; Wright, J. |
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An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
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Journal Article |
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2006 |
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Appl. Geochem. |
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21 |
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12 |
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2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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Author |
Erten-Unal, M.; Wixson, B.G. |
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Title |
Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA |
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Journal Article |
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1999 |
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Water Air Soil Pollut. |
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116 |
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3-4 |
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501-522 |
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biotreatment lead and zinc mine wastewater MINTEQ speciation biotreatment lead and zinc mine wastewater minteq speciation trout salmo-gairdneri water |
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Continued mining development in the world's largest lead producing area has generated and increased concern over effective mine water treatment in Missouri's New Lead Belt. A new type of mine/mill wastewater treatment system was constructed which consisted of a tailings pond followed by a series of artificially constructed meandering biotreatment channels and a polishing lagoon. This system provided additional retention time and distance for the removal of heavy metals by abundant aquatic plants and sedimentation. Seasonal field sampling and analytical testing that evaluated the present system confirmed that it provided good treatment for removal of heavy metals within the company property and produced a final effluent within the state and federal regulatory guidelines. On average, greater than 95% of zinc and manganese in the drainage water were removed by the biotreatment system, while lead and copper were 50 to 60%. A chemical equilibrium model, MINTEQ, was also used to identify various species of lead and zinc in the biotreatment system. The model predicted that the major species of carbonates and hydroxides would be the predominant complexes of lead and zinc for the pH and alkalinity values reported in the biotreatment system. These results were also supported by the literature. |
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0049-6979 |
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Dec.; Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA; Isi:000083273200004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10115.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17472 |
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16 |
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Niyogi, D.K.; McKnight, D.M.; Lewis, W.M., Jr.; Kimball, B.A. |
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Title |
Experimental diversion of acid mine drainage and the effects on a headwater stream |
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1999 |
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Water-Resources Investigations Report |
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Wri 99-4018-A |
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123-130 |
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abandoned mines acid mine drainage algae benthonic taxa biomass biota Colorado experimental studies heavy metals Lake County Colorado Leadville Colorado metals mines pH Plantae pollution remediation Saint Kevin Gulch Colorado tracers United States USGS water zinc |
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An experimental diversion of acid mine drainage was set up near an abandoned mine in Saint Kevin Gulch, Colorado. A mass-balance approach using natural tracers was used to estimate flows into Saint Kevin Gulch. The diversion system collected about 85 percent of the mine water during its first year of operation (1994). In the first 2 months after the diversion, benthic algae in an experimental reach (stream reach around which mine drainage was diverted) became more abundant as water quality improved (increase in pH, decrease in zinc concentrations) and substrate quality changed (decrease in rate of metal hydroxide deposition). Further increases in pH to levels above 4.6, however, led to lower algal biomass in subsequent years (1995-97). An increase in deposition of aluminum precipitates at pH greater than 4.6 may account for the suppression of algal biomass. The pH in the experimental reach was lower in 1998 and algal biomass increased. Mine drainage presents a complex, interactive set of stresses on stream ecosystems. These interactions need to be considered in remediation goals and plans. |
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0092-332x |
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Experimental diversion of acid mine drainage and the effects on a headwater stream; 2; GeoRef: 2001-017199 als Datei vorhanden 4 Abb.; VORHANDEN | AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17398 |
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286 |
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