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Schueck, J. H. (1995). Limestone diversion wells; a low-maintenance, cost-effective method for treating acid-mine drainage with limestone. In C. R. Carnein, & J. H. Way (Eds.), Guidebook for the Annual Field Conference of Pennsylvania Geologists, vol.60 Applied geology in the Lock Haven and Williamsport region, Clinton and Lycoming counties, northcentral Pennsylvania (pp. 9–12).
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Scharp, R. A., Kawahara, F., Burckle, J., Allan, J., & Govind, R. (2002). Recovery of metals from acid mine drainage Hardrock mining 2002; issues shaping the industry..
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Sato, D., & Tazaki, K. (2000). Calcification treatment of mine drainage and depositional formula of heavy metals. Chikyu Kagaku = Earth Science, 54(5), 328–336.
Abstract: Depositional formula of heavy metals after disposal of the mine drainage from the Ogoya Mine in Ishikawa Prefecture, Japan, was mineralogically investigated. Strong acidic wastewater (pH 3.5) from pithead of the mine contains high concentration of heavy metals. In this mine, neutralizing coagulation treatment is going on by slaked lime (calcium hydroxides: Ca(OH) (sub 2) ). Core samples were collected at disposal pond to which the treated wastewater flows. The core samples were divided into 44 layers based on the color variation. The mineralogical and chemical compositions of each layer were analyzed by an X-ray powder diffractometer (XRD), an energy dispersive X-ray fluorescence analyzer (ED-XRF) and a NCS elemental analyzer. The upper parts are rich in brown colored layers, whereas discolored are the deeper parts. The color variation is relevant to Fe concentration. Brown colored core sections are composed of abundant hydrous ferric oxides with heavy metals, such as Cu, Zn, and Cd. On the other hand, S concentration gradually increases with depth. XRD data indicated that calcite decreases with increasing depth, and ettringite is produced at the deeper parts. Cd concentration shows similar vertical profile to those of calcite and ettringite. The results revealed that hydrous ferric oxides, calcite and ettringite are formed on deposition, whereby incorporating the heavy metals.
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Sanders, F., Rahe, J., Pastor, D., & Anderson, R. (1999). Wetlands treat mine runoff. Civil Engineering, 69(1), 53–55.
Abstract: In the late 1890s, silver, lead and zinc deposits were discovered along the headwaters of the Blackfoot River, northeast of Missoula, Mont. Settlers began mining the metals in earnest, and eventually the mines became known as the Upper Blackfoot Mining Complex (UBMC). Many of the mines were operated long enough to supply metals for World War II weaponry, but after the war the mines were abandoned, and by the 1960s, their orange-tainted runoff began to concern both passersby and state officials. In 1991, the state contacted the current owners of several of those mines-including the Mike Horse and the Anaconda-to negotiate a voluntary cleanup. The American Smelting and Refining Co. (ASARCO) and the Atlantic Richfield Co. (ARCO) agreed to remediate the sites' metal-enriched, moderately to severely acidic drainage, which was discharging into the upper Blackfoot River. As part of effort to reclaim the Mike Horse and Anaconda mines, engineers with McCulley, Frick and Gilman Inc. (MFG), Boulder, Colo., developed an integrated, passive wetland treatment system that will take several years to reach full treatment capacity in the high-elevation environment, but will last for decades. (Constructed and restored wetlands have also been part of the remediation of other UBMC mines, such as the Carbonate and Paymaster mines.) The Mike Horse and Anaconda system, designed to meet National Pollutant Discharge Elimination Systems (NPDES) restrictions, concentrates primarily on zinc and iron and, to a lesser extent, on copper, lead and other metals.
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Rukin, N. (2003). Whittle mine water treatment system: In-river attenuation of manganese. Land Contam. Reclam., 11(2), 137–144.
Abstract: Much work has been undertaken on the design of treatment systems to remove iron from ochreous mine water discharges. Unlike iron, manganese removal is far more difficult and generally requires active chemical dosing rather than passive treatment. The need for manganese removal can therefore significantly change the economics, management attention and sustainability of a site. Understanding natural attenuation of manganese in river systems is therefore key to deciding whether (active) manganese treatment is needed to protect downstream receptors. Nuttall (2002, this volume) describes the effectiveness of the passive treatment system at Whittle in reducing both iron and manganese concentrations in ochreous mine waters. This paper discusses the results of in-river monitoring and provides evidence for manganese removal downstream of the discharge point. In addition to dilution, attenuation appears to be in the order of 20 to 50%, depending on relative rates of mine water discharge and river flows. Such attenuation means that active treatment may not be needed for the long-term operation of the Whittle scheme. Operation of the scheme commenced in July 2002, with monitoring to further examine evidence for manganese attenuation and any impact on the ecology of the recipient watercourses.
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