| Records |
| Author |
Barton, C.D.; Karathanasis, A.D. |
| Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Book Chapter |
| Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
Abbreviated Journal |
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Issue  |
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Pages |
1545 |
| Keywords |
acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
| Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
Place of Publication |
81 |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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no |
| Call Number |
CBU @ c.wolke @ 16630 |
Serial |
70 |
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| Author |
Wilmoth, R.C. |
| Title |
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Type |
Book Whole |
| Year |
1973 |
Publication |
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Issue |
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Pages |
159 pp |
| Keywords |
acid mine drainage |
| Abstract |
EPA 670 2 73 100 Spiral-wound reverse osmosis systems were tested on four different acid mine drainage discharges in west virginia and pennsylvania. Comparison studies were made of the hollow-fiber, tubular, and spiral-wound systems at a ferrous iron acid discharge; and of hollow-fiber and spiral-wound systems at a ferric iron acid discharge. At all sites, the limiting factor in high recovery operation was calcium sulfate insolubility. An empirical formula was developed for predicting maximum recovery. Application of reverse osmosis was demonstrated to be technically feasible for a large percentage of acid mine drainage discharges. A process called 'neutrolisis' was developed in which the reverse osmosis brine is neutralized and clarified, and the supernatant recycled to the influent to the reverse osmosis unit. In this manner, the neutrolosis process discharges only a high quality product water and a neutralized sludge. Neutrolosis recoveries as high as 98.8 percent were achieved at a ferric iron acid discharge site. (epa) |
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U.S. Government Print. Offfice |
Place of Publication |
Washington |
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Environmental Protection Agency, Technology Series Report |
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Applications of reverse osmosis to acid mine drainage treatment; 99; AMD ISI | Wolkersdorfer; TUB München |
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no |
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CBU @ c.wolke @ 9961 |
Serial |
74 |
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| Author |
Schueck, J.H. |
| Title |
Limestone diversion wells; a low-maintenance, cost-effective method for treating acid-mine drainage with limestone |
Type |
Book Chapter |
| Year |
1995 |
Publication |
Guidebook for the Annual Field Conference of Pennsylvania Geologists, vol.60 Applied geology in the Lock Haven and Williamsport region, Clinton and Lycoming counties, northcentral Pennsylvania |
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Pages |
9-12 |
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acid mine drainage; Babb Creek watershed; Blossburg coal basin; carbonate rocks; ground water; hydrology; limestone; Pennsylvania; pollution; remediation; sedimentary rocks; Tioga County Pennsylvania; United States; water wells; watersheds; wells 22, Environmental geology |
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Editor |
Carnein, C.R.; Way, J.H. |
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Limestone diversion wells; a low-maintenance, cost-effective method for treating acid-mine drainage with limestone; GeoRef; English; 1996-018760; 60th annual field conference of Pennsylvania geologists, Williamsport, PA, United States, Oct. 5-7, 1995 References: 3; 1 table, sketch map |
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no |
| Call Number |
CBU @ c.wolke @ 6420 |
Serial |
77 |
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| Author |
Diamond, J.M.; Bower, W.; Gruber, D. |
| Title |
Use of man-made impoundment in mitigating acid mine drainage in the North Branch Potomac River |
Type |
Journal Article |
| Year |
1993 |
Publication |
Environ. Manage. |
Abbreviated Journal |
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17 |
Issue |
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Pages |
14 |
| Keywords |
Acid mine drainage Potomac River Reservoir macroinvertebrate Fish Mayflies |
| Abstract |
The US Department of the Army, Baltimore District Corps of Engineers, oversees a long-term monitoring study to assess and evaluate effects of the Jennings-Randolph reservoir on biota in the North Branch Potomac River. The reservoir was intended, in part, to mitigate effects of acid mine drainage originating in upstream and headwater areas. The present study assessed recovery of benthos and fish in this system, six years after completion of the reservoir. Higher pH and lower iron and sulfate concentrations were observed upstream of the reservoir compared to preimpoundment conditions, suggesting better overall water quality in the upper North Branch. Water quality improved slightly directly downstream of the reservoir. However, the reservoir itself was poorly colonized by macrophytes and benthic organisms, and plankton composition suggested either metal toxicity and/or nutrient limitation. One large tributary to the North Branch and the reservoir (Stony River) was shown to have high (and possibly toxic) levels of manganese, iron, zinc, and aluminum due to subsurface coal mine drainage. Macroinvertebrate diversity and number of taxa were higher in sites downstream of the reservoir in the present study. Compared with previous years, the present study suggested relatively rapid recovery in the lower North Branch due to colonization from two major unimpacted tributaries in this system: Savage River and South Branch Potomac. Abundance of certain mayfly species across sites provided the most clear evidence of longitudinal gradients in water quality parameters and geomorphology. Fish data were consistent with macroinvertebrate results, but site-to-site variation in species composition was greater. Data collected between 1982 and 1987 suggested that certain fish species have unsuccessfully attempted to colonize sites directly downstream of the reservoir despite the more neutral pH water there. Our results show that recovery of biota in the North Branch Potomac was attributed to decreased acid inputs from mining operations and dilution from the Savage River, which contributed better water quality. Continued improvement of North Branch Potomac biota may not be expected unless additional mitigation attempts, either within the reservoir or upstream, are undertaken. |
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0364-152x |
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Feb.; Use of man-made impoundment in mitigating acid mine drainage in the North Branch Potomac River; New York, NY ; Heidelberg ; Berlin : Springer; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7016.pdf; Opac |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 7016 |
Serial |
79 |
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| Author |
Cravotta, C.A., III; Watzlaf, G.R.; Naftz, D.L.; Morrison, S.J.; Fuller, C.C.; Davis, J.A. |
| Title |
Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients |
Type |
Book Chapter |
| Year |
2002 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
acid mine drainage; alkaline earth metals; aquatic environment; aquifers; calcium; carbonate rocks; chemical properties; construction; construction materials; crushed stone; dissolved materials; drainage; effluents; ground water; limestone; magnesium; metals; pH; pollution; porous materials; precipitation; retention; saturation; sedimentary rocks; sulfate ion; suspended materials 22, Environmental geology |
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Academic Press |
Place of Publication |
Amsterdam |
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0125135637 |
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Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients; GeoRef; English; 2004-040518; References: 66; illus. incl. 4 tables |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 5686 |
Serial |
81 |
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