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Author Wingenfelder, U.; Hansen, C.; Furrer, G.; Schulin, R.
Title Removal of heavy metals from mine waters by natural zeolites Type Journal Article
Year 2005 Publication Environ Sci Technol, ES & T Abbreviated Journal
Volume 39 Issue 12 Pages (down) 4606-4613
Keywords Groundwater problems and environmental effects Pollution and waste management non radioactive remediation heavy metal mine drainage acid mine drainage; acidification; Central Europe; chemical composition; chemical fractionation; dissolved materials; Europe; framework silicates; geochemistry; grain size; heavy metals; hydrochemistry; ion exchange; lead; metals; mines; mining; mobilization; models; pH; pollutants; pollution; precipitation; remediation; samples; silicates; spectra; Switzerland; toxic materials; X-ray diffraction data; X-ray fluorescence spectra; zeolite group
Abstract
Address G. Furrer, Institute of Terrestrial Ecology, Swiss Federal Institute of Technology, Zurich, Grabenstrasse 3, CH-8952 Schlieren, Switzerland gerhard.furrer@env.ethz.ch
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ISSN 0013-936x ISBN Medium
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Notes Removal of heavy metals from mine waters by natural zeolites; 2006-086777; References: 42; illus. incl. 3 tables United States (USA); GeoRef; English Approved no
Call Number CBU @ c.wolke @ 5382 Serial 71
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Author McLeod, K.W.; Ciravolo, T.G.
Title Sensitivity of water tupelo (Nyssa aquatica) and bald cypress (Taxodium distichum) seedlings to manganese enrichment under water-saturated conditions Type Journal Article
Year 2003 Publication Environmental Toxicology and Chemistry Abbreviated Journal
Volume 22 Issue 12 Pages (down) 2948-2951
Keywords Heavy metals ecological abstracts: pollution (73 7 3) seedling saturated medium biomass manganese sensitivity analysis bioaccumulation Nyssa aquatica Taxodium distichum
Abstract In anaerobic soils of wetlands, Mn is highly available to plants because of the decreasing redox potential and pH of flooded soil. When growing adjacent to each another in wetland forests, water tupelo (Nyssa aquatica L.) had 10 times greater leaf manganese concentration than bald cypress (Taxodium distichum [L.] Richard). This interspecific difference was examined over a range of manganese-enriched soil conditions in a greenhouse experiment. Water tupelo and bald cypress seedlings were grown in fertilized potting soil enriched with 0, 40, 80, 160, 240, 320, and 400 mg Mn/L of soil and kept at saturated to slightly flooded conditions. Leaf Mn concentration was greater in water tupelo than bald cypress for all but the highest Mn addition treatment. Growth of water tupelo seedlings was adversely affected in treatments greater than 160 mg Mn/L. Total biomass of water tupelo in the highest Mn treatment was less than 50% of the control. At low levels of added Mn, bald cypress was able to restrict uptake of Mn at the roots with resulting low leaf Mn concentrations. Once that root restriction was exceeded, Mn concentration in bald cypress leaves increased greatly with treatment; that is, the highest treatment was 40 times greater than control (4,603 vs 100 < mu >g/g, respectively), but biomass of bald cypress was unaffected by manganese additions. Bald cypress, a tree that does not naturally accumulate manganese, does so under manganese-enriched conditions and without biomass reduction in contrast to water tupelo, which is severely affected by higher soil Mn concentrations. Thus, bald cypress would be less affected by increased manganese availability in swamps receiving acidic inputs such as acid mine drainage, acid rain, or oxidization of pyritic soils.
Address K.W. McLeod, Savannah River Ecology Laboratory, University of Georgia, P.O. Drawer E, Aiken, SC 29802, United States mcleod@srel.edu
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ISSN 0730-7268 ISBN Medium
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Notes Sensitivity of water tupelo (Nyssa aquatica) and bald cypress (Taxodium distichum) seedlings to manganese enrichment under water-saturated conditions; 2574798; United-States 15; Geobase Approved no
Call Number CBU @ c.wolke @ 16010 Serial 302
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Author Wolkersdorfer, C.
Title Type Book Whole
Year 2006 Publication Abbreviated Journal
Volume Issue Pages (down) 2490-2501 [Cd-Rom]
Keywords mine water flooded shaft underground mining mine water pollution
Abstract Acid mine drainage, the drainage of metals, and the prediction of mine water rebound after mine closure are major problems for the mining industry. In the literature, the difficulties in evaluating the hydrodynamics of flooded mines are well described, although only a few tracer tests in flooded mines have been published. Increased knowledge about the hydraulic behaviour of the mine water within a flooded mine might significantly reduce the costs of mine closure and remediation. Relatively cheap and reliable results for decision making can be obtained when tracer tests are properly conducted in a flooded mine prior to planning of remediation strategies or numerical simulations. Applying the results of successful tracer tests allows one to optimise remediation designs and thereby diminish the costs of remediation. The paper summarises the results of several tracer tests and draws general conclusions from such tests.
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Publisher Proceedings, International Conference of Acid Rock Drainage (ICARD) Place of Publication 7 Editor
Language Summary Language Original Title
Series Editor Series Title Icard 2006 Abbreviated Series Title
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ISSN ISBN Medium
Area Expedition Conference
Notes Acid Mine Drainage Tracer Tests; 2; AMD ISI | Wolkersdorfer; 5 Abb. Approved no
Call Number CBU @ c.wolke @ 17446 Serial 203
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Author Conca, J.L.; Wright, J.
Title An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd Type Journal Article
Year 2006 Publication Appl. Geochem. Abbreviated Journal
Volume 21 Issue 12 Pages (down) 2188-2200
Keywords Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry
Abstract Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed).
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ISSN 0883-2927 ISBN Medium
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Notes Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct Approved no
Call Number CBU @ c.wolke @ 17248 Serial 44
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Author Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W.
Title Evaluation of in situ layers for treatment of acid mine drainage: A field comparison Type Journal Article
Year 2006 Publication Water Res Abbreviated Journal
Volume 40 Issue 9 Pages (down) 1816-1826
Keywords mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment
Abstract Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell.
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ISSN 0043-1354 ISBN Medium
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Notes May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 10040 Serial 49
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