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Author Jarvis, A.P.; Younger, P.L.
Title Passive treatment of ferruginous mine waters using high surface area media Type Journal Article
Year 2001 Publication Water Res. Abbreviated Journal
Volume 35 Issue 15 Pages (down) 3643-3648
Keywords mine water treatment passive treatment mine water accretion oxidation iron manganese water treatment
Abstract Rapid oxidation and accretion of iron onto high surface area media has been investigated as a potential passive treatment option for ferruginous, net-alkaline minewaters. Two pilot-scale reactors were installed at a site in County Durham, UK. Each 2.0m high cylinder contained different high surface area plastic trickling filter media. Ferruginous minewater was fed downwards over the media at various flow-rates with the objective of establishing the efficiency of iron removal at different loading rates. Residence time of water within the reactors was between 70 and 360s depending on the flow-rate (1 and 12l/min, respectively). Average influent total iron concentration for the duration of these experiments was 1.43mg/l (range 1.08-1.84mg/l; n=16), whilst effluent iron concentrations averaged 0.41mg/l (range 0.20-1.04mg/l; n=15) for Reactor A and 0.38mg/l (range 0.11-0.93mg/l; n=16) for Reactor B. There is a strong correlation between influent iron load and iron removal rate. Even at the highest loading rates (approximately 31.6g/day) 43% and 49% of the total iron load was removed in Reactors A and B, respectively. At low manganese loading rates (approximately 0.50-0.90g/day) over 50% of the manganese was removed in Reactor B. Iron removal rate (g/m3/d) increases linearly with loading rate (g/day) up to 14g/d and the slope of the line indicates that a mean of 85% of the iron is removed. In conclusion, it appears that the oxidation and accretion of ochre on high surface area media may be a promising alternative passive technology to constructed wetlands at certain sites.
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Series Volume Series Issue Edition
ISSN 0043-1354 ISBN Medium
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Notes Oct; Passive treatment of ferruginous mine waters using high surface area media; 9; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9698.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 9698 Serial 27
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Author Hulshof, A.H.M.; Blowes, D.W.; Douglas Gould, W.
Title Evaluation of in situ layers for treatment of acid mine drainage: A field comparison Type Journal Article
Year 2006 Publication Water Res Abbreviated Journal
Volume 40 Issue 9 Pages (down) 1816-1826
Keywords mine water Pollution and waste management non radioactive Groundwater problems and environmental effects acid mine drainage organic carbon oxidation microbial activity drainage groundwater pollution Bacteria microorganisms Contamination Groundwater Barriers Drainage Treatment
Abstract Reactive treatment layers, containing labile organic carbon, were evaluated to determine their ability to promote sulfate reduction and metal sulfide precipitation within a tailings impoundment, thereby treating tailings effluent prior to discharge. Organic carbon materials, including woodchips and pulp waste, were mixed with the upper meter of tailings in two separate test cells, a third control cell contained only tailings. In the woodchip cell sulfate reduction rates were 500 mg L-1 a-1, (5.2 mmol L-1 a-1) this was coupled with the gradual removal of 350 mg L-1 Zn (5.4 mmol L-1). Decreased δ13CDIC values from -3‰ to as low as -12‰ indicated that sulfate reduction was coupled with organic carbon oxidation. In the pulp waste cell the most dramatic change was observed near the interface between the pulp waste amended tailings and the underlying undisturbed tailings. Sulfate reduction rates were 5000 mg L-1 a-1 (52 mmol L-1 a-1), Fe concentrations decreased by 80–99.5% (148 mmol L-1) and Zn was consistently <5 mg L-1. Rates of sulfate reduction and metal removal decreased as the pore water migrated upward into the shallower tailings. Increased rates of sulfate reduction in the pulp waste cell were consistent with decreased δ13CDIC values, to as low as -22‰, and increased populations of sulfate reducing bacteria. Lower concentrations of the nutrients, phosphorus, organic carbon and nitrogen in the woodchip material contribute to the lower sulfate reduction rates observed in the woodchip cell.
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ISSN 0043-1354 ISBN Medium
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Notes May; Evaluation of in situ layers for treatment of acid mine drainage: A field comparison; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10040.pdf; Science Direct Approved no
Call Number CBU @ c.wolke @ 10040 Serial 49
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Author Burgess, J.E.; Stuetz, R.M.
Title Activated Sludge for the Treatment of Sulphur-rich Wastewaters Type Journal Article
Year 2002 Publication Miner. Eng. Abbreviated Journal
Volume 15 Issue 11 Pages (down) 839-846
Keywords acid rock drainage biooxidation biotechnology environmental waste processing acid-mine drainage sulfate-reducing bacteria biological treatment waste-water metals acclimation remediation oxidation reduction removal
Abstract The aim of this investigation was to assess the potential of activated sludge for the remediation of sulphur-rich wastewaters. A pilot-scale activated sludge plant was acclimatised to a low load of sulphide and operated as a flow-through unit. Additional sludge samples from different full-scale plants were compared with the acclimatised and unacclimatised sludges using batch absorption tests. The effects of sludge source and acclimatisation on the ability of the sludge to biodegrade high loads of sulphide were evaluated. Acclimatisation to low-sulphide concentrations enabled the sludge to degrade subsequent high loads which were toxic to unacclimatised sludge. Acclimatisation was seen to be an effect of selection pressure on the biomass, suggesting that the treatment capability of activated sludge will develop after acclimation, indicating potential for treatment of acid mine drainage (AMD) by a standard wastewater treatment process. Existing options for biological treatment of AMD are described and the potential of activated sludge treatment for AMD discussed in comparison with existing technologies. (C) 2002 Elsevier Science Ltd.
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ISSN 0892-6875 ISBN Medium
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Notes Nov.; Activated Sludge for the Treatment of Sulphur-rich Wastewaters; Isi:000179970500009; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10093.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 10093 Serial 40
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Author Kuyucak, N.
Title Type Book Whole
Year 1999 Publication Abbreviated Journal
Volume Issue Pages (down) 599-606
Keywords hydrogeology mining water acid mine drainage environment treatment control economy oxidation sulphide hydrochemistry
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Publisher International Mine Water Association Place of Publication Ii Editor Fernández Rubio, R.
Language Summary Language Original Title
Series Editor Series Title Mine, Water & Environment Abbreviated Series Title
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Notes Acid Mine Drainage Prevention and Control Options; 1; AMD ISI | Wolkersdorfer; FG 'de' 6 Abb., 1 Tab. Approved no
Call Number CBU @ c.wolke @ 17373 Serial 325
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Author Cravotta, C.A., III; Trahan, M.K.
Title Limestone drains to increase pH and remove dissolved metals from acidic mine drainage Type Journal Article
Year 1999 Publication Appl. Geochem. Abbreviated Journal
Volume 14 Issue 5 Pages (down) 581-606
Keywords manganese oxide redox processes sulfate waters iron-oxides adsorption ions oxidation surfaces environments aluminum
Abstract Despite encrustation by Fe and Al hydroxides, limestone can be effective for remediation of acidic mine drainage (AMD). Samples of water and limestone (CaCO3) were collected periodically for 1 a at 3 identical limestone-filled drains in Pennsylvania to evaluate the attenuation of dissolved metals and the effects of pH and Fe- and Al-hydrolysis products on the rate of CaCO3 dissolution. The influent was acidic and relatively dilute (pH < 4; acidity < 90 mg) but contained 1-4 mg . L-1 of O-2, Fe3+, Al3+ and Mn2+. The total retention time in the oxic limestone drains (OLDs) ranged from 1.0 to 3.1 hr. Effluent remained oxic (O-2 > 1 mg . L-1) but was near neutral (pH = 6.2-7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs, The hydrous oxides, nominally Fe(OH)(3) and Al(OH)(3), were visible as loosely bound, orange-yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)(3) and Al(OH)(3) particles were transported downflow. The accumulation of hydrous oxides and elevated pH (> 5) in the downflow part of the OLDs promoted sorption and coprecipitation of dissolved Mn, Cu, Co, Ni and Zn as indicated by decreased concentrations of the metals in effluent and their enrichment relative to Fe in hydrous-oxide particles and coatings on limestone. Despite thick (similar to 1 mm) hydrous-oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within and the OLD where the limestone was not coated. The high rates of CaCO3 dissolution and Fe(OH3) precipitation were associated with the relatively low pH and high Fe3+ concentration near the inflow. The rate of CaCO3 dissolution decreased with increased pH and concentrations of Ca2+ and HCO3- and decreased Pco(2). Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two-stagetreatment system consisting of an anoxic limestone drain and oxidation-settling pond or wetland. To facilitate removal of hydrous-oxide sludge, a perforated-pipe subdrain can be installed within an OLD. (C) 1999 Elsevier Science Ltd.
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Series Volume Series Issue Edition
ISSN 0883-2927 ISBN Medium
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Notes Jul; Limestone drains to increase pH and remove dissolved metals from acidic mine drainage; Isi:000080043300004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10102.pdf; AMD ISI | Wolkersdorfer Approved no
Call Number CBU @ c.wolke @ 17470 Serial 22
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