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Murray-Gulde, C.L. |
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Contributions of Schoenoplectus californicus in a constructed wetland system receiving copper contaminated wastewater |
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Water, Air, Soil Pollut. |
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163 |
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1-4 |
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355-378 |
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mine water treatment |
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Functional roles of Schoenoplectus californicus, giant bulrush, were evaluated in an 3.2 ha (8-acre) constructed wetland treatment system receiving copper-contaminated water. The constructed wetland used in this research was designed to decrease bioavailable copper concentrations in a wastestream and eliminate associated toxicity to downstream biota by exploiting the thermodynamic processes responsible for copper speciation. This was achieved by integrating carbon, sulfur and copper biogeochemical cycles. In this system, S. californicus, which represents an integral part of the carbon cycle, provides a physical, chemical and biological role in removing metals from the aqueous phase. The specific contributions of S. californicus in this system are to provide a sustainable carbon source for removal of copper by (1) provision of an organic ligand for sorption of copper entering the system, (2) production of organic ligands through growth of S. californicus, (3) accretion of organic ligands over time due to decomposition of S. californicus detritus, and (4) use of organic carbon as an energy source for dissimilatory sulfate production. Shoots and roots of viable S. californicus sorbed 0.88% and 5.88%, respectively, of copper entering the system. The half-life of S. californicus detritus in the constructed wetland system was approximately 184 d, indicating that sufficient detritus will accrete over time, providing binding sites for copper and an energy source for bacterial metabolic processes that contribute to copper immobilization in wetland systems. |
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Contributions of Schoenoplectus californicus in a constructed wetland system receiving copper contaminated wastewater; Wos:000229973400022; Times Cited: 2; ISI Web of Science |
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CBU @ c.wolke @ 16969 |
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115 |
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Whitehead, P.G. |
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Bioremediation of acid mine drainage: an introduction to the Wheal Jane wetlands project |
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Journal Article |
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2005 |
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Science of the Total Environment |
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338 |
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1-2 |
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15-21 |
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mine water treatment |
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Acid mine drainage (AMD) is a widespread environmental problem associated with both working and abandoned mining operations. As part of an overall strategy to determine a long-term treatment option for AMD, a pilot passive treatment plant was constructed in 1994 at Wheat Jane Mine in Cornwall, UK. The plant consists of three separate systems; each containing aerobic reed beds, anaerobic cell and rock filters, and represents the largest European experimental facility of its kind. The systems only differ by the type of pre-treatment utilised to increase the pH of the influent minewater (pH<4): lime-dosed (LD), anoxic limestone drain (ALD) and lime free (LF), which receives no form of pre-treatment. The Wheal Jane pilot plant offered a unique facility and a major research project was established to evaluate the pilot plant and study in detail the biological mechanisms and the geochemical and physical processes that control passive treatment systems. The project has led to data, knowledge, models and design criteria for the future design, planning and sustainable management of passive treatment systems. A multidisciplinary team of scientists and managers from the U.K. universities, the Environment Agency and the Mining Industry has been put together to obtain the maximum advantage from the excellent facilities facility at Wheal Jane. (C) 2004 Elseaier B.V All rights reserved. |
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Bioremediation of acid mine drainage: an introduction to the Wheal Jane wetlands project; Wos:000227130400003; Times Cited: 1; ISI Web of Science |
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CBU @ c.wolke @ 16972 |
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116 |
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Zhuang, J.M. |
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Lignor(TM) process for acidic rock drainage treatment |
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2004 |
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Environ. Technol. |
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25 |
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9 |
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1031-1040 |
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mine water treatment |
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The process using lignosulfonates for acidic rock drainage (ARD) treatment is referred to as the Lignor(TM) process. Lignosulfonates are waste by-products produced in the sulfite pulping process. The present study has shown lignosulfonates are able to protect lime from developing an external surface coating, and hence to favor its dissociation. Further, the addition of lignosulfonates to ARD solutions increased the clotting and settling rate of the formed sludge. The capability of lignosulfonates to form stable metal-lignin complexes makes them very useful in retaining metal ions and thus improving the long-term stability of the sludge against leaching. The Lignor(TM) process involves metal sorption with lignosulfonates, ARD neutralization by lime to about pH 7, pH adjustment with caustic soda to 9.4 – 9.6, air oxidation to lower the pH to a desired level, and addition of a minimum amount of FeCl3 for further removal of dissolved metals. The Lignor(TM) process removes all concerned metals (especially Al and Mn) from the ARD of the Britannia Mine (located at Britannia Beach, British Columbia, Canada) to a level lower than the limits of the B.C. Regulations. Compared with the high-density sludge (HDS) process, the Lignor(TM) process has many advantages, such as considerable savings in lime consumption, greatly reduced sludge volume, and improved sludge stability. |
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Lignor(TM) process for acidic rock drainage treatment; Wos:000224971800006; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16998 |
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117 |
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Scholz, M. |
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Mature experimental constructed wetlands treating urban water receiving high metal loads |
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2002 |
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Biotechnology Progress |
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18 |
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6 |
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1257-1264 |
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mine water treatment |
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The aim was to assess over 2 years the treatment efficiencies of vertical-flow wetland filters containing macrophytes and granular media of different. adsorption capacities. Different concentrations of lead and copper sulfate (constant for 1 year each) were added to urban beck inflow water in order to simulate pretreated (pH adjustment assumed) mine wastewater. After 1 year of operation, the inflow concentrations for lead and copper were increased from 1.30 to 2.98 and from 0.98 to 1.93 mg/L, respectively. However, the metal mass load rates (mg/m(2)/d) were increased by a factor of approximately 4.9 for lead and 4.3 for copper. No breakthrough of metals was recorded. Lead and copper accumulated in the biomass of the litter zone and rhizomes of the macrophytes. Furthermore, microbiological activity decreased during the second year of operation. Bioindicators such as ciliated protozoa and zooplankton decreased sharply in numbers but diatoms increased. In conclusion, the use of macrophytes and, adsorption media did not significantly enhance the filtration of lead and copper. Particulate lead is removed by filtration processes including straining. Furthermore, some expensive and time-consuming water quality variables can be predicted with less expensive ones such as temperature in order to reduce sampling costs. |
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Mature experimental constructed wetlands treating urban water receiving high metal loads; Wos:000179760000018; Times Cited: 11; ISI Web of Science |
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CBU @ c.wolke @ 17032 |
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119 |
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Author |
Lawrence, R. |
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Title |
Technology reduces sulphur compounds – A new way of treating acid mine drainage |
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2002 |
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Canadian Mining Journal |
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123 |
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7 |
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27-27 |
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mine water treatment |
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Technology reduces sulphur compounds – A new way of treating acid mine drainage; Wos:000179123100016; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 8075 |
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120 |
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