| Records |
| Author |
Herbert, R.B., Jr.; Benner, S.G.; Blowes, D.W. |
| Title |
Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation |
Type |
Book Chapter |
| Year |
1998 |
Publication |
Groundwater Quality: Remediation and Protection |
Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
451-457 |
| Keywords |
acid mine drainage Canada chemical analysis contaminant plumes Eastern Canada ground water hydraulic conductivity hydrolysis Nickel Rim Mine Ontario pH pollution porosity pyrrhotite remediation sample preparation Sudbury Basin sulfides sulfur tailings water pollution 22, Environmental geology |
| Abstract |
A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997. |
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Thesis |
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| Publisher |
IAHS-AISH Publication, vol.250 |
Place of Publication |
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Editor |
Herbert, M.; Kovar, K. |
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Summary Language |
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Original Title |
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Series Issue |
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Edition |
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| ISSN |
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ISBN |
1901502554 |
Medium |
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Expedition |
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Conference |
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| Notes |
Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation; GeoRef; English; 1999-065115; GQ 98 conference, Tubingen, Federal Republic of Germany, Sept. 21-24, 1998 References: 15; illus. |
Approved |
no |
Call Number  |
CBU @ c.wolke @ 16621 |
Serial |
65 |
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| Author |
Barton, C.D.; Karathanasis, A.D. |
| Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Journal Article |
| Year |
1998 |
Publication |
Environ Geosci |
Abbreviated Journal |
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| Volume |
5 |
Issue |
2 |
Pages |
43-56 |
| Keywords |
acid mine drainage aerobic environment anaerobic environment attenuation chemical fractionation chemical properties concentration constructed wetlands controls degradation detection environmental analysis ferric iron goethite heavy metals iron jarosite Kentucky McCreary County Kentucky metals oxides pollutants pollution seepage soils solubility sulfates surface water United States water treatment wetlands X-ray diffraction data 22, Environmental geology |
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Series Title |
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Abbreviated Series Title |
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Series Issue |
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Edition |
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| ISSN |
1075-9565 |
ISBN |
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Expedition |
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Conference |
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| Notes |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; 2001-034195; References: 41; illus. incl. 1 table United States (USA); GeoRef; English |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16623 |
Serial |
61 |
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| Author |
Barton, C.D.; Karathanasis, A.D. |
| Title |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage |
Type |
Book Chapter |
| Year |
1997 |
Publication |
AAPG Eastern Section and the Society for Organic Petrology joint meeting; abstracts |
Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
1545 |
| Keywords |
acid mine drainage aerobic environment air-water interface anaerobic environment attenuation buffers constructed wetlands controls diffusion iron manganese metals mineral composition pollution precipitation processes SEM data solubility solution sulfate ion sulfur wetlands X-ray diffraction data 22, Environmental geology |
| Abstract |
The use of constructed wetlands for acid mine drainage amelioration has become a popular alternative to conventional treatment methods, however, the metal attenuation processes of these systems are poorly understood. Precipitates from biotic and abiotic zones of a staged constructed wetland treating high metal load (approx. equal to 1000 mg L (super -1) ) and low pH (approx. 3.0) acid mine drainage were characterized by chemical dissolution, x-ray diffraction, thermal analysis and scanning electron microscopy. Characterization of abiotic/aerobic zones within the treatment system suggest the presence of crystalline iron oxides and hydroxides such as hematite, lepidocrocite, goethite, and jarosite. At the air/water interface of initial abiotic treatment zones, SO (sub 4) /Fe ratios were low enough (<2.0) for the formation of jarosite and goethite, but as the ratio increased due to treatment and subsequent reductions in iron concentration, jarosite was transformed to other Fe-oxyhydroxysulfates and goethite formation was inhibited. In addition, elevated pH conditions occurring in the later stages of treatment promoted the formation of amorphous iron oxyhydroxides. Biotic wetland cell substrate characterizations suggest the presence of amorphous iron minerals such as ferrihydrite and Fe(OH) (sub 3) . Apparently, high Fe (super 3+) activity, low Eh and low oxygen diffusion rates in the anaerobic subsurface environment inhibit the kinetics of crystalline iron precipitation. Some goethite, lepidocrocite and hematite, however, were observed near the surface in biotic areas and are most likely attributable to increased oxygen levels from surface aeration and/or oxygen transport by plant roots. Alkalinity generation from limestone dissolution within the substrate and bacterially mediated sulfate reduction also has a significant role on the mineral retention process. The formation of gypsum, rhodochrocite and siderite are by-products of alkalinity generating reactions in this system and may have an impact on S, Mn, and Fe solubility controls. Moreover, the buffering of acidity through excess alkalinity appears to facilitate the precipitation and retention of metals within the system. |
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Thesis |
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| Publisher |
AAPG Bulletin |
Place of Publication |
81 |
Editor |
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Summary Language |
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ISBN |
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| Notes |
Aerobic and anaerobic metal attenuation processes in a constructed wetland treating acid mine drainage; GeoRef; English; 1997-067790; AAPG Eastern Section and the Society for Organic Petrology joint meeting, Lexington, KY, United States, Sep. 27-30, 1997 |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16630 |
Serial |
70 |
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| Author |
Gong, Z.; Huang, J.; Jiang, H. |
| Title |
Study of comprehensive retrieval utilization and the treatment of acid mine wastewater |
Type |
Journal Article |
| Year |
1996 |
Publication |
Zhongnan Gongye Daxue Xuebao = Journal of Central South University of Technology |
Abbreviated Journal |
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| Volume |
27 |
Issue |
4 |
Pages |
432-435 |
| Keywords |
acid mine drainage Asia China copper Far East heavy metals metals pH pollution sulfides utilization waste water water 22, Environmental geology |
| Abstract |
Impact of precipitating on removing harmful metal ion in the acid mine wastewater with pH neutralizer and sulfide was studied. The possible way of retrieving heavy metal ion in wastewater was probed. The techniques for lime carbonate to reject iron for hydrogen sulfide to precipitate copper and for zinc-lime cream neutralization flocculation to treat, mine acid wastewater were chosen. The final water quality may reach national effluent standard; the copper content was 32% in the sulfide slag. |
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Summary Language |
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Series Issue |
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Edition |
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| ISSN |
1005-9792 |
ISBN |
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Medium |
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Expedition |
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Conference |
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| Notes |
Study of comprehensive retrieval utilization and the treatment of acid mine wastewater; 1998-066886; References: 4; 4 tables China (CHN); GeoRef; Chinese |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16650 |
Serial |
370 |
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| Author |
Cram, J.C. |
| Title |
Diversion well treatment of acid water, Lick Creek, Tioga County, PA |
Type |
Book Whole |
| Year |
1996 |
Publication |
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Abbreviated Journal |
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| Volume |
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Issue |
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Pages |
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| Keywords |
acid mine drainage acid rain atmospheric precipitation carbonate rocks diversion wells Lick Creek limestone Pennsylvania pH pollution rain sedimentary rocks surface water Tioga County Pennsylvania United States water quality water treatment wells 22, Environmental geology |
| Abstract |
Diversion wells implement a fluidized bed of limestone for the treatment of acid water resulting from acid mine drainage or acid precipitation. This study was undertaken to better understand the operation of diversion wells and to define the physical and chemical factors having the greatest impact on the neutralization performance of the system. The study site was located near Lick Creek, a tributary stream of Babb Creek, near the Village of Arnot in Tioga County, Pennsylvania. Investigative methods included collection and analysis of site water quality and limestone data and field study of this as well as other diversion well sites. Analysis of data led to these general conclusions: The site received surface water influenced by three primary sources 1) precipitation, 2) mine drainage baseflow, and 3) melted snow. Water mostly influenced by precipitation events and mine drainage baseflow was more acidic than water influenced by melting snow conditions. The diversion wells were generally able to treat only half or less of the total stream flow of Lick Creek and under extremely high flow conditions the treatment provided was minimal. A range of flow conditions were identified which produced the best performance for the two diversion wells. Treatment produced by the system decreased through the loading cycle and increases to a maximum value after each weekly refilling of limestone. Fine grained sediment in the stream was found to be limestone of the same general composition as the material placed within the wells. Neutralization of acid water was largely due to microscopic particles rather than the limestone sediment discharged to the stream. Additional downstream buffering due to the limestone sediment physically discharged from the vessels was not apparent. Diversion well systems are inexpensive and simple to construct. In addition, the systems were found to be highly reliable and able to effectively treat acid water resulting from mine drainage and acid precipitation. Diversion wells provide better treatment when the treatment site is located at the source of the acidity (such as a mine discharge), rather than at the receiving stream. Systems should be designed with 15 to 20 feet of hydraulic head and the site must have year-round access. Diversion well systems require weekly addition of limestone gravel to the vessels to facilitate continual treatment. A great deal of commitment is necessary to maintain a diversion well system for long periods of time. These systems are more economical and require less attention that conventional chemical treatment of acid water. However, these systems require more attention that traditional passive treatment methods for treatment of acid, including mine drainage. |
| Address |
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| Corporate Author |
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Thesis |
Ph.D. thesis |
| Publisher |
Pennsylvania State University at University Park, |
Place of Publication |
University Park |
Editor |
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Summary Language |
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Conference |
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| Notes |
Diversion well treatment of acid water, Lick Creek, Tioga County, PA; GeoRef; English; References: 49; illus. |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16652 |
Serial |
411 |
| Permanent link to this record |
