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Mitchell, P. (2000). Silica micro encapsulation: An innovative commercial technology for the treatment of metal and radionuclide contamination in water and soil. Environmental Issues and Management of Waste in Energy and Mineral Production, , 307–314.
Abstract: Klean Earth Environmental Company (KEECO) has developed the Silica Micro Encapsulation (SME) technology to treat heavy metals and radionuclides in water and soil. Unlike conventional neutralization/precipitation methods, SME encapsulates the contaminants in a permanent silica matrix resistant to degradation under even extreme environmental conditions. Encapsulated metals and radionuclides are effectively immobilized, minimising the potential for environmental contamination and impacts on human or ecosystem health. The effectiveness of SME has been proven through independent reviews, laboratory and field trials and commercial contracts, and the technology can be used to control and prevent acid drainage and the transport of soluble metals from mine sites, tailings areas, landfills and industrial sites. Successful demonstrations in the treatment of sediments and in brownfield redevelopment, treatment of metal-finishing wastewaters, and control of hazardous, low-level, and mixed waste at DOE/DOD sites and commercial nuclear power plants have also been undertaken. This paper describes the reactions involved in the SME process, the methods by which SME chemicals are introduced to various media, and recent project applications relevant to the cost effective remediation and prevention of environmental problems arising from energy and mineral production.
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Weeks, R. E., Krohn, R., & Walker, T. H. (2000). Water management during the Pinto Valley removal action. In Tailings and Mine and Waste 2000, Proceedings of the Seventh International Conference, Fort Collins, US, Jan 22 26, 2000 (pp. 499–506).
Abstract: Der Bruch des Dammes einer Halde der Grube Nr. 14 des Kupfer- Bergbaubetriebes Pinto Valley in Arizona, USA, im Jahre 1997 führte zum Eintrag von 370000 yd(exp 3) Bergematerials und Tailings in das Bett des Flusses Pinto Creek, USA, wodurch letzteres blockiert wurde. Der Vorfall ereignete sich in bergigem Gelände unterhalb eines 14 Quadratmeilen großen Abschnittes des Flusseinzugsgebietes oberhalb des Sees Roosevelt Lake, USA, einer Trinkwasserquelle für Phoenix, USA. Aufgrund der Bedeutung des Gebietes wurde eine Strategie zur Verhütung weiterer Beeinträchtigungen der Wasserqualität ausgearbeitet. Diese beinhaltete Managementaspekte zur Gewährleistung einer schnellen Planung und Ausführung der notwendigen Arbeiten gekoppelt mit der Planung, dem Bau und dem Betrieb von Rückhalte und Umleitungssystemen für auftretende Wässer. Die Auslegung dieser Systeme erfolgte auf der Grundlage der Daten des Einzugsgebietes und der klimatischen Verhältnisse, wobei verschiedene Wahrscheinlichkeiten der Überschreitung der ermittelten Werte berücksichtigt wurden. Innerhalb von acht Monaten konnten die Tailings aus dem betroffenen Gebiet entfernt werden, ohne dass belastete Oberflächenwässer freigesetzt wurden.
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Watzlaf, G. R., Schroeder, K. T., & Kairies, C. L. (2000). Proceedings, 17th Annual National Meeting – American Society for Surface Mining and Reclamation. Tampa.
Abstract: Ten passive treatment systems, located in Pennsylvania and Maryland, have been intensively monitored for up to ten years. Influent and effluent water quality data from ten anoxic limestone drains (ALDs) and six reducing and alkalinity-producing systems (RAPS) have been analyzed to determine long-term performance for each of these specific unit operations. ALDs and RAPS are used principally to generate alkalinity, ALDs are buried beds of limestone that add alkalinity through dissolution of calcite. RAPS add alkalinity through both limestone dissolution and bacterial sulfate reduction. ALDs that received mine water containing less than 1 mg/L of both ferric iron and aluminum have continued to produce consistent concentrations of alkalinity since their construction. However, an ALD that received 20 mg/L of aluminum experienced a rapid reduction in permeability and failed within five months. Maximum levels of alkalinity (between 150 and 300 m&) appear to be reached after I5 hours of retention. All but one RAPS in this study have been constructed and put into operation only within the past 2.5 to 5 years. One system has been in operation and monitored for more than nine years. AIkalinity due to sulfate reduction was highest during the first two summers of operation. Alkalinity due to a limestone dissolution has been consistent throughout the life of the system. For the six RAPS in this study, sulfate reduction contributed an average of 28% of the total alkalinity. Rate of total alkalinity generation range from 15.6 gd''rn-'to 62.4 gd-'mL2 and were dependent on influent water quality and contact time.
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Stoica, L., & Dima, G. (2000). Pb(II) removal from aqueous systems by biosorption-flotation on mycelial residues of Penicillium chrysogenum. In A. Rozkowski (Ed.), 7th international Mine Water Association congress; Mine water and the environment (pp. 472–481). Sosnowiec: Uniwersytet Slaski.
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Smith, I. J. H. (2000). AMD treatment, it works but are we using the right equipment? Tailings and mine waste ', , 419–427.
Abstract: For the past 40 years various approaches have been developed to treat acid waters coming from abandoned as well as operating mining operations. System designs have evolved to meet increasingly stringent discharge permit limits for treated water, as well as to provide solid disposal within economic constraints. A treatment system for remediation of acid mine drainage (AMD) or acid groundwater (AG) requires two main steps: 1. The addition of chemicals to precipitate dissolved metals contained in the waters, and if necessary, to coagulate the precipitated solids ahead of physical separation. 2. Physical separation of the precipitated solids from the water so the water can be lawfully discharged from the site. Choosing the appropriate technology and equipment results in the most efficient plant design, the lowest capital outlay, and minimum operating cost. The goal of these plants is to discharge liquids and solids able to meet standards. The separation of solids from liquids can be achieved through various means, including gravity settling, flotation, mechanical dewatering, filtration and evaporation. As important as the liquid solids separation unit operations are, they are driven by the chemistry of the water to be treated. The content of the dissolved solids will influence the quality and quantity of the solids produced during precipitation. Thus the two aspects must be integrated, with chemistry first, then mechanical engineering. This presentation will provide an overview of a number of liquid solids separation tools currently being used to treat AMD-AG at several sites in the USA. It will also discuss how their operations are impacted by the chemistry of their particular acid water feeds. The tools used include clarifier-thickeners, solids contact clarifiers, dissolved air flotation, polishing filters, membrane filters, and mechanical dewatering devices (belt and filter presses, vacuum filters, and driers).
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