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Foucher, S.; Battaglia-Brunet, F.; Ignatiadis, I.; Morin, D. |
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Title |
Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery |
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Journal Article |
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Year |
2001 |
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Chemical Engineering Science |
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56 |
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4 |
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1639-1645 |
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Acid mine drainage Sulfate-reducing bacteria Sulfide precipitation Hydrogen transfer Fixed bed column reactor |
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Abstract |
Acid-mine drainage can contain high concentrations of heavy metals and release of these contaminants into the environment is generally avoided by lime neutralization. However, this classical treatment is expensive and generates large amounts of residual sludge. The selective precipitation of metals using H2S produced biologically by sulfate-reducing bacteria has been proposed as an alternative process. Here, we report on experiments using real effluent from the disused Chessy-les-Mines mine-site at the laboratory pilot scale. A fixed-bed bioreactor, fed with an H2/CO2 mixture, was used in conjunction with a gas stripping column. The maximum rate of hydrogen transfer in the bioreactor was determined before inoculation. kLa was deduced from measurements of O2 using Higbie and Danckwert's models which predict a dependence on diffusivity. The dynamic method of physical absorption and desorption was used. The maximum rate of H2 transfer suggests that this step should not be a limiting factor. However, an increase in H2 flow rate was observed to induce an increase in sulfate reduction rate. For the precipitation step, the gas mixture from the bioreactor was bubbled into a stirred reactor fed with the real effluent. Cu and Zn could be selectively recovered at pH=2.8 and pH=3.5, respectively. Other impurities such as Ni and Fe could also be removed at pH=6 by sulfide precipitation. Part of the outlet stream from the bioreactor was used to regulate and maintain the pH during sulfide precipitation by feeding the outlet stream back into the bioreactor. The replacement of synthetic medium with real effluent had a positive effect on sulfate reduction rate which increased by 30-40%. This improvement in bacterial efficiency may be related to the large range of oligo-elements provided by the mine-water. The maximum sulfate reduction rate observed with the real effluent was 200 mgl-1 h-1, corresponding to a residence time of 0.9 day. A preliminary cost estimation based on a treatment rate of 5 m3 h-1 of a mine effluent containing 5 gl-1 SO42- is presented. |
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0009-2509 |
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Feb.; Treatment by sulfate-reducing bacteria of Chessy acid-mine drainage and metals recovery; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10064.pdf; Science Direct |
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CBU @ c.wolke @ 10064 |
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54 |
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Barton, C.D.; Karathanasis, A.D. |
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Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
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Book Chapter |
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Year |
1997 |
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AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
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1545 |
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acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
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The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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AAPG Bulletin |
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Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
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CBU @ c.wolke @ 16630 |
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70 |
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Mohan, D.; Chander, S. |
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Removal and recovery of metal ions from acid mine drainage using lignite-A low cost sorbent |
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2006 |
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J. Hazard. Mater. |
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137 |
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3 |
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1545-1553 |
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Geobase: Related Topics geobase: related topics (901) acid mine drainage adsorption ion iron sulfide lignite wastewater water treatment |
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Acid mine drainage (AMD), has long been a significant environmental problem resulting from the microbial oxidation of iron pyrite in presence of water and air, affording an acidic solution that contains toxic metal ions. The main objective of this study was to remove and recover metal ions from acid mine drainage (AMD) by using lignite, a low cost sorbent. Lignite has been characterized and used for the AMD treatment. Sorption of ferrous, ferric, manganese, zinc and calcium in multi-component aqueous systems was investigated. Studies were performed at different pH to find optimum pH. To simulate industrial conditions for acid mine wastewater treatment, all the studies were performed using single and multi-columns setup in down flow mode. The empty bed contact time (EBCT) model was used for minimizing the sorbent usage. Recovery of the metal ions as well as regeneration of sorbent was achieved successfully using 0.1 M nitric acid without dismantling the columns. < copyright > 2006 Elsevier B.V. All rights reserved. |
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D. Mohan, Department of Energy and Geo-Environmental Engineering, The Pennsylvania State University, University Park, PA 16802, United States dm_1967@hotmail.com |
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0304-3894 |
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Oct 11; Removal and recovery of metal ions from acid mine drainage using lignite-A low cost sorbent; 2919875; Netherlands 56; Geobase |
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CBU @ c.wolke @ 17634 |
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295 |
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Tsukamoto, T.K.; Miller, G.C. |
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Title |
Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage |
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Journal Article |
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Year |
1999 |
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Water Res. |
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33 |
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6 |
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1365-1370 |
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mine water treatment mining activity sulfate-reducing bacteria microbial activity acid mine drainage methanol passive treatment systems sulfate-reducing bacterium sp-nov |
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Sulfate reducing passive bioreactors are increasingly being used to remove metals and raise the pH of acidic waste streams from abandoned mines. These systems commonly use a variety of organic substrates (i.e. manure, wood chips) for sulfate reduction. The effectiveness of these systems decreases as easily accessible reducing equivalents are consumed in the substrate through microbial activity. Using column studies at room temperature (23-26 degrees C), we investigated the addition of lactate and methanol to a depleted manure substrate as a method to reactivate a bioreactor that had lost >95% of sulfate reduction activity. A preliminary experiment compared sulfate removal in gravity fed, flow through bioreactors in which similar masses of each substrate were added to the influent solution. Addition of 148 mg/l lactate resulted in a 69% reduction in sulfate concentration from 300 to 92 mg/l, while addition of 144 mg/l methanol resulted in an 88% reduction in sulfate concentration from 300 to 36 mg/l. Because methanol was found to be an effective sulfate reducing substrate, it was chosen for further experiments due to its inherent physical properties (cost, low freezing point and low viscosity liquid) that make it a superior substrate for remote, high elevation sites where freezing temperatures would hamper the use of aqueous solutions. In these column studies, water containing sulfate and ferrous iron was gravity-fed through the bioreactor columns, along with predetermined methanol concentrations containing reducing equivalents to remove 54% of the sulfate. Following an acclimation period for the columns, sulfate concentrations were reduced from of 900 mg/l in the influent to 454 mg/l in the effluent, that reflects a 93% efficiency of electrons from the donor to the terminal electron acceptor. Iron concentrations were reduced from 100 to 2 mg/l and the pH increased nearly 2 units. (C) 1999 Elsevier Science Ltd. |
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0043-1354 |
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Apr; Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage; Isi:000079485400004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10197.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 10197 |
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50 |
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Akcil, A.; Koldas, S. |
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Acid Mine Drainage (AMD): causes, treatment and case studies |
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2006 |
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J. Cleaner Prod. |
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14 |
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12-13 |
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1139-1145 |
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contamination effluents government industrial pollution industrial waste mining industry research initiatives wastewater treatment acid mine drainage environmental problems mining industry government research initiatives contamination civil engineering mining quarrying activity environmental impact acid generating process acid drainage migration prevention measures effluent treatment chemical treatment biological treatment Manufacturing and Production Entwässern=Gelände Umweltbelastung Bauingenieurwesen Bergbau Sickerwasser Steinbruch Säureproduktion Neutralisation Bergbauindustrie technische Forschung Ingenieurswissenschaft Steinbruchabbau Acid Mine Drainage Mining Environmental Chemical and biological treatment |
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This paper describes Acid Mine Drainage (AMD) generation and its associated technical issues. As AMD is recognized as one of the more serious environmental problems in the mining industry, its causes, prediction and treatment have become the focus of a number of research initiatives commissioned by governments, the mining industry, universities and research establishments, with additional inputs from the general public and environmental groups. In industry, contamination from AMD is associated with construction, civil engineering mining and quarrying activities. Its environmental impact, however, can be minimized at three basic levels: through primary prevention of the acid-generating process; secondary control, which involves deployment of acid drainage migration prevention measures; and tertiary control, or the collection and treatment of effluent. |
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0959-6526 |
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Acid Mine Drainage (AMD): causes, treatment and case studies; Science Direct |
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CBU @ c.wolke @ 17462 |
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36 |
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