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Author Barton, C.D.; Karathanasis, A.D.
Title Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage Type Book Chapter
Year 1997 Publication AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts Abbreviated Journal
Volume Issue Pages 1545
Keywords acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology
Abstract The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system.
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Publisher AAPG Bulletin Place of Publication 81 Editor
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Notes Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 Approved no
Call Number CBU @ c.wolke @ 16630 Serial 70
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Author Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R.
Title Removal of heavy metals from mine waters by natural zeolites Type Journal Article
Year 2005 Publication Environ Sci Technol, ES & T Abbreviated Journal
Volume 39 Issue 12 Pages 4606-4613
Keywords Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group
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Address G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch
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ISSN 0013-936x ISBN (up) Medium
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Notes Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English Approved no
Call Number CBU @ c.wolke @ 5382 Serial 71
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Author Fisher, T.S.R.; Lawrence, G.A.
Title Treatment of acid rock drainage in a meromictic mine pit lake Type Journal Article
Year 2006 Publication Journal of environmental engineering Abbreviated Journal
Volume 132 Issue 4 Pages 515-526
Keywords Pollution and waste management non radioactive Groundwater problems and environmental effects geological abstracts: environmental geology (72 14 2) geomechanics abstracts: excavations (77 10 10) meromictic lake acid mine drainage mine waste copper water pollution Bacteria microorganisms Canada Vancouver Island British Columbia North America
Abstract The Island Copper Mine pit near Port Hardy, Vancouver Island, B.C., Canada, was flooded in 1996 with seawater and capped with fresh water to form a meromictic (permanently stratified) pit lake of maximum depth 350 m and surface area 1.72 km2. The pit lake is being developed as a treatment system for acid rock drainage. The physical structure and water quality has developed into three distinct layers: a brackish and well-mixed upper layer; a plume stirred intermediate layer; and a thermally convecting lower layer. Concentrations of dissolved metals have been maintained well below permit limits by fertilization of the surface waters. The initial mine closure plan proposed removal of heavy metals by metal-sulfide precipitation via anaerobic sulfate-reducing bacteria, once anoxic conditions were established in the intermediate and lower layers. Anoxia has been achieved in the lower layer, but oxygen consumption rates have been less than initially predicted, and anoxia has yet to be achieved in the intermediate layer. If anoxia can be permanently established in the intermediate layer then biogeochemical removal rates may be high enough that fertilization may no longer be necessary. < copyright > 2006 ASCE.
Address Prof. G.A. Lawrence, Univ. of British Columbia, Vancouver, BC V6T 1Z4, Canada lawrence@civil.ubc.ca
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ISSN 0733-9372 ISBN (up) Medium
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Notes Apr.; Treatment of acid rock drainage in a meromictic mine pit lake; 2873922; United-States 38; Geobase Approved no
Call Number CBU @ c.wolke @ 17494 Serial 72
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Author Ueki, K.; Kotaka, K.; Itoh, K.; Ueki, A.
Title Potential availability of anaerobic treatment with digester slurry of animal waste for the reclamation of acid mine water containing sulfate and heavy metals Type Journal Article
Year 1988 Publication Journal of Fermentation Technology Abbreviated Journal
Volume 66 Issue 1 Pages
Keywords mine water treatment
Abstract The use of an anaerobic digester slurry of cattle waste for the reclamation of acid mine water was examined. When the digester slurry was mixed with acid mine water, anaerobic digestion, including sulfate reduction and methanogenesis, was enhanced. In the mixture of acid mine water and the digester slurry, sulfate reduction proceeded without diminishing methanogenesis. The digester slurry and its supernatant (SDF-sup) showed a significant capacity to act as a strong alkaline reagent, and the pH of the acid mine water was markedly elevated by the addition of the digester slurry of SDF-sup even at the low ratio of 1% (v/v). Precipitation of heavy metals in the acid mine water occurred as the pH was elevated by the addition of SDF-sup. When the digester slurry was added at the ratio of 5% (v/v) to acid mine water which had been pretreated with SDF-sup, the rate of sulfate reduction increased with increasing the concentration of sulfate in the mixture up to about 1,400 mg·l-1. In acid mine water pretreated with SDF-sup and supplemented with the digester slurry at the ratio of 5% (v/v), the maximum amount of sulfate reduced within 20 d of incubation was about 1,000 mg·l-1, and the maximum rate of sulfate reduction was about 120 mg SO42-·l-1·d-1.
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ISSN 0385-6380 ISBN (up) Medium
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Notes Potential availability of anaerobic treatment with digester slurry of animal waste for the reclamation of acid mine water containing sulfate and heavy metals; Amsterdam [u.a.] : Elsevier; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7036.pdf; Opac Approved no
Call Number CBU @ c.wolke @ 7036 Serial 75
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Author Ye, Z.H.; Whiting, S.N.; Qian, J.H.; Lytle, C.M.; Lin, Z.Q.; Terry, N.
Title Trace element removal from coal ash leachate by a 10-year-old constructed wetland Type Journal Article
Year 2001 Publication J. Environ. Qual. Abbreviated Journal
Volume 30 Issue 5 Pages 1710-1719
Keywords acid mine drainage; Alabama; ash; bioaccumulation; boron; cadmium; constructed wetlands; environmental analysis; environmental effects; iron; Jackson County Alabama; Juncus effusus; leachate; manganese; metals; pH; pollutants; pollution; remediation; soils; sulfur; trace elements; Typha latifolia; United States; vegetation; waste water; wetlands; Widows Creek; Widows Creek Steam Plant; zinc; Typha; Juncus 22, Environmental geology
Abstract This study investigated the ability of a 10-yr-old constructed wetland to treat metal-contaminated leachate emanating from a coal ash pile at the Widows Creek electric utility, Alabama (USA). The two vegetated cells, which were dominated by cattail (Typha latifolia L.) and soft rush (Juncus effusus L.), were very effective at removing Fe and Cd from the wastewater, but less efficient for Zn, S, B, and Mn. The concentrations were decreased by up to 99% for Fe, 91% for Cd, 63% for Zn, 61% for S, 58% for Mn, and 50% for B. Higher pH levels (>6) in standing water substantially improved the removing efficiency of the wetland for Mn only. The belowground tissues of both cattail and soft rush had high concentrations of all elements; only for Mn, however, did the concentration in the shoots exceed those in the belowground tissues. The concentrations of trace elements in fallen litter were higher than in the living shoots, but lower than in the belowground tissues. ne trace element accumulation in the plants accounted for less than 2.5% of the annual loading of each trace element into the wetland. The sediments were the primary sinks for the elements removed from the wastewater. Except for Mn, the concentrations of trace elements in the upper layer (0-5 cm) of the sediment profile tended to be higher than the lower layers (5-10 and 10-15 cm). We conclude that constructed wetlands are still able to efficiently remove metals in the long term (i.e., >10 yr after construction).
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ISSN 0047-2425 ISBN (up) Medium
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Notes Aug 1; Trace element removal from coal ash leachate by a 10-year-old constructed wetland; 2002-017274; References: 33; illus. incl. 2 tables United States (USA); file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/5703.pdf; GeoRef; English Approved no
Call Number CBU @ c.wolke @ 5703 Serial 76
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