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Wolkersdorfer, C. (2005). Mine water tracer tests as a basis for remediation strategies. Chemie der Erde, 65(Suppl. 1), 65–74.
Abstract: Mining usually causes severe anthropogenic changes by which the ground- or surface water might be significantly polluted. One of the main problems in the mining industry are acid mine drainage, the drainage of heavy metals, and the prediction of mine water rebound after mine closure. Therefore, the knowledge about the hydraulic behaviour of the mine water within the flooded mine might significantly reduce the costs of mine closure and remediation. In the literature, the difficulties in evaluating the hydrodynamics of flooded mines are well described, but only few tracer tests in flooded mines have been published so far. Most tracer tests linked to mine water problems were related to either pollution of the aquifer or radioactive waste disposal and not the mine water itself. Applying the results of the test provides possibilities f or optimizing the outcome of the source-path-target methodology and therefore diminishes the costs of remediation strategies. Consequently, prior to planning of remediation strategies or numerical simulations, relatively cheap and reliable results for decision making can be obtained via a well conducted tracer test. < copyright > 2005 Elsevier GmbH. All rights reserved.
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Hulshof, A. H. M., Blowes, D. W., & Douglas Gould, W. (2006). Evaluation of in situ layers for treatment of acid mine drainage: A field comparison. Water Res, 40(9), 1816–1826.
Abstract: Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell.
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Yernberg, W. R. (2000). Improvements seen in acid-mine-drainage technology. Min. Eng., 52(9), 67–70.
Keywords: acid mine drainage; bacteria; chemical weathering; coal mines; Colorado; copper ores; effects; geochemistry; hydrogen; inorganic acids; international cooperation; ions; lead ores; medical geology; metal ores; mines; molybdenum ores; oxidation; pH; pollution; prediction; pyrite; reclamation; remediation; research; risk assessment; silicates; soil treatment; solid waste; sulfides; sulfuric acid; Summitville Mine; tailings; tailings ponds; technology; United States; waste disposal; weathering; zinc ores 22, Environmental geology
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Zhuang, J. M. (2004). Lignor(TM) process for acidic rock drainage treatment. Environ. Technol., 25(9), 1031–1040.
Abstract: The process using lignosulfonates for acidic rock drainage (ARD) treatment is referred to as the Lignor(TM) process. Lignosulfonates are waste by-products produced in the sulfite pulping process. The present study has shown lignosulfonates are able to protect lime from developing an external surface coating, and hence to favor its dissociation. Further, the addition of lignosulfonates to ARD solutions increased the clotting and settling rate of the formed sludge. The capability of lignosulfonates to form stable metal-lignin complexes makes them very useful in retaining metal ions and thus improving the long-term stability of the sludge against leaching. The Lignor(TM) process involves metal sorption with lignosulfonates, ARD neutralization by lime to about pH 7, pH adjustment with caustic soda to 9.4 – 9.6, air oxidation to lower the pH to a desired level, and addition of a minimum amount of FeCl3 for further removal of dissolved metals. The Lignor(TM) process removes all concerned metals (especially Al and Mn) from the ARD of the Britannia Mine (located at Britannia Beach, British Columbia, Canada) to a level lower than the limits of the B.C. Regulations. Compared with the high-density sludge (HDS) process, the Lignor(TM) process has many advantages, such as considerable savings in lime consumption, greatly reduced sludge volume, and improved sludge stability.
Keywords: mine water treatment
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Govind, R. (2001). Treatment of acid mine drainage using membrane bioreactors. Bioremediation of Inorganic Compounds, 6(9), 1–8.
Abstract: Acid mine drainage is a severe water pollution problem attributed to past mining activities. The exposure of the post-mining mineral residuals to water and air results in a series of chemical and biological oxidation reactions, that produce an effluent which is highly acidic and contains high concentrations of various metal sulfates. Several treatment techniques utilizing sulfate reducing bacteria have been proposed in the past; however few of them have been practically applied to treat acid mine drainage. This research deals with membrane reactor studies to treat the acid mine drainage water from Berkeley Pit in Butte, Montana using hydrogen-consuming sulfate reducing bacteria. Eventually, the membrane reactor system can be applied towards the treatment of acid mine drainage to produce usable water.
Keywords: mine water treatment
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