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Matlock, M. M., Howerton, B. S., & Atwood, D. A. (2002). Chemical precipitation of heavy metals from acid mine drainage. Water Res, 36(19), 4757–4764.
Abstract: The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR).
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Brown, M., Barley, B., & Wood, H. (2002). Minewater Treatment – Technology, Application and Policy. London: IWA Publishing.
Abstract: Much work has been carried out in recent decades concerning minewater treatment, both in the UK and worldwide. Many different bodies and organizations are involved in developing minewater treatment processes and schemes. Minewater Treatment addresses the need for a single source of state-of-the-art information that draws all the latest research material together. Key features of the book include: a full literature review of minewater treatment throughout the world; an overview of relevant legislation and policy in a global context; a review of currently available methods for treating minewater worldwide; a site specific inventory of minewater treatment schemes within the UK, including compilation of available monitoring data and assessment of performance; a review of emerging and innovative minewater treatment technologies and consideration of related academic research within the UK; a comprehensive list of active and innovative minewater treatment technologies that are not currently compiled in a book or other review publication; a detailed summary and recommendations section assessing the applicability, efficiency and cost-effectiveness of minewater treatment schemes. Relevant scientific subject matter is presented in a concise, easily accessible manner to assist with the objective assessment of the progress made to date. Heavily illustrated with many colour photographs, the book allows best use to be made of the collective experience of minewater treatment practitioners throughout the UK, whilst at the same time placing the UK experience within a global context. An invaluable reference work for mining companies, consultants, planning officers, environmental research scientists, environmental agencies, water utilities and regulatory bodies, Minewater Treatment is a definitive source of information on minewater treatment technologies and will help facilitate the selection of the most appropriate technique required to tackle particular minewater discharge problems. Contents 1. The mine water problem 2. Treatment options 3. Existing sites in the UK: Case studies 4. Existing sites in the UK: Site summaries 5. Summary & conclusions
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Wiseman, I. (2002). Constructed wetlands for minewater treatment. Bristol, England: Environment Agency.
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