| |
Records |
Links |
|
Author |
Cravotta, C.A., III; Trahan, M.K. |
|
| |
Title |
Limestone drains to increase pH and remove dissolved metals from acidic mine drainage |
Type |
Journal Article |
| |
Year |
1999 |
Publication |
Appl. Geochem. |
Abbreviated Journal |
|
|
| |
Volume |
14 |
Issue |
5 |
Pages |
581-606 |
|
| |
Keywords |
manganese oxide redox processes sulfate waters iron-oxides adsorption ions oxidation surfaces environments aluminum |
|
| |
Abstract |
Despite encrustation by Fe and Al hydroxides, limestone can be effective for remediation of acidic mine drainage (AMD). Samples of water and limestone (CaCO3) were collected periodically for 1 a at 3 identical limestone-filled drains in Pennsylvania to evaluate the attenuation of dissolved metals and the effects of pH and Fe- and Al-hydrolysis products on the rate of CaCO3 dissolution. The influent was acidic and relatively dilute (pH < 4; acidity < 90 mg) but contained 1-4 mg . L-1 of O-2, Fe3+, Al3+ and Mn2+. The total retention time in the oxic limestone drains (OLDs) ranged from 1.0 to 3.1 hr. Effluent remained oxic (O-2 > 1 mg . L-1) but was near neutral (pH = 6.2-7.0); Fe and Al decreased to less than 5% of influent concentrations. As pH increased near the inflow, hydrous Fe and Al oxides precipitated in the OLDs, The hydrous oxides, nominally Fe(OH)(3) and Al(OH)(3), were visible as loosely bound, orange-yellow coatings on limestone near the inflow. As time elapsed, Fe(OH)(3) and Al(OH)(3) particles were transported downflow. The accumulation of hydrous oxides and elevated pH (> 5) in the downflow part of the OLDs promoted sorption and coprecipitation of dissolved Mn, Cu, Co, Ni and Zn as indicated by decreased concentrations of the metals in effluent and their enrichment relative to Fe in hydrous-oxide particles and coatings on limestone. Despite thick (similar to 1 mm) hydrous-oxide coatings on limestone near the inflow, CaCO3 dissolution was more rapid near the inflow than at downflow points within and the OLD where the limestone was not coated. The high rates of CaCO3 dissolution and Fe(OH3) precipitation were associated with the relatively low pH and high Fe3+ concentration near the inflow. The rate of CaCO3 dissolution decreased with increased pH and concentrations of Ca2+ and HCO3- and decreased Pco(2). Because overall efficiency is increased by combining neutralization and hydrolysis reactions, an OLD followed by a settling pond requires less land area than needed for a two-stagetreatment system consisting of an anoxic limestone drain and oxidation-settling pond or wetland. To facilitate removal of hydrous-oxide sludge, a perforated-pipe subdrain can be installed within an OLD. (C) 1999 Elsevier Science Ltd. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0883-2927 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Jul; Limestone drains to increase pH and remove dissolved metals from acidic mine drainage; Isi:000080043300004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10102.pdf; AMD ISI | Wolkersdorfer |
Approved |
no |
|
| |
Call Number  |
CBU @ c.wolke @ 17470 |
Serial |
22 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Erten-Unal, M.; Wixson, B.G. |
|
| |
Title |
Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA |
Type |
Journal Article |
| |
Year |
1999 |
Publication |
Water Air Soil Pollut. |
Abbreviated Journal |
|
|
| |
Volume |
116 |
Issue |
3-4 |
Pages |
501-522 |
|
| |
Keywords |
biotreatment lead and zinc mine wastewater MINTEQ speciation biotreatment lead and zinc mine wastewater minteq speciation trout salmo-gairdneri water |
|
| |
Abstract |
Continued mining development in the world's largest lead producing area has generated and increased concern over effective mine water treatment in Missouri's New Lead Belt. A new type of mine/mill wastewater treatment system was constructed which consisted of a tailings pond followed by a series of artificially constructed meandering biotreatment channels and a polishing lagoon. This system provided additional retention time and distance for the removal of heavy metals by abundant aquatic plants and sedimentation. Seasonal field sampling and analytical testing that evaluated the present system confirmed that it provided good treatment for removal of heavy metals within the company property and produced a final effluent within the state and federal regulatory guidelines. On average, greater than 95% of zinc and manganese in the drainage water were removed by the biotreatment system, while lead and copper were 50 to 60%. A chemical equilibrium model, MINTEQ, was also used to identify various species of lead and zinc in the biotreatment system. The model predicted that the major species of carbonates and hydroxides would be the predominant complexes of lead and zinc for the pH and alkalinity values reported in the biotreatment system. These results were also supported by the literature. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0049-6979 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Dec.; Biotreatment and Chemical Speciation of Lead and Zinc Mine/Mill Wastewater Discharges in Missouri, USA; Isi:000083273200004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10115.pdf; AMD ISI | Wolkersdorfer |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 17472 |
Serial |
16 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Hedin, R.S.; Nairn, R.W.; Kleinmann, R.L.P. |
|
| |
Title |
Passive Treatment of Coal Mine Drainage |
Type |
Journal Article |
| |
Year |
1994 |
Publication |
Bureau of Mines Information Circular |
Abbreviated Journal |
|
|
| |
Volume |
Ic-9389 |
Issue |
|
Pages |
1-35 |
|
| |
Keywords |
wetland Grubenwasser treatment Wasserreinigung Wasserbehandlung mine water |
|
| |
Abstract |
Passive methods of treating mine water utilize chemical and biological processes that decrease metal concentrations and neutralize acidity. Compared to conventional chemical treatment, passive methods generally require more land area, but utilize less costly reagents and require less operational attention and maintenance. Currently, three types of passive technologies exist: aerobic wetlands, wetlands that contain an organic substrate, and anoxic limestone drains. Aerobic wetlands promote mixed oxidation and hydrolysis reactions, and are most effective when the raw mine water is net alkaline. Organic substrate wetlands promote anaerobic bacterial activity that results in the precipitation of metal sulfides and the generation of bicarbonate alkalinity. Anoxic limestone drains generate bicarbonate alkalinity and can be useful for the pretreatment of mine water before it flows into a wetland. Rates of metal and acidity removal for passive systems have been developed empirically. Aerobic wetlands remove Fe and Mn from alkaline water at rates of 10-20 g×m-2×d-1 and 0.5-1.0 g×m-2×d-1, respectively. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0096-1914 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Passive Treatment of Coal Mine Drainage; 1; abgegeben an TUFG 100700 / € 0 13 Abb., 19 Tab.; AMD ISI | Wolkersdorfer |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 17474 |
Serial |
355 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Kuyucak, N. |
|
| |
Title |
Mining, the Environment and the Treatment of Mine Effluents |
Type |
Journal Article |
| |
Year |
1998 |
Publication |
Int. J. Environ. Pollut. |
Abbreviated Journal |
|
|
| |
Volume |
10 |
Issue |
2 |
Pages |
315-325 |
|
| |
Keywords |
mine water treatment acid mine drainage high density sludge lime neutralization mining environment passive treatment sulfate-reducing bacteria |
|
| |
Abstract |
The environmental impact of mining on the ecosystem, including land, water and air, has become an unavoidable reality. Guidelines and regulations have been promulgated to protect the environment throughout mining activities from start-up to site decommissioning. In particular, the occurrence of acid mine drainage (AMD), due to oxidation of sulfide mineral wastes, has become the major area of concern to many mining industries during operations and after site decommissioning. AMD is characterized by high acidity and a high concentration of sulfates and dissolved metals. If it cannot be prevented or controlled, it must be treated to eliminate acidity, and reduce heavy metals and suspended solids before release to the environment. This paper discusses conventional and new methods used for the treatment of mine effluents, in particular the treatment of AMD. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0957-4352 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Mining, the Environment and the Treatment of Mine Effluents; Isi:000078420600009; AMD ISI | Wolkersdorfer |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 17477 |
Serial |
56 |
|
| Permanent link to this record |
| |
|
| |
|
Author |
Schoeman, J.J.; Steyn, A. |
|
| |
Title |
Investigation into alternative water treatment technologies for the treatment of underground mine water discharged by Grootvlei Proprietary Mines Ltd into the Blesbokspruit in South Africa |
Type |
Journal Article |
| |
Year |
2001 |
Publication |
Desalination |
Abbreviated Journal |
|
|
| |
Volume |
133 |
Issue |
1 |
Pages |
13-30 |
|
| |
Keywords |
underground mine water treatment technologies reverse osmosis electrodialysis reversal ion-exchange water quality brine disposal treatment costs |
|
| |
Abstract |
Grootvlei Proprietary Mines Ltd is discharging between 80 and 100 Ml/d underground water into the Blesbokspruit. This water is pumped out of the mine to keep the underground water at such a level as to make mining possible. The water is of poor quality because it contains high TDS levels (2700-3800 mg/l) including high concentrations of iron, manganese, sulphate, calcium, magnesium, sodium and chloride. This water will adversely affect the water ecology in the Blesbokspruit, and it will significantly increase the TDS concentration of one of the major water resources if not treated prior to disposal into the stream. Therefore, alternative water desalination technologies were evaluated to estimate performance and the economics of the processes for treatment of the mine water. It was predicted that water of potable quality should be produced from the mine water with spiral reverse osmosis (SRO). It was demonstrated that it should be possible to reduce the TDS of the mine water (2000-2700-3400-4500 mg/l) to potable standards with SRO (85% water recovery). The capital costs (pretreatment and desalination) for a 80 Ml/d plant (worst-case water) were estimated at US$35M. Total operating costs were estimated at 88.1c/kl. Brine disposal costs were estimated at US$18M. Therefore, the total capital costs are estimated at US$53M. It was predicted that it should be possible to produce potable water from the worst-case feed water (80 Ml/d) with the EDR process. It was demonstrated that the TDS in the feed could be reduced from 4178 to 246 mg/l in the EDR product (65% water recovery). The capital costs (pretreatment plus desalination) to desalinate the worst-case feed water to potable quality with EDR is estimated at US$53.3M. The operational costs are estimated at 47.6 c/kl. Brine disposal costs were estimated at US$42M. Therefore, the total capital costs are estimated at US$95.3 M. It was predicted that it should be possible to produce potable water from the mine water with the GYP-CIX ion- exchange process. It was demonstrated that the feed TDS (2000- 4500 mg/l) could be reduced to less than 240 mg/l (54% water recovery for the worst-case water). The capital cost for an 80 Ml/d ion-exchange plant (worst-case water) was estimated at US$26.7M (no pretreatment). Operational costs were estimated at 60.4 c/kl. Brine disposal costs were estimated at US$55.1M. Therefore, the total desalination costs were estimated at US$81.8M. The capital outlay for a SRO plant will be significantly less than that for either an EDR or a GYP-CIX plant. The operating costs, however, of the RO plant are significantly higher than for the other two processes. Potable water sales, however, will bring more in for the RO process than for the other two processes because a higher water recovery can be obtained with RO. The operating costs minus the savings in water sales were estimated at 17.2; 6.7 and US$8.6M/y for the RO, EDR and GYP-CIX processes, respectively (worst case). Therefore, the operational costs of the EDR and GYP-CIX processes are the lowest if the sale of water is taken into consideration. This may favour the EDR and GYP-CIX processes for the desalination of the mine water. |
|
| |
Address |
|
|
| |
Corporate Author |
|
Thesis |
|
|
| |
Publisher |
|
Place of Publication |
|
Editor |
|
|
| |
Language |
|
Summary Language |
|
Original Title |
|
|
| |
Series Editor |
|
Series Title |
|
Abbreviated Series Title |
|
|
| |
Series Volume |
|
Series Issue |
|
Edition |
|
|
| |
ISSN |
0011-9164 |
ISBN |
|
Medium |
|
|
| |
Area |
|
Expedition |
|
Conference |
|
|
| |
Notes |
Feb. 10; Investigation into alternative water treatment technologies for the treatment of underground mine water discharged by Grootvlei Proprietary Mines Ltd into the Blesbokspruit in South Africa; Isi:000167087500002; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10184.pdf; AMD ISI | Wolkersdorfer |
Approved |
no |
|
| |
Call Number |
CBU @ c.wolke @ 17480 |
Serial |
23 |
|
| Permanent link to this record |
