| Records |
| Author |
Kepler, D.A.; Mc Cleary, E.C. |
| Title |
Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage |
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Journal Article |
| Year |
1994 |
Publication |
Proceedings, International Land Reclamation and Mine Drainage Conference |
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| Volume |
1 |
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195-204 |
| Keywords |
acid mine drainage; alkalinity; anaerobic environment; calcium carbonate; chemical reactions; experimental studies; pH; pollutants; pollution; remediation; water quality SAPS mine water RAPS |
| Abstract |
Constructed wetland treatment system effectiveness has been limited by the alkalinity-producing, or acidity-neutralizing, capabilities of systems. Anoxic limestone drains (ALD's) have allowed for the treatment of approximately 300 mg/L net acidic mine drainage, but current design guidance precludes using successive ALD's to generate alkalinity in excess of 300 mg/L because of concerns with dissolved oxygen. “Compost” wetlands designed to promote bacterially mediated sulfate reduction are suggested as a means of generating alkalinity required in excess of that produced by ALD's. Compost wetlands create two basic needs of sulfate reducing bacteria; anoxic conditions resulting from the inherent oxygen demand of the organic substrate, and quasi-circumneutral pH values resulting from the dissolution of the carbonate fraction of the compost. However, sulfate reduction treatment area needs are generally in excess of area availability and/or cost effectiveness. Second generation alkalinity-producing systems demonstrate that a combination of existing treatment mechanisms has the potential to overcome current design concerns and effectively treat acidic waters ad infinitum. Successive alkalinity-producing systems (SAPS) combine ALD technology with sulfate reduction mechanisms. SAPS promote vertical flow through rich organic wetland substrates into limestone beds beneath the organic compost, discharging the pore waters. SAPS allow for conservative wetland treatment sizing calculations to be made as a rate function based on pH and alkalinity values and associated contaminant loadings. SAPS potentially decrease treatment area requirements and have the further potential to generate alkalinity in excess of acidity regardless od acidity concentrations. |
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Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage; Cn, Kj, Aj; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9722.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9722 |
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55 |
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Kuyucak, N. |
| Title |
Acid mine drainage prevention and control options |
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Journal Article |
| Year |
2002 |
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CIM Bull. |
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95 |
Issue |
1060 |
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96-102 |
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acid mine drainage prevention tailings environment waste sulphides Groundwater problems and environmental effects Pollution and waste management non radioactive Surface water quality Waste Management and Pollution Policy tailings sulfide mining industry waste management |
| Abstract |
Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. It occurs as a result of natural oxidation of sulphide minerals contained in mining wastes at operating and closed/decommissioned mine sites. AMD may adversely impact the surface water and groundwater quality and land use due to its typical low pH, high acidity and elevated concentrations of metals and sulphate content. Once it develops at a mine, its control can be difficult and expensive. If generation of AMD cannot be prevented, it must be collected and treated. Treatment of AMD usually costs more than control of AMD and may be required for many years after mining activities have ceased. Therefore, application of appropriate control methods to the site at the early stage of the mining would be beneficial. Although prevention of AMD is the most desirable option, a cost-effective prevention method is not yet available. The most effective method of control is to minimize penetration of air and water through the waste pile using a cover, either wet (water) or dry (soil), which is placed over the waste pile. Despite their high cost, these covers cannot always completely stop the oxidation process and generation of AMD. Application of more than one option might be required. Early diagnosis of the problem, identification of appropriate prevention/control measures and implementation of these methods to the site would reduce the potential risk of AMD generation. AMD prevention/control measures broadly include use of covers, control of the source, migration of AMD, and treatment. This paper provides an overview of AMD prevention and control options applicable for developing, operating and decommissioned mines. |
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Dr. N. Kuyucak, Golder Associates Ltd., Ottawa, Ont., Canada |
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0317-0926 |
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Acid mine drainage prevention and control options; 2419232; Canada 38; Geobase |
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CBU @ c.wolke @ 17532 |
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64 |
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Benner, S.G.; Blowes, D.W.; Ptacek, C.J. |
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A full-scale porous reactive wall for prevention of acid mine drainage |
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Journal Article |
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1997 |
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Ground Water Monitoring and Remediation |
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17 |
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4 |
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99-107 |
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acid mine drainage alkalinity bacteria Canada case studies concentration dissolved materials drainage Eastern Canada ground water mines observation wells Ontario permeability pH pollution porous materials recharge reduction remediation site exploration Sudbury District Ontario sulfate ion surface water waste disposal water pollution Groundwater quality Groundwater problems and environmental effects Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 11) geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) groundwater protection permeable barrier acid mine drainage aquifer groundwater acid min drainage contamination permeable barrier groundwater protection permeable barrier acid mine drainage aquifer Canada, Ontario, Sudbury, Nickel Rim |
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The generation and release of acidic drainage containing high concentrations of dissolved metals from decommissioned mine wastes is an environmental problem of international scale. A potential solution to many acid drainage problem is the installation of permeable reactive walls into aquifers affected by drainage water derived from mine waste materials. A permeable reactive wall installed into an aquifer impacted by low-quality mine drainage waters was installed in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The reactive mixture, containing organic matter, was designed to promote bacterially mediated sulfate reduction and subsequent metal sulfide precipitation. The reactive wall is installed to an average depth of 12 feet (3.6 m) and is 49 feet (15 m) long perpendicular to ground water flow. The wall thickness (flow path length) is 13 feet (4 m). Initial results, collected nine months after installation, indicate that sulfate reduction and metal sulfide precipitation is occurring. Comparing water entering the wall to treated water existing the wall, sulfate concentrations decrease from 2400 to 4600 mg/L to 200 to 3600 mg/L; Fe concentration decrease from 250 to 1300 mg/L to 1.0 to 40 mg/L, pH increases from 5.8 to 7.0; and alkalinity (as CaCO<inf>3</inf>) increases from 0 to 50 mg/L to 600 to 2000 mg/L. The reactive wall has effectively removed the capacity of the ground water to generate acidity on discharge to the surface. Calculations based on comparison to previously run laboratory column experiments indicate that the reactive wall has potential to remain effective for at least 15 years. |
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Dr. S.G. Benner, Earth Sciences Department, University of Waterloo, Waterloo, Ont. N2L 3G1, Canada |
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1069-3629 |
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Review; A full-scale porous reactive wall for prevention of acid mine drainage; 0337197; United-States 46; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10621.pdf; Geobase |
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CBU @ c.wolke @ 17555 |
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67 |
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Karathanasis, A.D.; Barton, C.D. |
| Title |
The revival of a failed constructed wetland treating a high Fe load AMD |
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Book Chapter |
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1999 |
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Proceedings; biogeochemistry of trace elements in coal and coal combustion byproducts |
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abandoned mines acid mine drainage anaerobic environment carbonate rocks characterization composting constructed wetlands design environmental analysis ferrihydrite geologic hazards hydrology hydroxides iron iron hydroxides Kentucky limestone metals minerals mines organic compounds oxides pollution remediation runoff sedimentary rocks sediments solubility sulfate ion United States water quality water treatment wetlands 22, Environmental geology |
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Kluwer Academic/Plenum Publishers |
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New York |
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Sajwan, K.S.; Alva, A.K.; Keefer, R.F. |
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0306462885 |
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The revival of a failed constructed wetland treating a high Fe load AMD; GeoRef; English; 2002-039561; Fourth international conference on the Biogeochemistry of trace elements, Berkeley, CA, United States, June 23, 1997 References: 45; illus. incl. 2 tables, sketch maps |
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CBU @ c.wolke @ 16571 |
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82 |
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Blowes, D.W.; Ptacek, C.J.; Benner, S.G.; McRae, C.W.T.; Puls, R.W. |
| Title |
Treatment of dissolved metals using permeable reactive barriers |
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Journal Article |
| Year |
1998 |
Publication |
Groundwater Quality: Remediation and Protection |
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250 |
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483-490 |
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adsorption; aquifers; attenuation; dissolved materials; metals; nutrients; oxidation; pollutants; pollution; precipitation; reduction; water treatment Groundwater quality Pollution and waste management non radioactive Groundwater acid mine drainage aquifer pollution conference proceedings containment barrier metal tailings Canada Ontario Nickel Rim Mine United States North Carolina Elizabeth City mine water treatment |
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Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1). |
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0144-7815 |
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Treatment of dissolved metals using permeable reactive barriers; Isip:000079718200072; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8601 |
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178 |
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