|
|
Matsuoka, I. (1996). Mine drainage treatment. Shigen to Sozai = Journal of the Mining and Materials Processing Institute of Japan, 112(5), 273–281.
|
|
|
|
Johnson, D. B., & Hallberg, K. B. (2002). Pitfalls of passive mine water treatment. Reviews in Environmental Science & Biotechnology, 1(5), 335–343.
Abstract: Passive (wetland) treatment of waters draining abandoned and derelict mine sites has a number of detrac-tions. Detailed knowledge of many of the fundamental processes that dictate the performance and longevity of constructed systems is currently very limited and therefore more research effort is needed before passive treatment becomes an “off-the-shelf” technology.
|
|
|
|
Jarvis, A. P., & Younger, P. L. (1999). Design, construction and performance of a full-scare compost wetland for mine-spoil drainage treatment at quaking houses. Jciwem, 13(5), 313–318.
Abstract: Acidic spoil-heap drainage, containing elevated concentrations of iron, aluminium and manganese, has been polluting the Stanley Burn in County Durham for nearly two decades. Following the success of a pilot-scale wetland (the first application of its kind in Europe), a full-scale wetland was installed. Waste manures and composts have been used as the main substrate which is contained within embankments constructed from compacted pulverized fuel ash. The constructed wetland, which cost less than £20,000 to build, has consistently reduced iron and aluminium concentrations and has markedly lowered the acidity of the drainage. A third phase of activities at the site aims to identify and eliminate pollutant-release 'hot spots' within the spoil.
|
|
|
|
Demin, O. A., Dudeney, A. W. L., & Tarasova, I. I. (2002). Remediation of Ammonia-rich Minewater in Constructed Wetlands. Environ. Technol., 23(5), 497–514.
Abstract: A three-year study of ammonia removal from minewater was carried out employing constructed wetland systems (surface flow wetland and subsurface flow wetland cells) at the former Woolley Mine in West Yorkshire, UK The 1.4 Ha surface flow wetland (constructed in 1995) reduced the ammonia concentration from 3.5 – 4.5 mg l(-1) to < 2 3 mg V during the first half of the study and to essentially zero in the last year (2000 – 2001). About 25 % of contained ammonia was converted to nitrate, about 10 % was consumed by the plants and up to 30 % was converted to nitrogen gas. This maturation effect was attributed to increased depth of sludge from sedimentation of ochre, providing increased surface area for immobilisation of ammonia oxidising bacteria. The surface flow wetland finally removed 23 g m(-2) day(-1) ammonia in comparison with 3.8 g m(-2) day' for the subsurface flow (pea gravel) wetland cells, constructed for the present work and dosed with ammonium salts. Removal of ammonia by both systems was consistent with well-established mechanisms of nitrification and denitrification. It was also consistent with ammonia removal in wastewater wetland systems, although the greater aeration in the minewater systems obviated the need for special aeration cycles. The general role of wetland plants in such aerated conditions was attributed to maintaining hydraulic conditions (such as hydraulic efficiency and hydraulic resistance of substratum in subsurface flow systems) in the wetlands and providing a suspended solids filter for minewater.
|
|
|
|
Foucher, S., Battaglia-Brunet, F., Ignatiadis, I., & Morin, D. (2001). Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery. Chemical Engineering Science, 56(4), 1639–1645.
Abstract: Acid-mine drainage can contain high concentrations of heavy metals and release of these contaminants into the environment is generally avoided by lime neutralization. However, this classical treatment is expensive and generates large amounts of residual sludge. The selective precipitation of metals using H2S produced biologically by sulfate-reducing bacteria has been proposed as an alternative process. Here, we report on experiments using real effluent from the disused Chessy-les-Mines mine-site at the laboratory pilot scale. A fixed-bed bioreactor, fed with an H2/CO2 mixture, was used in conjunction with a gas stripping column. The maximum rate of hydrogen transfer in the bioreactor was determined before inoculation. kLa was deduced from measurements of O2 using Higbie and Danckwert's models which predict a dependence on diffusivity. The dynamic method of physical absorption and desorption was used. The maximum rate of H2 transfer suggests that this step should not be a limiting factor. However, an increase in H2 flow rate was observed to induce an increase in sulfate reduction rate. For the precipitation step, the gas mixture from the bioreactor was bubbled into a stirred reactor fed with the real effluent. Cu and Zn could be selectively recovered at pH=2.8 and pH=3.5, respectively. Other impurities such as Ni and Fe could also be removed at pH=6 by sulfide precipitation. Part of the outlet stream from the bioreactor was used to regulate and maintain the pH during sulfide precipitation by feeding the outlet stream back into the bioreactor. The replacement of synthetic medium with real effluent had a positive effect on sulfate reduction rate which increased by 30-40%. This improvement in bacterial efficiency may be related to the large range of oligo-elements provided by the mine-water. The maximum sulfate reduction rate observed with the real effluent was 200 mgl-1 h-1, corresponding to a residence time of 0.9 day. A preliminary cost estimation based on a treatment rate of 5 m3 h-1 of a mine effluent containing 5 gl-1 SO42- is presented.
|
|
