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Fisher, T. S. R., & Lawrence, G. A. (2006). Treatment of acid rock drainage in a meromictic mine pit lake. Journal of environmental engineering, 132(4), 515–526.
Abstract: The Island Copper Mine pit near Port Hardy, Vancouver Island, B.C., Canada, was flooded in 1996 with seawater and capped with fresh water to form a meromictic (permanently stratified) pit lake of maximum depth 350 m and surface area 1.72 km2. The pit lake is being developed as a treatment system for acid rock drainage. The physical structure and water quality has developed into three distinct layers: a brackish and well-mixed upper layer; a plume stirred intermediate layer; and a thermally convecting lower layer. Concentrations of dissolved metals have been maintained well below permit limits by fertilization of the surface waters. The initial mine closure plan proposed removal of heavy metals by metal-sulfide precipitation via anaerobic sulfate-reducing bacteria, once anoxic conditions were established in the intermediate and lower layers. Anoxia has been achieved in the lower layer, but oxygen consumption rates have been less than initially predicted, and anoxia has yet to be achieved in the intermediate layer. If anoxia can be permanently established in the intermediate layer then biogeochemical removal rates may be high enough that fertilization may no longer be necessary. < copyright > 2006 ASCE.
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Sanders, F., Rahe, J., Pastor, D., & Anderson, R. (1999). Wetlands treat mine runoff. Civil Engineering, 69(1), 53–55.
Abstract: In the late 1890s, silver, lead and zinc deposits were discovered along the headwaters of the Blackfoot River, northeast of Missoula, Mont. Settlers began mining the metals in earnest, and eventually the mines became known as the Upper Blackfoot Mining Complex (UBMC). Many of the mines were operated long enough to supply metals for World War II weaponry, but after the war the mines were abandoned, and by the 1960s, their orange-tainted runoff began to concern both passersby and state officials. In 1991, the state contacted the current owners of several of those mines-including the Mike Horse and the Anaconda-to negotiate a voluntary cleanup. The American Smelting and Refining Co. (ASARCO) and the Atlantic Richfield Co. (ARCO) agreed to remediate the sites' metal-enriched, moderately to severely acidic drainage, which was discharging into the upper Blackfoot River. As part of effort to reclaim the Mike Horse and Anaconda mines, engineers with McCulley, Frick and Gilman Inc. (MFG), Boulder, Colo., developed an integrated, passive wetland treatment system that will take several years to reach full treatment capacity in the high-elevation environment, but will last for decades. (Constructed and restored wetlands have also been part of the remediation of other UBMC mines, such as the Carbonate and Paymaster mines.) The Mike Horse and Anaconda system, designed to meet National Pollutant Discharge Elimination Systems (NPDES) restrictions, concentrates primarily on zinc and iron and, to a lesser extent, on copper, lead and other metals.
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Banks, D., Younger, P. L., Arnesen, R. - T., Iversen, E. R., & Banks, S. B. (1997). Mine-water chemistry: The good, the bad and the ugly. Environ. Geol., 32(3), 157–174.
Abstract: Contaminative mine drainage waters have become one of the major hydrogeological and geochemical problems arising from mankind's intrusion into the geosphere. Mine drainage waters in Scandinavia and the United Kingdom are of three main types: (1) saline formation waters; (2) acidic, heavy-metal-containing, sulphate waters derived from pyrite oxidation, and (3) alkaline, hydrogen-sulphide-containing, heavy-metal-poor waters resulting from buffering reactions and/or sulphate reduction. Mine waters are not merely to be perceived as problems, they can be regarded as industrial or drinking water sources and have been used for sewage treatment, tanning and industrial metals extraction. Mine-water problems may be addressed by isolating the contaminant source, by suppressing the reactions releasing contaminants, or by active or passive water treatment. Innovative treatment techniques such as galvanic suppression, application of bactericides, neutralising or reducing agents (pulverised fly ash-based grouts, cattle manure, whey, brewers' yeast) require further research.
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Coulton, R., Bullen, C., & Hallett, C. (2003). The design and optimisation of active mine water treatment plants. Land Contam. Reclam., 11(2), 273–280.
Abstract: This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters.
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Laine, D. M., & Jarvis, A. P. (2003). Engineering design aspects of passive in situ remediation of mining effluents. Land Contam. Reclam., 11(2), 113–126.
Abstract: Passive treatment of contaminated effluents can offer a 'low cost' management opportunity to remediate drainages to the standards required by enforcement agencies. However, the initial cost of construction of passive treatment systems is significant and often in excess of that for active treatment systems. It is therefore important that the engineering design of the passive systems produces an effective and efficient scheme to enable the construction and maintenance costs to be minimised as far as possible. Possible parameters for the design of passive systems are suggested to seek to obtain uniformity in size and layout of treatment elements where this may be possible. Passive treatment systems include aeration systems, sedimentation ponds, aerobic and anaerobic wetlands, anoxic limestone drains and reducing alkalinity producing systems. Most active treatment systems also include passive elements in the treatment stream. The basic design considerations that should be considered to ensure the construction of efficient systems are discussed.
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