Blowes, D. W., Ptacek, C. J., Benner, S. G., McRae, C. W. T., & Puls, R. W. (1998). Treatment of dissolved metals using permeable reactive barriers. Groundwater Quality: Remediation and Protection, (250), 483–490.
Abstract: Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1).
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Blowes, D. W., Bain, J. G., Smyth, D. J., Ptacek, C. J., Jambor, J. L., Blowes, D. W., et al. (2003). Treatment of mine drainage using permeable reactive materials. Environmental Aspects of Mine Wastes, 31, 361–376.
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Bloom, N. S., Preus, E., Kilner, P. I., von der Geest, E., & Hensman, C. E. (2002). Very efficient removal of toxic metals from acid mine drainage water (Berkeley Pit, Montana) with a recycled alkaline industrial waste product Hardrock mining 2002; issues shaping the industry..
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Berg, G. J., & Arthur, B. (1999). Proposed mine water treatment in Wisconsin. In D. Goldsack, N. Belzile, P. Yearwood, & G. J. Hall (Eds.), Sudbury '99; mining and the environment II; Conference proceedings. Sudbury: Sudbury Environmental.
Abstract: Water quality standards are driving wastewater effluent limits to ultra-low levels in the nanogram/L range. Standards are proposed that require discharges to match background water quality. The new ultra-low level standards require cautious sampling techniques, super clean laboratory methods and more advanced treatment technologies. This paper follows a case history through water quality standards for ultra-low metals, laboratory selection, and the design of a wastewater treatment system that can meet the water quality standards which are required to permit a proposed copper and zinc mine in Northern Wisconsin. A high degree of care must be taken when sampling for ultra-low level metals. Both surface water and treated effluent samples present new challenges. Sampling methods used must assure that there are no unwanted contaminants being introduced to the samples. The selection of a laboratory is as critical as the construction of a state of the art wastewater treatment system. Treatment methods such as lime and sulfide precipitation have had a high degree of success, but they do have limitations. Given today's ultra-low standards, it is necessary to assess the ability of reverse osmosis, deionization, and evaporation to provide the high level of treatment required.
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Becker, G., Wade, S., Riggins, J. D., Cullen, T. B., Venn, C., & Hallen, C. P. (2005). Effect of Bast Mine treatment discharge on Big Mine Run AMD and Mahanoy Creek in the Western Middle Anthracite Field of Pennsylvania.
Abstract: The Bast Mine (reopened in 2001) and Big Mine are two anthracite coal mines near Ashland, PA, that were abandoned in the 1930's and that are now causing drastic and opposite effects on the water quality of the streams originating from them. To quantify these effects, multiple samples were taken at 5 different sites: 3 along Big Mine Run and 2 from Mahanoy Creek (1 upstream and 1 downstream of the confluence with Big Mine Run). At each site, one set of the samples was treated with nitric acid for metals survey, one set was acidified with sulfuric acid for nitrate preservation, one set was filtered for sulfate and phosphate tests, and one set was unaltered. Measurements of pH, TDS, dissolved oxygen, and temperature were made in the field. Alkalinity, acidity, hardness, nitrates, orthophosphates and sulfates were analyzed using Hach procedures. Selected metals (Fe, Ni, Mg, Ca, Cu, Zn, Hg, Pb) were analyzed utilizing flame atomic absorption spectroscopy. Drainage from the Bast Mine is actively treated with hydrated lime before the water is piped down to Big Mine Run. pH and alkalinity values were much higher at the outflow compared to those in the water with which it merged. The two waters could be visibly distinguished some distance downstream. pH values decreased, sulfate and dissolved iron increased and alkalinity was reduced to zero until the confluence with Mahanoy Creek. The high alkalinity, turbidity, TDS and calcium values in Mahanoy Creek were somewhat reduced downstream of the confluence with the much lower discharge Big Mine Run.
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