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Author Wolkersdorfer, C. url  openurl
  Title Mine water tracer tests as a basis for remediation strategies Type Journal Article
  Year 2005 Publication Chemie der Erde Abbreviated Journal  
  Volume 65 Issue Suppl. 1 Pages 65-74  
  Keywords Mine water treatment Stratification Convection First flush Tracer tests Microspheres Reactive transport Groundwater problems and environmental effects Pollution and waste management non radioactive acid mine drainage remediation  
  Abstract Mining usually causes severe anthropogenic changes by which the ground- or surface water might be significantly polluted. One of the main problems in the mining industry are acid mine drainage, the drainage of heavy metals, and the prediction of mine water rebound after mine closure. Therefore, the knowledge about the hydraulic behaviour of the mine water within the flooded mine might significantly reduce the costs of mine closure and remediation. In the literature, the difficulties in evaluating the hydrodynamics of flooded mines are well described, but only few tracer tests in flooded mines have been published so far. Most tracer tests linked to mine water problems were related to either pollution of the aquifer or radioactive waste disposal and not the mine water itself. Applying the results of the test provides possibilities f or optimizing the outcome of the source-path-target methodology and therefore diminishes the costs of remediation strategies. Consequently, prior to planning of remediation strategies or numerical simulations, relatively cheap and reliable results for decision making can be obtained via a well conducted tracer test. < copyright > 2005 Elsevier GmbH. All rights reserved.  
  Address C. Wolkersdorfer, TU Bergakademie Freiberg, Lehrstuhl fur Hydrogeologie, 09596 Freiberg, Sachsen, Germany c.wolke@tu-freiberg.de  
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  Series Volume Series Issue Edition  
  ISSN 0009-2819 ISBN Medium  
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  Notes Sep 19; Mine water tracer tests as a basis for remediation strategies; 2767887; Germany 34; Geobase Approved no  
  Call Number CBU @ c.wolke @ 17499 Serial 34  
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Author Akcil, A.; Koldas, S. url  openurl
  Title Acid Mine Drainage (AMD): causes, treatment and case studies Type Journal Article
  Year 2006 Publication J. Cleaner Prod. Abbreviated Journal  
  Volume 14 Issue 12-13 Pages 1139-1145  
  Keywords contamination effluents government industrial pollution industrial waste mining industry research initiatives wastewater treatment acid mine drainage environmental problems mining industry government research initiatives contamination civil engineering mining quarrying activity environmental impact acid generating process acid drainage migration prevention measures effluent treatment chemical treatment biological treatment Manufacturing and Production Entwässern=Gelände Umweltbelastung Bauingenieurwesen Bergbau Sickerwasser Steinbruch Säureproduktion Neutralisation Bergbauindustrie technische Forschung Ingenieurswissenschaft Steinbruchabbau Acid Mine Drainage Mining Environmental Chemical and biological treatment  
  Abstract This paper describes Acid Mine Drainage (AMD) generation and its associated technical issues. As AMD is recognized as one of the more serious environmental problems in the mining industry, its causes, prediction and treatment have become the focus of a number of research initiatives commissioned by governments, the mining industry, universities and research establishments, with additional inputs from the general public and environmental groups. In industry, contamination from AMD is associated with construction, civil engineering mining and quarrying activities. Its environmental impact, however, can be minimized at three basic levels: through primary prevention of the acid-generating process; secondary control, which involves deployment of acid drainage migration prevention measures; and tertiary control, or the collection and treatment of effluent.  
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  ISSN 0959-6526 ISBN Medium  
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  Notes Acid Mine Drainage (AMD): causes, treatment and case studies; Science Direct Approved no  
  Call Number CBU @ c.wolke @ 17462 Serial 36  
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Author Evangelou, V.P. url  openurl
  Title Pyrite microencapsulation technologies: Principles and potential field application Type Journal Article
  Year 2001 Publication Ecological Engineering Abbreviated Journal  
  Volume 17 Issue 2-3 Pages 165-178  
  Keywords mine water treatment Acid mine drainage Acidity Alkalinity Amelioration Coating Oxidation Surface reactions  
  Abstract In nature, pyrite is initially oxidized by atmospheric O2, releasing acidity and Fe2+. At pH below 3.5, Fe2+ is rapidly oxidized by T. ferrooxidans to Fe3+, which oxidizes pyrite at a much faster rate than O2. Commonly, limestone is used to prevent pyrite oxidation. This approach, however, has a short span of effectiveness because after treatment the surfaces of pyrite particles remain exposed to atmospheric O2 and oxidation continuous abiotically. Currently, a proposed mechanism for explaining non-microbial pyrite oxidation in high pH environments is the involvement of OH- in an inner-sphere electron-OH exchange between pyrite/surface-exposed disulfide and pyrite/surface-Fe(III)(OH)n3-n complex and/or formation of a weak electrostatic pyrite/surface-CO3 complex which enhances the chemical oxidation of Fe2+. The above infer that limestone application to pyritic geologic material treats only the symptoms of pyrite oxidation through acid mine drainage neutralization but accelerates non-microbial pyrite oxidation. Therefore, only a pyrite/surface coating capable of inhibiting O2 diffusion is expected to control long-term oxidation and acid drainage production. The objective of this study was to examine the feasibility in controlling pyrite oxidation by creating, on pyrite surfaces, an impermeable phosphate or silica coating that would prevent either O2 or Fe3+ from further oxidizing pyrite. The mechanism underlying this coating approach involves leaching mine waste with a coating solution composed of H2O2 or hypochlorite, KH2PO4 or H4SiO4, and sodium acetate (NaAC) or limestone. During the leaching process, H2O2 or hypochlorite oxidizes pyrite and produces Fe3+ so that iron phosphate or iron silicate precipitates as a coating on pyrite surfaces. The purpose of NaAC or limestone is to eliminate the inhibitory effect of the protons (produced during pyrite oxidation) on the precipitation of iron phosphate or silicate and to generate iron-oxide pyrite coating, which is also expected to inhibit pyrite oxidation. The results showed that iron phosphate or silicate coating could be established on pyrite by leaching it with a solution composed of: (1) H2O2 0.018-0.16 M; (2) phosphate or silicate 10-3 to 10-2 M; (3) coating-solution pH [approximate]5-6; and (4) NaAC as low as 0.01 M. Leachates from column experiments also showed that silicate coatings produced the least amount of sulfate relative to the control, limestone and phosphate treatments. On the other hand, limestone maintained the leachate near neutral pH but produced more sulfate than the control.  
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  ISSN 0925-8574 ISBN Medium  
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  Notes July 01; Pyrite microencapsulation technologies: Principles and potential field application; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10063.pdf; Science Direct Approved no  
  Call Number CBU @ c.wolke @ 10063 Serial 37  
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Author Baker, K.A.; Fennessy, M.S.; Mitsch, W.J. url  openurl
  Title Designing wetlands for controlling coal mine drainage: an ecologic- economic modelling approach Type Journal Article
  Year 1991 Publication Ecological Economics Abbreviated Journal  
  Volume 3 Issue 1 Pages 1-24  
  Keywords mine drainage economic cost iron removal simulation model ecotechnology modelling approach treatment efficiency wetland design wastewater treatment USA Alabama USA Tennessee USA Ohio  
  Abstract A simulation model is developed of the efficiency and economics of an application of ecotechnology – using a created wetland to receive and treat coal mine drainage. The model examines the role of loading rates of iron on treatment efficiencies and the economic costs of wetland versus conventional treatment of mine drainage. It is calibrated with data from an Ohio wetland site and verified from multi-site data from Tennessee and Alabama. The model predicts that iron removal is closely tied to loading rates and that the cost of wetland treatment is less than that of conventional for iron loading rates of approximately 20-25 g Fe m “SUP -2” day “SUP -1” and removal efficiencies less than 85%. A wetland to achieve these conditions would cost approximately US$50 000 per year according to the model. When higher loading rates exist and higher efficiencies are needed, wetland systems are more costly than conventional treatment. -Authors  
  Address Third author School of Natural Resources & Environmental Biology Program, Ohio State Univ., Columbus, OH 43210-1085, USA  
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  ISSN 0921-8009 ISBN Medium  
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  Notes Mar.; Designing wetlands for controlling coal mine drainage: an ecologic- economic modelling approach; (0882174); 91h-08506; Using Smart Source Parsing pp; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10684.pdf; Geobase Approved no  
  Call Number CBU @ c.wolke @ 17570 Serial 38  
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Author Conca, J.L.; Wright, J. url  openurl
  Title An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd Type Journal Article
  Year 2006 Publication Appl. Geochem. Abbreviated Journal  
  Volume 21 Issue 12 Pages 2188-2200  
  Keywords Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry  
  Abstract Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed).  
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  ISSN 0883-2927 ISBN Medium  
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  Notes Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct Approved no  
  Call Number CBU @ c.wolke @ 17248 Serial 44  
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