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Goulet, R. R. (2001). Changes in dissolved and total Fe and Mn in a young constructed wetland: Implications for retention performance. Ecological Engineering, 17(4), 373–384.
Abstract: Surface-flow wetlands are generally considered sinks for Fe and Mn but they may also export and affect the partitioning of these metals. This study was undertaken to evaluate the effect of a young constructed wetland on the retention and transformation of both dissolved and particulate Fe and Mn. Duplicate water samples were collected every three days at the inlet and outlet structures of the Monahan Wetland, Kanata, Ontario, from spring of 1997 to 1999. While on a yearly basis the wetland showed significant retention of che dissolved phase, the retention of total Fe and Mn was poor. There were strong seasonal differences in retention and, during the winter, the wetland was a source. The wetland transformed dissolved into particulate Fe and Mn from spring to fall whereas during the winter, dissolved Fe and Mn were released. Changes in pH, alkalinity and temperature could explain 11% and 40% of the outlet variation in the ratio of dissolved to total Fe and Mn respectively. Furthermore, from spring to late summer, planktonic algal biomass was negatively related to the ratio of dissolved to total Fe and Mn implying a role in Fe and Mn transformations in young wetlands where emergent and submerged vegetation have yet to dominate the system. (C) 2001 Elsevier Science B.V. All rights reserved.
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Nakazawa, H. (2006). Treatment of acid mine drainage containing iron ions and arsenic for utilization of the sludge. Sohn International Symposium Advanced Processing of Metals and Materials, Vol 9, , 373–381.
Abstract: An acid mine drainage in abandoned Horobetsu mine in Hokkaido, Japan, contains arsenic and iron ions; total arsenic ca.10ppm, As(III) ca. 8.5ppm, total iron 379ppm, ferrous iron 266ppm, pH1.8. Arsenic occurs mostly as arsenite (As (III)) or arsenate (As (V)) in natural water. As(III) is more difficult to be remove than As(V), and it is necessary to oxidize As(III) to As(V) for effective removal. 5mL of the mine drainage or its filtrate through the membrane filter (pore size 0.45 mu m) were added to arsenite solutions (pH1.8) with the concentration of 5ppm. After the incubation of 30 days, As(III) was oxidized completely with the addition of the mine drainage while the oxidation did not occur with the addition of filtrate, indicating the microbial oxidation of As(III). In this paper, we have investigated the microbial oxidation of As(III) in acid water below pH2.0.
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Ye, Z. H. (2004). Use of a wetland system for treating Pb/Zn mine effluent: A case study in southern China from 1984 to 2002. Wetlands Ecosystems in Asia: Function and Management, 1, 413–434.
Abstract: A constructed wetland system in Guangdong Province, South of China has been used for treating Pb/Zn mine discharge since 1984. In this chapter, the performance of this system in the purification of mine discharge, metal accumulation in different ecological compartments and ecological succession within the system during the period of 1984-2002 has been reviewed. The data show that the wetland system not only effectively remove metals (mainly Pb, Zn, Cd and Cu) and total suspended solids from the mine discharge over a long period leading to significant improvement in water quality, but also gradually increase diversity and abundance of living organisms.
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Groudev, S. N., Georgiev, P. S., Spasova, I. I., & Nicolova, M. N. (2000). In situ treatment of mine waters by means of a permeable barrier. Groundwater 2000, , 417–418.
Abstract: Acid ground waters contaminated with radioactive elements (U, Ra, Th), toxic heavy metals (Cu, Zn, Cd, Mn, Fe), arsenic and sulphates were treated by means of a permeable barrier. The barrier was filled with a mixture of biodegradable solid organic substrates (spent mushroom compost, sawdust and cow manure) and was inhabited by a mixed microbial community consisting of sulphate-reducing bacteria and other metabolically interdependent microorganisms. An efficient removal of the pollutants was achieved by this barrier during the different climatic seasons, even at ambient temperatures close to degrees C. The microbial dissimilatory sulphate reduction and the sorption of pollutants by the organic matter in the barrier were the main processes involved in this removal.
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Gobla, M. J. (2002). A rapid response to cleanup – Gilt Edge Superfund Site, South Dakota. Tailings and Mine Waste '02, , 421–425.
Abstract: The Gilt Edge gold mine is an acid drainage site that has been put on an accelerated closure schedule. The mine ceased activities in 1999 when Dakota Mining Corporation declared bankruptcy forcing the State of South Dakota to immediatly assume water treatment operations. Evaluation of conceptual closure plan options and cost estimates led the State of South Dakota to a decision to seek Federal assistance. The site has quickly moved into reclamation mode for the principal contamination source, the Ruby waste-rock dump. Designs and specifications for capping the Ruby waste-rock dump were prepared while Superfund listing was pursued. In October of 2000, mobilization of the first reclamation contractor began and by December the site was added to the National Priorities List. Capping the waste-rock dump will address a major acid drainage source. Water treatment requirements are expected to decline as conventional methods such as diverting clean water, backfilling, grading, capping, limestone neutralization, and revegetation are implemented. Acid seepage from underground workings, steep highwalls, and some pit backfills will remain. Major field trials of emerging technologies are nearing completion and some are showing promising results. Carbon reduction in a pit lake, and pyrite microencapsulation on simulated waste dumps, are showing initial success. Their application may minimize or eliminate the need for long-term active water treatment which has been a long sought goal for major acid rock drainage sites.
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