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Meek, F. A., Jr., Skousen, J. G., & Ziemkiewicz, P. F. (1996). Evaluation of acid prevention techniques used in surface mining. In Acid mine drainage control and treatment. Morgantown: West Virginia University and the National Mine Land Reclamation Center.
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McConchie, D. M., Clark, M., Hanahan, C., & Baun, R. (2000). New treatments for the old problems of acid mine drainage and sulphidic mine tailings storage.
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Matlock, M. M., Howerton, B. S., & Atwood, D. A. (2002). Chemical precipitation of heavy metals from acid mine drainage. Water Res, 36(19), 4757–4764.
Abstract: The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR).
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Magdziorz, A., & Sewerynski, J. (2000). The use of membrane technique in mineralised water treatment for drinking and domestic purposes at “Pokoj” coal mine district under liquidation. In A. Rozkowski (Ed.), 7th international Mine Water Association congress; Mine water and the environment (pp. 430–442). Sosnowiec: Uniwersytet Slaski.
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Lin, C., Lu, W., & Wu, Y. (2005). Agricultural soils irrigated with acidic mine water: Acidity, heavy metals, and crop contamination. Australian Journal of Soil Research, 43(7), 819–826.
Abstract: Agricultural soils irrigated with acidic mine water from the Guangdong Dabaoshan Mine, China, were investigated. The pH of the soils could be as low as 3.9. However, most of the mineral acids introduced into the soils by irrigation were transformed to insoluble forms through acid buffering processes and thus temporarily stored in the soils. Different heavy metals exhibited different fraction distribution patterns, with Zn and Cu being mainly associated with organic matter and Pb being primarily bound to oxides (statistically significant at P = 0.05). Although the mean of exchangeable Cd was greatest among the Cd fractions, there was no statistically significant difference between the exchangeable Cd and the oxide-bound Cd (the 2nd greatest fraction) or between the exchangeable Cd and the carbonate-bound Cd (the 3rd greatest fraction). It was also found that there were generally good relationships between the concentrations of various Zn, Cu, Pb, and Cd fractions and pH, suggesting that a major proportion of each heavy metal in the soils was mainly derived from the acidic irrigation water. The results also show that the crops grown in these soils were highly contaminated by heavy metals, particularly Cd. The concentration of Cd in the edible portions of most crops was far in excess of the limits set in China National Standards for Vegetables and Fruits and this can be attributable to the extremely high transfer rate of Cd from the soils to the crops under the cropping system adopted in the study area. < copyright > CSIRO 2005.
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