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Turek, M., & Gonet, M. (1997). Nanofiltration in the utilization of coal-mine brines. Desalination, 108(1-3), 171–177.
Abstract: The utilization of saline coal mine waters is considered to be the most adequate method of solving ecological problems caused by this kind of water in Poland. In the case of most concentrated waters, the so-called coalmine brines, the method of concentrating by evaporation in a twelve-stage expansion installation or vapour compression is applied, after which sodium chloride is manufactured. A considerable restriction in the utilization of coal mine brines is the high energy consumption in these methods of evaporation. An obstacle in the application of low energy evaporation processes, e.g. multi-stage flash, is the high concentration of calcium and sulfate ions in the coal mine brines. The present paper deals with the application of nanofiltration in the pretreatment of the brine. The application of nanofiltration membranes with an adequate pore size, including charged membranes, makes it possible to decrease the concentration of divalent ions in the permeate practically without any changes in the concentration of sodium chloride. Then the permeate may be concentrated in a multi-stage evaporation process, e.g. MSF, without any risk of the crystallization of gypsum. A combination of NF and MSF ought to set down the unit costs of the concentration of coal mine brines below those of mere evaporation.
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Arnekleiv, J. V., & Storset, L. (1995). Downstream effects of mine drainage on benthos and fish in a Norwegian river; a comparison of the situation before and after river rehabilitation. Heavy metal aspects of mining pollution and its remediation, 52, 35–43.
Abstract: Parts of the Norwegian river Gaula are strongly polluted from former mining activity in the area. In the most polluted parts of the river the concentration levels of Cu and Zn in 1986-1987 were up to 155 mu g l (super -1) and 186 mu g l (super -1) , respectively. In 1989 the spoil heaps in the mining area were covered with protective layers of moss-covered plastic. In 1991-1992 the concentration levels of Cu and Zn had decreased by 75% and 65%, respectively. Animal life in the polluted area seemed to be strongly affected by the trace metals in 1986-1987. The 1991-1992 results showed a marked increase in the number of species and in the number of individuals of each species of Ephemeroptera and Plecoptera, compared with the results from 1986-87. Good correlations were found between the concentrations of Cu in the water and both the number of species and the number of individuals of Ephemeroptera and Plecoptera. Analysis of the species Baetis rhodani, Diura nanseni and Rhyacophila nubila showed an average total dry weight content of Cu up to 264 mu g g (super -1) , of Zn up to 1930 mu g g (super -1) and of Cd up to 16 mu g g (super -1) . The contents of the three trace metals were significantly different from one species to another and in part between the stations for each species. In 1987 trout died after an exposure of one to two days on three test sites in the river, whereas in 1991-1992 40-75% of the trout survived an exposure period of several weeks at two of the sites. Electrofishing in 1991-1992 indicated recolonization of trout in the lower parts of the former affected and uninhabitable area.
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Boonstra, J., van Lier, R., Janssen, G., Dijkman, H., Buisman, C. J. N., & Ballester, R. A. and A. (1999). Biological treatment of acid mine drainage. In Process Metallurgy (pp. 559–567). Volume 9, Part 2: Elsevier Science B.V.
Abstract: In this paper experience obtained with THIOPAQ technology treating Acid Mine Drainage is described. THIOPAQ Technology involves biological sulfate reduction technology and the removal of heavy metals as metal sulfide precipitates. The technology was developed by the PAQUES company, who have realised over 350 high rate biological treatment plants world wide. 5 plants specially designed for sulfate reduction are successfully operated on a continuous base (1998 status). At Budelco, a zinc refinery in the Netherlands, an acid groundwater stream is effectively treated since 1992, removing metals and sulfate. At Kennecott Utah Copper (USA) a demo plant is in operation since 1995. An acid groundwater flow is treated to remove sulfate and metals, whereas the excess sulfide is used to selectively recover copper economically. Early 1998, a demonstration project was executed at the Wheal Jane mine in Cornwall, UK. In this demonstration project it has been proven that THIOPAQ technology can effectively be used to treat the Wheal Jane Acid Mine Drainage. Relative to lime dosing technology, very high removal efficiencies of all heavy metals (including cadmium and arsenic) can be obtained.
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Guay, R., Cantin, P., Karam, A., Vezina, S., Paquet, A., & Ballester, R. A. and A. (1999). Effect of flooding of oxidized mine tailings on T. ferrooxidans and T. thiooxidans survival and acid mine drainage production: a 4 year restoration-environmental follow-up. In Process Metallurgy (pp. 635–643). Volume 9, Part 2: Elsevier Science B.V.
Abstract: A pilot-scale study on the effect of flooding unoxidized and oxidized Cu/Zn tailings demonstrated the technical feasability of this technology to remediate a mining site where over 3 million tons of tailings were impounded. Full-scale flooding of the tailing pond with free running water was undertaken after the construction of an impervious dam; approximately 2 million m3 of surface water at pH 7,4 completely covered the tailings after 16 months. The minimal water column over the tailings was established at 1,20 m and reached 4,5 m, depending on the site topography. Water and tailings samples were collected from 9 different locations from the surface of the man-made lake using a specially designed borer and were analyzed for pH, conductivity, iron- and sulfur-oxidizing bacteria activity and numbers as well as the sulfate reducing bacteria (SRB) population. We showed that over a four year period of flooding, the overall population of iron-oxidizers decreased considerably; their numbers drastically fell from 1x106 to 1x102 active cells per g of oxidized tailings while the SRBs increased from 101 to 105/g. The pH of the influent, the reservoir and the effluent water remained fairly constant between 6,9 up to 7,4 over the entire period. During this time, interstitial water pH increased from 2,9 to 4,3 in flooded tailings where lime could not be incorporated in the first 20 cm of tailings; elsewhere, the pH of the tailings suspensions remained fairly constant around neutral values (pH 7,0). Dissolved oxygen was measured at fixed intervals and remained also constant between 6 and 7.5 mg/L while water temperatures fluctuated below freezing point to +20C respectively in winter and summer season.
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Wolkersdorfer, C. (2005). Mine water tracer tests as a basis for remediation strategies. Chemie der Erde, 65(Suppl. 1), 65–74.
Abstract: Mining usually causes severe anthropogenic changes by which the ground- or surface water might be significantly polluted. One of the main problems in the mining industry are acid mine drainage, the drainage of heavy metals, and the prediction of mine water rebound after mine closure. Therefore, the knowledge about the hydraulic behaviour of the mine water within the flooded mine might significantly reduce the costs of mine closure and remediation. In the literature, the difficulties in evaluating the hydrodynamics of flooded mines are well described, but only few tracer tests in flooded mines have been published so far. Most tracer tests linked to mine water problems were related to either pollution of the aquifer or radioactive waste disposal and not the mine water itself. Applying the results of the test provides possibilities f or optimizing the outcome of the source-path-target methodology and therefore diminishes the costs of remediation strategies. Consequently, prior to planning of remediation strategies or numerical simulations, relatively cheap and reliable results for decision making can be obtained via a well conducted tracer test. < copyright > 2005 Elsevier GmbH. All rights reserved.
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