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Curi, A. C., Granda, W. J. V., Lima, H. M., & Sousa, W. T. (2006). Zeolites and their application in the decontamination of mine waste water. Informacion Tecnologica, 17(6), 111–118.
Abstract: This paper describes the genesis, structure and classification of natural zeolites, including their most relevant properties such as porosity, adsorption and ionic exchange. The use of natural zeolites in the treatment of effluents containing heavy metals is reviewed based on current literature. These uses are focused on mineral-metallurgical effluents and mercury pollution related to artisan mining activities. The study shows that natural zeolites are efficient in removal of heavy metals in metal mining effluents, can be produced and improved at a low cost, and can also be used to adsorb mercury vapors from ovens used to fire amalgams.
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Cambridge, M. (1999). (R. Fernández Rubio, Ed.). Mine, Water & Environment. Ii: International Mine Water Association.
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Burnett, M., Skousen, J. G., Skousen, J. G., & Ziemkiewicz, P. F. (1996). Injection of limestone into underground mines for AMD control. In Acid mine drainage control and treatment. Morgantown: West Virginia University and the National Mine Land Reclamation Center.
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Brown, M., Barley, B., & Wood, H. (2002). Minewater treatment; technology, application and policy. London: IWA Publishing.
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Bolzicco, J., Carrera, J., & Ayora, C. (2004). Eficiencia de la barrera permeable reactiva de Aznalcollar (Sevilla, Espana) como remedio de aguas acidas de mina. Reactive permeable disposal barrier at Aznalcollar Mine, Seville, Spain; as remediation for acid mine drainage. Revista Latino-Americana de Hidrogeologia, 4, 27–34.
Abstract: As a result of the collapse of a mine tailing dam in april 1998 about 40 km of the Agrio and Guadiamar valleys were covered with a layer of pyrite sludge. Although most of the sludge was removed, a small amount remains in the soil of the Agrio valley and the aquifer remains polluted with acid water (ph<4) and metals (10 mg/L Zn, 5 mg/L Cu and Al). A permeable reactive barrier was build across the aquifer to increase the alcalinity and retain the metals. The barrier is made up of three sections of 30 m longX1.4 m thickX5 m deep (average) containing different proportions of limestone gravel, organic compost and zero-valent iron. The residence time of the water in the barrier is about two days. Within the barrier, the pH values increase to near neutral mainly due to calcite dissolution. Metals co-precipitate as oxyhydroxides, and they are also adsorbed on the organic matter surface. Down-stream the barrier, the total pollution removal is around 60-90% for Zn and Cu, and from 50 to 90% for Al and acidity.
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