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Wingenfelder, U., Hansen, C., Furrer, G., & Schulin, R. (2005). Removal of heavy metals from mine waters by natural zeolites. Environ Sci Technol, ES & T, 39(12), 4606–4613.
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Fisher, T. S. R., & Lawrence, G. A. (2006). Treatment of acid rock drainage in a meromictic mine pit lake. Journal of environmental engineering, 132(4), 515–526.
Abstract: The Island Copper Mine pit near Port Hardy, Vancouver Island, B.C., Canada, was flooded in 1996 with seawater and capped with fresh water to form a meromictic (permanently stratified) pit lake of maximum depth 350 m and surface area 1.72 km2. The pit lake is being developed as a treatment system for acid rock drainage. The physical structure and water quality has developed into three distinct layers: a brackish and well-mixed upper layer; a plume stirred intermediate layer; and a thermally convecting lower layer. Concentrations of dissolved metals have been maintained well below permit limits by fertilization of the surface waters. The initial mine closure plan proposed removal of heavy metals by metal-sulfide precipitation via anaerobic sulfate-reducing bacteria, once anoxic conditions were established in the intermediate and lower layers. Anoxia has been achieved in the lower layer, but oxygen consumption rates have been less than initially predicted, and anoxia has yet to be achieved in the intermediate layer. If anoxia can be permanently established in the intermediate layer then biogeochemical removal rates may be high enough that fertilization may no longer be necessary. < copyright > 2006 ASCE.
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Ye, Z. H., Whiting, S. N., Qian, J. H., Lytle, C. M., Lin, Z. Q., & Terry, N. (2001). Trace element removal from coal ash leachate by a 10-year-old constructed wetland. J. Environ. Qual., 30(5), 1710–1719.
Abstract: This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. ne trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e., >10 yr after construction).
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Wolkersdorfer, C. (2002). Mine water tracing. Geological Society Special Publication, -(198), 47–60.
Abstract: This paper describes how tracer tests can be used in flooded underground mines to evaluate the hydrodynamic conditions or reliability of dams. Mine water tracer tests are conducted in order to evaluate the flow paths of seepage water, connections from the surface to the mine, and to support remediation plans for abandoned and flooded underground mines. There are only a few descriptions of successful tracer tests in the literature, and experience with mine water tracing is limited. Potential tracers are restricted due to the complicated chemical composition or low pH mine waters. A new injection and sampling method ('LydiA'-technique) overcomes some of the problems in mine water tracing. A successful tracer test from the Harz Mountains in Germany with Lycopodium clavatum, microspheres and sodium chloride is described, and the results of 29 mine water tracer tests indicate mean flow velocities of between 0.3 and 1.7 m min-1.
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Zinck, J. M., & Aube, B. C. (2000). Optimization of lime treatment processes. CIM Bull., 93(1043), 98–105.
Abstract: Lime neutralization technology is widely used in Canada for the treatment of acid mine drainage and other acidic effluents. In many locations, improvements to the lime neutralization process are necessary to achieve a maximum level of sludge densification and stability. Conventional lime neutralization technology effectively removes dissolved metals to below regulated limits. However, the metal hydroxide and gypsum sludge generated is voluminous and often contains less than 5% solids. Despite recent improvements in the lime neutralization technology, each year, more than 6 700 000 m3 of sludge are generated by treatment facilities operated by the Canadian mining industry. Because lime neutralization is still seen as the best available approach for some sites, sludge production and stability are expected to remain as issues in the near future. Several treatment parameters significantly impact operating costs, effluent quality, sludge production and the geochemical stability of the sludge. Studies conducted both at CANMET and NTC have shown that through minor modifications to the treatment process, plant operators can experience a reduction in operating costs, volume of sludge generated, metal release to the environment and liability. This paper discusses how modifications in plant operation and design can reduce treatment costs and liability associated with lime treatment.
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