| Records |
| Author |
Totsche, O.; Fyson, A.; Kalin, M.; Steinberg Christian, E.W. |
| Title |
Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters |
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Journal Article |
| Year |
2006 |
Publication |
ESPR Environmental Science and Pollution Research |
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| Volume |
13 |
Issue |
4 |
Pages |
215-224 |
| Keywords |
Abwasseraufbereitung Bergbau Titration Säuregehalt Grundwasser Pufferlösung Neutralisation Titrationskurve Bergbauabwasser |
| Abstract |
The acidification of mine waters is generally caused by metal sulfide oxidation, related to mining activities. These waters are characterized by low pH and high acidity due to strong buffering systems. The standard acidity parameter, the BNC (Base Neutralization Capacity), is determined by endpoint titration, and reflects a cumulative parameter of both hydrogen ions and all buffering systems, but does not give information on the individual buffer systems. It is demonstrated that a detailed interpretation of titration curves can provide information about the strength of the buffering systems. The buffering systems are of importance for environmental studies and treatment of acidic mining waters. Titrations were carried out by means of an automatic titrator using acidic mining waters from Germany and Canada. The curves were interpreted, compared with each other, to endpoint titration results and to elemental concentrations contained therein. The titration curves were highly reproducible, and contained information about the strength of the buffer systems present. Interpretations are given, and the classification and comparison of acidic mining waters, by the nature and strength of their buffering systems derived from titration curves are discussed. The BNC-values calculated from the curves were more precise than the ones determined by the standard endpoint titration method. Due to the complex buffer mechanisms in acidic mining waters, the calculation of major metal concentrations from the shape of the titration curve resulted in estimates, which should not be confused with precise elemental analysis results. Conclusion. Titration curves provide an inexpensive, valuable and versatile tool, by which to obtain sophisticated information of the acidity in acidic water. The information about the strength of the present buffer systems can help to understand and document the complex nature of acidic mining water buffer systems. Finally, the interpretation of titration curves could help to improve treatment measurements and the ecological understanding of these acidic waters. |
| Address |
Leibniz-Institut für Gewässerökologie und Binnenfischerei, Berlin, DE; Boojum Research, Toronto, CA; Humboldt-Universität Berlin, DE |
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0944-1344 |
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Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters; 39481, BERG , 13.11.06; Words: 519; 200610 05282; 10 Seiten, 15 Bilder, 2 Tabellen, 39 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3BX *chemische Grundlagen* 3IFC *Messung und Prüfung chemischer Größen, chemische Analytik* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
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CBU @ c.wolke @ 17580 |
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224 |
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Simmons, J.A.; Andrew, T.; Arnold, A.; Bee, N.; Bennett, J.; Grundman, M.; Johnson, K.; Shepherd, R. |
| Title |
Small-Scale Chemical Changes Caused by In-stream Limestone Sand Additions to Streams |
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Journal Article |
| Year |
2006 |
Publication |
Mine Water Env. |
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25 |
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4 |
Pages |
241-245 |
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acid mine drainage aluminum calcium limestone sand sediment stream liming West Virginia |
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In-stream limestone sand addition (ILSA) has been employed as the final treatment for acid mine drainage discharges at Swamp Run in central West Virginia for six years. To determine the small-scale longitudinal variation in stream water and sediment chemistry and stream biota, we sampled one to three locations upstream of the ILSA site and six locations downstream. Addition of limestone sand significantly increased calcium and aluminum concentrations in sediment and increased the pH, calcium, and total suspended solids of the stream water. Increases in alkalinity were not significant. The number of benthic macroinvertebrate taxa was significantly reduced but there was no effect on periphyton biomass. Dissolved aluminum concentration in stream water was reduced, apparently by precipitation into the stream sediment. |
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1025-9112 |
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Small-Scale Chemical Changes Caused by In-stream Limestone Sand Additions to Streams; 1; FG 4 Abb., 2 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17420 |
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248 |
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Plant, J. |
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Removal of base metals from mine waters using passive treatment processes involving autocatalytic oxidation and adsorption |
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2006 |
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Acid mine drainage Water — Pollution Mineral industries. — Wales |
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Removal of base metals from mine waters using passive treatment processes involving autocatalytic oxidation and adsorption; Opac |
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CBU @ c.wolke @ 7100 |
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269 |
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| Author |
Mohan, D.; Chander, S. |
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Removal and recovery of metal ions from acid mine drainage using lignite-A low cost sorbent |
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Journal Article |
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2006 |
Publication |
J. Hazard. Mater. |
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137 |
Issue |
3 |
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1545-1553 |
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Geobase: Related Topics geobase: related topics (901) acid mine drainage adsorption ion iron sulfide lignite wastewater water treatment |
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Acid mine drainage (AMD), has long been a significant environmental problem resulting from the microbial oxidation of iron pyrite in presence of water and air, affording an acidic solution that contains toxic metal ions. The main objective of this study was to remove and recover metal ions from acid mine drainage (AMD) by using lignite, a low cost sorbent. Lignite has been characterized and used for the AMD treatment. Sorption of ferrous, ferric, manganese, zinc and calcium in multi-component aqueous systems was investigated. Studies were performed at different pH to find optimum pH. To simulate industrial conditions for acid mine wastewater treatment, all the studies were performed using single and multi-columns setup in down flow mode. The empty bed contact time (EBCT) model was used for minimizing the sorbent usage. Recovery of the metal ions as well as regeneration of sorbent was achieved successfully using 0.1 M nitric acid without dismantling the columns. < copyright > 2006 Elsevier B.V. All rights reserved. |
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D. Mohan, Department of Energy and Geo-Environmental Engineering, The Pennsylvania State University, University Park, PA 16802, United States dm_1967@hotmail.com |
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0304-3894 |
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Oct 11; Removal and recovery of metal ions from acid mine drainage using lignite-A low cost sorbent; 2919875; Netherlands 56; Geobase |
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CBU @ c.wolke @ 17634 |
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295 |
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Märten, H. |
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Neueste Trends zur aktiven Wasserbehandlung und Anwendungsbeispiele |
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Journal Article |
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2006 |
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Wissenschaftliche Mitteilungen |
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31 |
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13-22 |
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Wasserbehandlung AMD Acidic Mine Drainage In-situ-Laugung ISL Tagebaurestsee |
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Aktuelle Entwicklungen auf dem Gebiet der aktiven Wasserbehandlung im Bergbau in den spezifischen Anwendungsgebieten • Behandlung von sauren Bergbauwässern (AMD – acidic mine drainage) mit Schwerpunkt HDS-Technologie (HDS – high-density sludge) • In-situ-Behandlung bergbaubeeinflusster Grundwasserkörper, insbesondere nach Anwendung der In-situ-Laugung (ISL) • In-situ-Behandlung von Tagebaurestseen mit Schwerpunkt In-lake-Verfahren werden hinsichtlich Machbarkeit, technologischer Kenngrößen und Effizienz bewertet und kommen-tiert. Recent developments in the field of active water treatment technologies in the mining sector are re-viewed. Application areas of interest include • Treatment of acidic mine drainage (AMD) emphasizing HDS technology (HDS – high-density sludge) • In-situ treatment of groundwater affected by mining, in particular after the application of in-situ leaching (ISL) • In-situ treatment of lakes arising in former open-pit lignite mines, in particular the application of in-lake methods The various applications are evaluated with regard to feasibility, technical characteristics and treat-ment efficiency. |
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1433-1284 |
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Neueste Trends zur aktiven Wasserbehandlung und Anwendungsbeispiele; 1; FG 'aha' 5 Abb.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17386 |
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308 |
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