| Records |
| Author |
Matlock, M.M.; Howerton, B.S.; Atwood, D.A. |
| Title |
Chemical precipitation of heavy metals from acid mine drainage |
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Journal Article |
| Year |
2002 |
Publication |
Water Res |
Abbreviated Journal |
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| Volume |
36 |
Issue |
19 |
Pages |
4757-4764 |
| Keywords |
mine water treatment BDET Acid mine drainage Water treatment Remediation Heavy metals Chemical precipitation Mercury Iron |
| Abstract |
The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR). |
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0043-1354 |
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Nov.; Chemical precipitation of heavy metals from acid mine drainage; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/15005.pdf; Science Direct |
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| Call Number |
CBU @ c.wolke @ 15005 |
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48 |
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| Author |
Kepler, D.A.; Mc Cleary, E.C. |
| Title |
Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage |
Type |
Journal Article |
| Year |
1994 |
Publication |
Proceedings, International Land Reclamation and Mine Drainage Conference |
Abbreviated Journal |
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| Volume |
1 |
Issue |
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Pages |
195-204 |
| Keywords |
acid mine drainage; alkalinity; anaerobic environment; calcium carbonate; chemical reactions; experimental studies; pH; pollutants; pollution; remediation; water quality SAPS mine water RAPS |
| Abstract |
Constructed wetland treatment system effectiveness has been limited by the alkalinity-producing, or acidity-neutralizing, capabilities of systems. Anoxic limestone drains (ALD's) have allowed for the treatment of approximately 300 mg/L net acidic mine drainage, but current design guidance precludes using successive ALD's to generate alkalinity in excess of 300 mg/L because of concerns with dissolved oxygen. “Compost” wetlands designed to promote bacterially mediated sulfate reduction are suggested as a means of generating alkalinity required in excess of that produced by ALD's. Compost wetlands create two basic needs of sulfate reducing bacteria; anoxic conditions resulting from the inherent oxygen demand of the organic substrate, and quasi-circumneutral pH values resulting from the dissolution of the carbonate fraction of the compost. However, sulfate reduction treatment area needs are generally in excess of area availability and/or cost effectiveness. Second generation alkalinity-producing systems demonstrate that a combination of existing treatment mechanisms has the potential to overcome current design concerns and effectively treat acidic waters ad infinitum. Successive alkalinity-producing systems (SAPS) combine ALD technology with sulfate reduction mechanisms. SAPS promote vertical flow through rich organic wetland substrates into limestone beds beneath the organic compost, discharging the pore waters. SAPS allow for conservative wetland treatment sizing calculations to be made as a rate function based on pH and alkalinity values and associated contaminant loadings. SAPS potentially decrease treatment area requirements and have the further potential to generate alkalinity in excess of acidity regardless od acidity concentrations. |
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Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage; Cn, Kj, Aj; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9722.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9722 |
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55 |
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| Author |
Laine, D.M.; Jarvis, A.P. |
| Title |
Engineering design aspects of passive in situ remediation of mining effluents |
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Journal Article |
| Year |
2003 |
Publication |
Land Contam. Reclam. |
Abbreviated Journal |
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11 |
Issue |
2 |
Pages |
113-126 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive waste management pyrite iron sulfide remediation mine drainage effluent |
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Passive treatment of contaminated effluents can offer a 'low cost' management opportunity to remediate drainages to the standards required by enforcement agencies. However, the initial cost of construction of passive treatment systems is significant and often in excess of that for active treatment systems. It is therefore important that the engineering design of the passive systems produces an effective and efficient scheme to enable the construction and maintenance costs to be minimised as far as possible. Possible parameters for the design of passive systems are suggested to seek to obtain uniformity in size and layout of treatment elements where this may be possible. Passive treatment systems include aeration systems, sedimentation ponds, aerobic and anaerobic wetlands, anoxic limestone drains and reducing alkalinity producing systems. Most active treatment systems also include passive elements in the treatment stream. The basic design considerations that should be considered to ensure the construction of efficient systems are discussed. |
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D.M. Laine, IMC Consulting Engineers, PO Box 18, Sutton-in-Ashfield NG17 2NS, United Kingdom |
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0967-0513 |
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Engineering design aspects of passive in situ remediation of mining effluents; 2530416; United-Kingdom 22; Geobase |
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no |
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CBU @ c.wolke @ 17523 |
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60 |
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| Author |
Smyth, D.; Blowes, D.; Ptacek, C.; Bain, J. |
| Title |
Application of permeable reactive barriers for treating mine drainage and dissolved metals in groundwater |
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Journal Article |
| Year |
2004 |
Publication |
Geotechnical News |
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| Volume |
22 |
Issue |
1 |
Pages |
39-44 |
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acid mine drainage; acid rock drainage; aquifers; Canada; Cochrane District Ontario; concentration; disposal barriers; Eastern Canada; ground water; Kidd Creek; mine drainage; mines; Ontario; oxidation; permeability; permeable reactive barrier; pollutants; pollution; remediation; sulfates; sulfides; tailings; testing; Timmins Ontario; waste disposal; waste management; waste rock; waste water; water treatment 22, Environmental geology |
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0823-650x |
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Application of permeable reactive barriers for treating mine drainage and dissolved metals in groundwater; 2006-058196; References: 20; sects. Canada (CAN); GeoRef; English |
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CBU @ c.wolke @ 5457 |
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66 |
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Benner, S.G.; Blowes, D.W.; Ptacek, C.J. |
| Title |
A full-scale porous reactive wall for prevention of acid mine drainage |
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Journal Article |
| Year |
1997 |
Publication |
Ground Water Monitoring and Remediation |
Abbreviated Journal |
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| Volume |
17 |
Issue |
4 |
Pages |
99-107 |
| Keywords |
acid mine drainage alkalinity bacteria Canada case studies concentration dissolved materials drainage Eastern Canada ground water mines observation wells Ontario permeability pH pollution porous materials recharge reduction remediation site exploration Sudbury District Ontario sulfate ion surface water waste disposal water pollution Groundwater quality Groundwater problems and environmental effects Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 11) geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) groundwater protection permeable barrier acid mine drainage aquifer groundwater acid min drainage contamination permeable barrier groundwater protection permeable barrier acid mine drainage aquifer Canada, Ontario, Sudbury, Nickel Rim |
| Abstract |
The generation and release of acidic drainage containing high concentrations of dissolved metals from decommissioned mine wastes is an environmental problem of international scale. A potential solution to many acid drainage problem is the installation of permeable reactive walls into aquifers affected by drainage water derived from mine waste materials. A permeable reactive wall installed into an aquifer impacted by low-quality mine drainage waters was installed in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The reactive mixture, containing organic matter, was designed to promote bacterially mediated sulfate reduction and subsequent metal sulfide precipitation. The reactive wall is installed to an average depth of 12 feet (3.6 m) and is 49 feet (15 m) long perpendicular to ground water flow. The wall thickness (flow path length) is 13 feet (4 m). Initial results, collected nine months after installation, indicate that sulfate reduction and metal sulfide precipitation is occurring. Comparing water entering the wall to treated water existing the wall, sulfate concentrations decrease from 2400 to 4600 mg/L to 200 to 3600 mg/L; Fe concentration decrease from 250 to 1300 mg/L to 1.0 to 40 mg/L, pH increases from 5.8 to 7.0; and alkalinity (as CaCO<inf>3</inf>) increases from 0 to 50 mg/L to 600 to 2000 mg/L. The reactive wall has effectively removed the capacity of the ground water to generate acidity on discharge to the surface. Calculations based on comparison to previously run laboratory column experiments indicate that the reactive wall has potential to remain effective for at least 15 years. |
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Dr. S.G. Benner, Earth Sciences Department, University of Waterloo, Waterloo, Ont. N2L 3G1, Canada |
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1069-3629 |
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Review; A full-scale porous reactive wall for prevention of acid mine drainage; 0337197; United-States 46; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10621.pdf; Geobase |
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CBU @ c.wolke @ 17555 |
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67 |
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