Abstract: Passive (wetland) treatment of waters draining abandoned and derelict mine sites has a number of detrac-tions. Detailed knowledge of many of the fundamental processes that dictate the performance and longevity of constructed systems is currently very limited and therefore more research effort is needed before passive treatment becomes an “off-the-shelf” technology.

Abstract: The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system.

Abstract: The mining industry has made tremendous strides in the last 20 years in the prevention and control of acid mine drainage. However, there remain a number of circumstances where the long-term operation, care and maintenance of tailings management facilities will be required. The application of progressive environmental technologies and management systems is key to cost control and environmental liability management at these sites. Mine Waste Management Inc. currently operates Rio Algom Limited's five effluent treatment plants and seven waste management areas in the Elliot Lake, Ontario region using a Remote Plant Monitoring and Control Network (RPMCN). This system, based on Intellutions's “Fix 32” technology, enables the monitoring and control of these plants from a centralized location thus reducing labour costs while providing 24-hour surveillance. Scheduling, auditing and reporting of plant operating and environmental monitoring programs are integrated and controlled using the Envista (super TM) environmental information management system. Proper application of these technologies and management systems facilitates delivery of cost-effective environmental monitoring, and care and maintenance programs at these sites and provides tools to demonstrate compliance with all environmental performance criteria.