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Author |
Juby, G.J.G. |
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Title |
Desalination of calcium sulphate scaling mine water: Design and operation of the SPARRO process |
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Journal Article |
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Year |
1996 |
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Water Sa |
Abbreviated Journal |
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22 |
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2 |
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161-172 |
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Keywords |
mine water treatment |
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Abstract |
The South African mining industry discharges relatively small quantities of mine service water to the environment, but these effluents contribute substantially to the salt load of the receiving waters. The poor quality of service water also has significant cost implications on the mining operations. Of the two main types of mine service water encountered in the gold mining industry, the so-called calcium sulphate scaling types is found in the majority of cases. Preliminary testwork on this type of water using membrane desalination processes revealed that only the seeded reverse osmosis type of process showed promise. To overcome certain process problems and high operating costs with this system, a novel membrane desalination technique incorporating seeded technology, called the SPARRO (slurry precipitation and recycle reverse osmosis) process, was developed. The novel features of the new process included; a lower linear slurry velocity in the membrane tubes, a lower seed slurry concentration, a dual pumping arrangement to a tapered membrane stack, a smaller reactor and a modified seed crystal and brine blow-down system. Evaluation of the SPARRO process and its novel features, over a five-year period, confirmed its technical viability for desalinating calcium sulphate-scaling mine water. The electrical power consumption of the process was approximately half that of previous designs, significantly improving its efficiency. Membrane performance was evaluated and was generally unsatisfactory with both fouling and hydrolysis dominating at times, although operating conditions for the membranes were not always ideal. The precise cause(s) for the membrane degradation was not established, but a mechanism for fouling (based upon the presence of turbidity in the mine water) and a hypothesis fora possible cause of hydrolysis (alluding to the presence of radionuclides in the mine water) were proposed. Product water from the SPARRO process has an estimated gross unit cost (including capital costs) of 383 c/m(3) (1994). |
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Desalination of calcium sulphate scaling mine water: Design and operation of the SPARRO process; Wos:A1996uh88100009; Times Cited: 5; ISI Web of Science |
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CBU @ c.wolke @ 17168 |
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86 |
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Banks, D.; Younger, P.L.; Arnesen, R.-T.; Iversen, E.R.; Banks, S.B. |
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Title |
Mine-water chemistry: The good, the bad and the ugly |
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Journal Article |
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1997 |
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Environ. Geol. |
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32 |
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3 |
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157-174 |
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Keywords |
mine water treatment mine-water chemistry acid mine drainage mine-water pollution mine-water treatment county-durham drainage movements Pollution and waste management non radioactive Groundwater problems and environmental effects mine drainage contamination hydrogeochemistry mine water drainage acid mine drainage |
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Contaminative mine drainage waters have become one of the major hydrogeological and geochemical problems arising from mankind's intrusion into the geosphere. Mine drainage waters in Scandinavia and the United Kingdom are of three main types: (1) saline formation waters; (2) acidic, heavy-metal-containing, sulphate waters derived from pyrite oxidation, and (3) alkaline, hydrogen-sulphide-containing, heavy-metal-poor waters resulting from buffering reactions and/or sulphate reduction. Mine waters are not merely to be perceived as problems, they can be regarded as industrial or drinking water sources and have been used for sewage treatment, tanning and industrial metals extraction. Mine-water problems may be addressed by isolating the contaminant source, by suppressing the reactions releasing contaminants, or by active or passive water treatment. Innovative treatment techniques such as galvanic suppression, application of bactericides, neutralising or reducing agents (pulverised fly ash-based grouts, cattle manure, whey, brewers' yeast) require further research. |
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D. Banks, Norges Geologiske Undersokelse, Postboks 3006 – Lade, N-7002 Trondheim, Norway |
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0943-0105 |
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Oct.; Mine-water chemistry: The good, the bad and the ugly; 0337169; Germany 78; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10620.pdf; Geobase |
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CBU @ c.wolke @ 10620 |
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18 |
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Van Hille, R.P.; Boshoff, G.A.; Rose, P.D.; Duncan, J.R. |
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A continuous process for the biological treatment of heavy metal contaminated acid mine water |
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Journal Article |
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1999 |
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Resour. Conserv. Recycl. |
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27 |
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1-2 |
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157-167 |
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mine water treatment biological treatment heavy metal acid mine water alkaline precipitation green-algae chlorella |
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Alkaline precipitation of heavy metals from acidic water streams is a popular and long standing treatment process. While this process is efficient it requires the continuous addition of an alkaline material, such as lime. In the long term or when treating large volumes of effluent this process becomes expensive, with costs in the mining sector routinely exceeding millions of rands annually. The process described below utilises alkalinity generated by the alga Spirulina sp., in a continuous system to precipitate heavy metals. The design of the system separates the algal component from the metal containing stream to overcome metal toxicity. The primary treatment process consistently removed over 99% of the iron (98.9 mg/l) and between 80 and 95% of the zinc (7.16 mg/l) and lead (2.35 mg/l) over a 14-day period (20 l effluent treated). In addition the pH of the raw effluent was increased from 1.8 to over 7 in the post-treatment stream. Secondary treatment and polishing steps depend on the nature of the effluent treated. In the case of the high sulphate effluent the treated stream was passed into an anaerobic digester at a rate of 4 l/day. The combination of the primary and secondary treatments effected a removal of over 95% of all metals tested for as well as a 90% reduction in the sulphate load. The running cost of such a process would be low as the salinity and nutrient requirements for the algal culture could be provided by using tannery effluent or a combination of saline water and sewage. This would have the additional benefit of treating either a tannery or sewage effluent as part of an integrated process. |
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0921-3449 |
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Jul; A continuous process for the biological treatment of heavy metal contaminated acid mine water; Isi:000081142100017; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9937.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9937 |
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26 |
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Benkovics, I.; Csicsák, J.; Csövári, M.; Lendvai, Z.; Molnár, J. |
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Title |
Mine Water Treatment – Anion-exchange and Membrane Process |
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Journal Article |
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1997 |
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Proceedings, 6th International Mine Water Association Congress, Bled, Slovenia |
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1 |
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149-157 |
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Keywords |
uranium mining Hungary Mecsek Ore Mining Company waste water mine water chemistry nano-filtration reverse osmosis pilot plant mine water treatment treatment |
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Mine Water Treatment – Anion-exchange and Membrane Process; 1; FG 6 Abb., 2 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9530 |
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455 |
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Wiseman, I.M.; Rutt, G.P.; Edwards, P.J. |
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Title |
Constructed wetlands for minewater treatment: Environmental benefits and ecological recovery |
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2004 |
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Water and Environment Journal |
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18 |
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3 |
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133-138 |
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mine water treatment |
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The ecology of the River Pelenna (in South Wales) was impoverished by polluted discharges from abandoned coal mines. A series of passive constructed wetlands was created in order to treat these discharges and to improve the ecology of the river. A three-year Environment Agency R&D project investigated the performance, environmental benefits and sustainability of the constructed wetlands. It showed that the treatment systems were removing most of the iron contamination. In the reaches downstream from the minewaters, the dissolved-iron concentration quickly dropped below the target level. Invertebrate abundance, trout and riverine bird populations increased in following years. However, occasional overflows from the systems have significantly affected the ecology of one stretch of river The research work has provided an insight into the potential for ecological recovery associated with future minewater treatment. |
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1747-6585 |
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Aug.; Constructed wetlands for minewater treatment: Environmental benefits and ecological recovery; Wos:000230520000002; Times Cited: 0; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7891.pdf; ISI Web of Science |
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CBU @ c.wolke @ 7891 |
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68 |
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