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Author Mustikkamaki, U.-P.
Title Metallipitoisten vesien biologisesta kasittelysta Outokummun kaivoksilla. Metal content treated with biological methods at the Outokummun operation Type Journal Article
Year 2000 Publication Vuoriteollisuus = Bergshanteringen Abbreviated Journal
Volume 58 Issue 1 Pages 44-47
Keywords acid mine drainage anaerobic environment bacteria biodegradation environmental analysis Europe filters Finland metals Outokummun Mine peat pollutants pollution reduction Scandinavia sediments sulfate ion Western Europe zinc 22, Environmental geology
Abstract Acid mine drainage (AMD) is one of the most serious environmental problems in the metal-mining industry. AMD is formed by the chemical and bacterial oxidation of sulphide minerals, and it is characterized by low pH values and high sulphate and metals content. The most common method to treat AMD is chemical neutralization. The chemical treatment requires high capital and operating costs and its use is problematic at the closed mines sites. Outokumpu has studied and used sulphate reducing bacteria (SRB) as an alternative method for the treatment of AMD. SRB existing in many natural anaerobic aqueous environments can reduce sulphate to sulphide which precipitates metals as extremely insoluble metal sulphides. Full scale experiments were begun in summer 1995 in the Ruostesuo open pit (depth 46 m) by adding liquid manure as a source of bacteria and press-juice as a growth substrate. The average Zn content of the whole column has decreased from 3,5 mg/l to 0,8 mg/l and below 25 m zinc is 0 mg/l. Similar results have been reached with nickel in the Kotalahti old nickel mine, where bacteria were brought in 1996. We have found that the same bacterial mechanism acts in peat-limestone filters, which Outokumpu has built at several mine sites since 1993.
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ISSN 0042-9317 ISBN Medium
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Notes Metallipitoisten vesien biologisesta kasittelysta Outokummun kaivoksilla. Metal content treated with biological methods at the Outokummun operation; 2001-069868; illus. incl. 3 tables Finland (FIN); GeoRef; Finnish Approved no
Call Number CBU @ c.wolke @ 16560 Serial 291
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Author Sottnik, P.; Sucha, V.
Title Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica Type Journal Article
Year 2001 Publication Mineralia Slovaca Abbreviated Journal
Volume 33 Issue 1 Pages 53-60
Keywords acid mine drainage aluminum Banska Stiavnica Slovakia Central Europe copper Eh Europe gangue heavy metals iron manganese metals metamorphic rocks oxidation pH pollution precipitation pyrite quartzites reduction remediation Slovakia Sobov Mine sulfides vegetation waste disposal wetlands 22, Environmental geology
Abstract A waste dump formed during the exploitation of quartzite deposit in Sobov mine (Slovakia) produces large quantity of acid mine drainage (AMD) which is mainly a product of pyrite oxidation. Sulphuric acid--the most aggressive oxidation product--attacks gangue minerals, mainly clays, as well. This process lead to a sharp decrease of the pH values (2-2.5) and increase of Fe, Al and SO (super 2-) (sub 4) contents (TDS = 20-30 mg/1). Passive treatment system was designed to remediate AMD. Chemical redox reactions along with microbial activity cause a precipitation of mobile contamination into a more stable forms. The sulphides are formed in the anaerobic cell, under reducing conditions. Fe-, Al- oxyhydroxides are precipitated in the aerobic part of the system. Precipitation decreases the Fe and Al contents along with immobilization of some heavy metal closely related to oxyhydroxides. Besides oxidation, the wetland vegetation is an active part of on aerobic cell. The system has been working effectively since September 1999. The pH values of outflowing water are apparently higher (6.2-6.8) and contents of dissolved elements (Fe from 2.260 to 4.1; Al from 900 to 0.18; Mn from 51 to 23; Cu from 4.95 to 0.03 mg/l) is significantly lowers.
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ISSN 0369-2086 ISBN Medium
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Notes Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica; 2004-084366; References: 21; illus. incl. sects. Slovak Republic (SVK); GeoRef; Slovakian Approved no
Call Number CBU @ c.wolke @ 16534 Serial 235
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Author Watzlaf, G.R.; Schroeder, K.T.; Kairies, C.L.
Title Type Book Whole
Year 2000 Publication Abbreviated Journal
Volume Issue Pages 262-274
Keywords passive treatment anoxic limestone drains wetlands sulfate reduction successive alkalinity-producing systems acid mine drainage ALD SAPS RAPS
Abstract Ten passive treatment systems, located in Pennsylvania and Maryland, have been intensively monitored for up to ten years. Influent and effluent water quality data from ten anoxic limestone drains (ALDs) and six reducing and alkalinity-producing systems (RAPS) have been analyzed to determine long-term performance for each of these specific unit operations. ALDs and RAPS are used principally to generate alkalinity, ALDs are buried beds of limestone that add alkalinity through dissolution of calcite. RAPS add alkalinity through both limestone dissolution and bacterial sulfate reduction. ALDs that received mine water containing less than 1 mg/L of both ferric iron and aluminum have continued to produce consistent concentrations of alkalinity since their construction. However, an ALD that received 20 mg/L of aluminum experienced a rapid reduction in permeability and failed within five months. Maximum levels of alkalinity (between 150 and 300 m&) appear to be reached after I5 hours of retention. All but one RAPS in this study have been constructed and put into operation only within the past 2.5 to 5 years. One system has been in operation and monitored for more than nine years. AIkalinity due to sulfate reduction was highest during the first two summers of operation. Alkalinity due to a limestone dissolution has been consistent throughout the life of the system. For the six RAPS in this study, sulfate reduction contributed an average of 28% of the total alkalinity. Rate of total alkalinity generation range from 15.6 gd''rn-'to 62.4 gd-'mL2 and were dependent on influent water quality and contact time.
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Series Editor Series Title Proceedings, 17th Annual National Meeting – American Society for Surface Mining and Reclamation Abbreviated Series Title
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Notes Long-Term Perpormance of Alkalinity-Producing Passive Systems for the Treatment of Mine Drainage; 2; VORHANDEN | AMD ISI | Wolkersdorfer; als Datei vorhanden 4 Abb., 5 Tab. Approved no
Call Number CBU @ c.wolke @ 17440 Serial 216
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