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Herbert, R. B., Jr., Benner, S. G., & Blowes, D. W. (1998). Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation. In M. Herbert, & K. Kovar (Eds.), Groundwater Quality: Remediation and Protection (pp. 451–457). IAHS-AISH Publication, vol.250.
Abstract: A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997.
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Barton, C. D., & Karathanasis, A. D. (1998). Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage. Environ Geosci, 5(2), 43–56.
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Barton, C. D., & Karathanasis, A. D. (1997). Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage. In AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts (1545). 81: AAPG Bulletin.
Abstract: The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system.
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Earley, D., III, Schmidt, R. D., & Kim, K. (1997). Is sustainable mining an oxymoron?.
Abstract: Sustainable mining is generally considered to be an oxymoron because mineral deposits are viewed as nonrenewable resources that are fixed in the crust. However, minerals are conserved and recycled by plate tectonics which continually creates and destroys ore deposits. Though it is true that rock cycles have much longer periods than biomass cycles, the crust is essentially an infinite reservoir so long as we continue to invest in mineral exploration and processing technology. Implicit in the definition of sustainable development is the recognition that human development of resources in one reservoir may subsequently degrade resources supplied by another. The depreciation of overlapping and adjacent resources is often externalized in the cost to benefit accounting and cannot be sustained if the integrated cost/benefit ratio is greater than 1. The greatest obstacle to sustainability in mining is the expanding scale of excavation required to develop leaner ores because this activity degrades connected resources. In the case of open pit, sulfide ore mining the disturbed land may produce acid rock drainage (ARD). Because ARD will self-generate over the course of tens to hundreds of years the cost of controlling this pollution and rehabilitating mined lands is large and often spread over many generations. Secondary production of minerals from partially excavated deposits where there are preexisting environmental impacts and mine infrastructure help to reduce the risk of depreciating pristine resources, provided that new mining operations “do no (additional) harm” (Margoles, 1996). In turn, a percentage of the profits derived from secondary mineral production can be used for rehabilitation of the previously mined lands. These lands contain significant, albeit low grade, metal concentrations. These concepts are being developed and tested at the Mineral Park Sustainable Mining Research Facility where an in situ copper sulfide mining field experiment was conducted. Monitoring data and computer modeling indicate that ARD is not generated after closure. This is because the ore is not disturbed and is left saturated, whereas unsaturated conditions generate acidic drainage. The short term risk of groundwater contamination is mitigated by utilizing an exempt mine pit to capture any leach solutions that are not intercepted by the wellfield. Using green accounting techniques and transfer models it can be communicated that this mining scenario is an approach to sustainability.
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Gong, Z., Huang, J., & Jiang, H. (1996). Study of comprehensive retrieval utilization and the treatment of acid mine wastewater. Zhongnan Gongye Daxue Xuebao = Journal of Central South University of Technology, 27(4), 432–435.
Abstract: Impact of precipitating on removing harmful metal ion in the acid mine wastewater with pH neutralizer and sulfide was studied. The possible way of retrieving heavy metal ion in wastewater was probed. The techniques for lime carbonate to reject iron for hydrogen sulfide to precipitate copper and for zinc-lime cream neutralization flocculation to treat, mine acid wastewater were chosen. The final water quality may reach national effluent standard; the copper content was 32% in the sulfide slag.
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