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Author |
Tsukamoto, T.K.; Miller, G.C. |
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Title |
Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage |
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Journal Article |
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Year |
1999 |
Publication |
Water Res. |
Abbreviated Journal |
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Volume |
33 |
Issue |
6 |
Pages |
1365-1370 |
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mine water treatment mining activity sulfate-reducing bacteria microbial activity acid mine drainage methanol passive treatment systems sulfate-reducing bacterium sp-nov |
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Abstract |
Sulfate reducing passive bioreactors are increasingly being used to remove metals and raise the pH of acidic waste streams from abandoned mines. These systems commonly use a variety of organic substrates (i.e. manure, wood chips) for sulfate reduction. The effectiveness of these systems decreases as easily accessible reducing equivalents are consumed in the substrate through microbial activity. Using column studies at room temperature (23-26 degrees C), we investigated the addition of lactate and methanol to a depleted manure substrate as a method to reactivate a bioreactor that had lost >95% of sulfate reduction activity. A preliminary experiment compared sulfate removal in gravity fed, flow through bioreactors in which similar masses of each substrate were added to the influent solution. Addition of 148 mg/l lactate resulted in a 69% reduction in sulfate concentration from 300 to 92 mg/l, while addition of 144 mg/l methanol resulted in an 88% reduction in sulfate concentration from 300 to 36 mg/l. Because methanol was found to be an effective sulfate reducing substrate, it was chosen for further experiments due to its inherent physical properties (cost, low freezing point and low viscosity liquid) that make it a superior substrate for remote, high elevation sites where freezing temperatures would hamper the use of aqueous solutions. In these column studies, water containing sulfate and ferrous iron was gravity-fed through the bioreactor columns, along with predetermined methanol concentrations containing reducing equivalents to remove 54% of the sulfate. Following an acclimation period for the columns, sulfate concentrations were reduced from of 900 mg/l in the influent to 454 mg/l in the effluent, that reflects a 93% efficiency of electrons from the donor to the terminal electron acceptor. Iron concentrations were reduced from 100 to 2 mg/l and the pH increased nearly 2 units. (C) 1999 Elsevier Science Ltd. |
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0043-1354 |
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Apr; Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage; Isi:000079485400004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10197.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 10197 |
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50 |
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Author |
Jarvis, A.P.; Younger, P.L. |
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Title |
Passive treatment of ferruginous mine waters using high surface area media |
Type |
Journal Article |
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Year |
2001 |
Publication |
Water Res. |
Abbreviated Journal |
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35 |
Issue |
15 |
Pages |
3643-3648 |
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Keywords |
mine water treatment passive treatment mine water accretion oxidation iron manganese water treatment |
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Abstract |
Rapid oxidation and accretion of iron onto high surface area media has been investigated as a potential passive treatment option for ferruginous, net-alkaline minewaters. Two pilot-scale reactors were installed at a site in County Durham, UK. Each 2.0m high cylinder contained different high surface area plastic trickling filter media. Ferruginous minewater was fed downwards over the media at various flow-rates with the objective of establishing the efficiency of iron removal at different loading rates. Residence time of water within the reactors was between 70 and 360s depending on the flow-rate (1 and 12l/min, respectively). Average influent total iron concentration for the duration of these experiments was 1.43mg/l (range 1.08-1.84mg/l; n=16), whilst effluent iron concentrations averaged 0.41mg/l (range 0.20-1.04mg/l; n=15) for Reactor A and 0.38mg/l (range 0.11-0.93mg/l; n=16) for Reactor B. There is a strong correlation between influent iron load and iron removal rate. Even at the highest loading rates (approximately 31.6g/day) 43% and 49% of the total iron load was removed in Reactors A and B, respectively. At low manganese loading rates (approximately 0.50-0.90g/day) over 50% of the manganese was removed in Reactor B. Iron removal rate (g/m3/d) increases linearly with loading rate (g/day) up to 14g/d and the slope of the line indicates that a mean of 85% of the iron is removed. In conclusion, it appears that the oxidation and accretion of ochre on high surface area media may be a promising alternative passive technology to constructed wetlands at certain sites. |
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0043-1354 |
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Oct; Passive treatment of ferruginous mine waters using high surface area media; 9; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9698.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9698 |
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27 |
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Author |
Wolkersdorfer, C. |
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Title |
Mine water tracer tests as a basis for remediation strategies |
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Journal Article |
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2005 |
Publication |
Chemie der Erde |
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65 |
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Suppl. 1 |
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65-74 |
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Mine water treatment Stratification Convection First flush Tracer tests Microspheres Reactive transport Groundwater problems and environmental effects Pollution and waste management non radioactive acid mine drainage remediation |
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Abstract |
Mining usually causes severe anthropogenic changes by which the ground- or surface water might be significantly polluted. One of the main problems in the mining industry are acid mine drainage, the drainage of heavy metals, and the prediction of mine water rebound after mine closure. Therefore, the knowledge about the hydraulic behaviour of the mine water within the flooded mine might significantly reduce the costs of mine closure and remediation. In the literature, the difficulties in evaluating the hydrodynamics of flooded mines are well described, but only few tracer tests in flooded mines have been published so far. Most tracer tests linked to mine water problems were related to either pollution of the aquifer or radioactive waste disposal and not the mine water itself. Applying the results of the test provides possibilities f or optimizing the outcome of the source-path-target methodology and therefore diminishes the costs of remediation strategies. Consequently, prior to planning of remediation strategies or numerical simulations, relatively cheap and reliable results for decision making can be obtained via a well conducted tracer test. < copyright > 2005 Elsevier GmbH. All rights reserved. |
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C. Wolkersdorfer, TU Bergakademie Freiberg, Lehrstuhl fur Hydrogeologie, 09596 Freiberg, Sachsen, Germany c.wolke@tu-freiberg.de |
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0009-2819 |
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Sep 19; Mine water tracer tests as a basis for remediation strategies; 2767887; Germany 34; Geobase |
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CBU @ c.wolke @ 17499 |
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34 |
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Author |
Gerth, A.; Kießig, G. |
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2001 |
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173-180 |
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mining uranium mining passive treatment Saxony mine water treatment |
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Treatment of radioactively-contaminated and metal-laden mine waters and of seepage fiom tailings ponds and waste rock piles is among the key issues facing WISMUT GmbH in their task to remediate the legacy of uranium mining and processing in the Free States of saxony and rhuringia, Federal Republic of Germany. Generally, contaminant loads of feed waters wn aimnisn over time. At a certain level of costs for the removal of one contaminant unit, continued operation of conventional water treatment plants can hardly be justified any longer. As treatment is still required for water protection, there is an urgent need for-the development and implementation of more cost efficient technologies. WISMUT GmbH and BioPlanta GmbH have studied the suitability of helophye species for contaminant removal from mine waters. In a fust step, original waters were used for an in vitro bioassay. The test results allowed for the determination of the effects of biotic and abiotic factors on helophy'tes'tolerancer ange, growth, and uptake capability of radionuclides and metals. Test series were carried out using Phiagmites australis, Carex disticha, Typha latifolia, and Juncus effusus. Relevant cont-aminant components of the mine waters under investigation included uraniunl iron, arsenic, manganese, nickel, and copper. Investigations led to a number of recommendations conceming plant selection for specific water treatment needs. In a second step, based on these results, a constructed wetland was built in l99g as a pilot plant for the treatment of flood waters liom the pöhla-Tellerhäuser mine and went on-line. Relevant constituents of the neutral flood waters include radium, iron, and arsenic. This wetland specifically uses both physico-chemical and microbiological processes as well as contaminant accumulation by helophytes to achieve the treatment objectives. with the pilot plant in operation for three years now, average removal rates achieved are 95 Yo for kon, 86 yo for arsenic, and 75 % for raäium. WISMUT GmbH intends to put a number of other projects of passive/biological mine water treatment into operation before the end of 2001_ |
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Battelle Press |
Place of Publication |
(6)5 |
Editor |
Leeson, A. |
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Phytoremediation, wetlands and sediments |
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1-57477-115-9 |
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Passive/Biological Treatment of Waters contaminated by Uranium Mining; 2; VORHANDEN | AMD ISI | Wolkersdorfer; als Datei vorhanden 4 Abb., 4 Tab. |
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CBU @ c.wolke @ 17345 |
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372 |
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Author |
Ettner, D.C. |
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Book Whole |
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2007 |
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187-191 |
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Passiv Mine Water Treatment alternative remediation technologies Kongens Mine Roros Folldal Mines Titania's tailings impoundment Storgangen Mine |
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Abstract |
Previous mining history in Norway has resulted in ongoing release of acid mine drainage. Preservation of the historical sites in mining areas does not allow for remediation technologies that result in significant alteration of the historical landscape. Therefore, alternative remediation techniques such as passive mine water treatment have been tested. The climate in Norway varies from mild coastal climates to artic climates, and one of the challenges with passive treatment systems is the cold winter conditions. Anaerobic treatment systems have been built at Kongens Mine near Røros, at Folldal mines, and at Titania's tailings impoundment near Storgangen Mine. These systems utilize sulfate-reducing bacteria that result in the precipitation of metal sulfides. A full- and pilot-scale system at Kongens Mine and Folldal were built in 2006 to remove copper and zinc from typical ARD in an alpine climate. Previous testing with pilot scale systems at Kongens Mine showed that up to 85% copper and 48% zinc could be removed. At Titania A/S the anaerobic system is designed to remove nickel from neutral waters. At this system over 90% nickel is removed when water flow is regulated at a constant flow. Testing shows that the system can function in cold winter conditions, however, optimal metal removal is achieved under warmer temperatures. Temperatures changes by global climatic warming will not adversely affect these anaerobic systems. However, extreme precipitation events and the resulting rapid fluctuations of ARD runoff will provide a challenge for the effectiveness of these systems. |
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Mako Edizioni |
Place of Publication |
Cagliari |
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Cidu, R.; Frau, F. |
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Water in Mining Environments |
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978-88-902955-0-8 |
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Passive Mine Water Treatment in Norway; 1; VORHANDEN | AMD ISI | Wolkersdorfer; als Datei vorhanden 3 Abb., 2 Tab. |
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CBU @ c.wolke @ 17338 |
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387 |
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