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Demchak, J.; Morrow, T.; Skousen, J.; Donovan, J.J.; Rose, A.W. |
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Title |
Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites |
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Journal Article |
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2001 |
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Geochemistry – Exploration, Environment, Analysis |
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1 |
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1 |
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71-80 |
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acid mine drainage alkalinity anaerobic environment Appalachian Plateau Appalachians carbonate rocks Clearfield County Pennsylvania constructed wetlands Eh equilibrium Filson Wetlands ground water Howe Bridge Wetlands hydrology Jefferson County Pennsylvania limestone McKinley Wetlands Mill Creek watershed Moose Creek movement North America passive methods Pennsylvania pH pollution reclamation sedimentary rocks Sommerville Wetlands systems United States water treatment watersheds wetlands 22 Environmental geology 02B Hydrochemistry |
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Abstract |
Acid mine drainage (AMD) is a serious problem in many watersheds where coal is mined. Passive treatments, such as wetlands and anoxic limestone drains (ALDs), have been developed, but these technologies show varying treatment efficiencies. A new passive treatment technique is a vertical flow wetland or successive alkalinity producing system (SAPS). Four SAPS in Pennsylvania were studied to determine changes in water chemistry from inflow to outflow. The Howe Bridge SAPS removed about 130 mg l (super -1) (40%) of the inflow acidity concentration and about 100 mg l (super -1) (60%) iron (Fe). The Filson 1 SAPS removed 68 mg l (super -1) (26%) acidity, 20 mg l (super -1) (83%) Fe and 6 mg l (super -1) (35%) aluminium (Al). The Sommerville SAPS removed 112 mg l (super -1) (31%) acidity, exported Fe, and removed 13 mg l (super -1) (30%) Al. The McKinley SAPS removed 54 mg l (super -1) (91%) acidity and 5 mg l (super -1) (90%) Fe. Acid removal rates at our four sites were 17 (HB), 52 (Filson1), 18 (Sommerville) and 11 (McKinley) g of acid per m (super 2) of surface wetland area per day (g/m (super 2) d (super -1) ). Calcium (Ca) concentrations in the SAPS effluents were increased between 8 and 57 mg l (super -1) at these sites. Equilibrators, which were inserted into compost layers to evaluate redox conditions at our sites, showed that reducing conditions were generally found at 60 cm compost depths and oxidized conditions were found at 30 cm compost depths. Deeply oxidized zones substantiated observations that channel flow was occurring through some parts of the compost. The Howe Bridge site has not declined in treatment efficiency over a six year treatment life. The SAPS construction costs were equal to about seven years of NaOH chemical treatment costs and 30 years of lime treatment costs. So, if the SAPS treatment longevity is seven years or greater and comparable effluent water quality was achieved, the SAPS construction was cost effective compared to NaOH chemical treatment. Construction recommendations for SAPS include a minimum of 50 cm of compost thickness, periodic replacement or addition of fresh compost material, and increasing the number of drainage pipes underlying the limestone. |
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1467-7873 |
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Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites; 2002-008380; References: 15; illus. incl. 5 tables United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 16518 |
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58 |
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Davies, G.J.; Holmes, M.; Wireman, M.; King, K.; Gertson, J.N.; Stefanic, J.M. |
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Title |
Water tracing at scales of hours to decades as an aid to estimating hydraulic characteristics of the Leadville Mine drainage tunnel |
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2001 |
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acid mine drainage Arkansas River Colorado drainage dye tracers field studies fluorescence ground water Lake County Colorado Leadville Mine Leadville mining district pH quantitative analysis recharge surveys tunnels United States water treatment 30 Engineering geology 21 Hydrogeology |
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The Leadville Mine Drainage Tunnel (LMDT) is a 3.3 kilometer structure that was constructed in the complicated geology of the Leadville mine district in the 1940's. Discharge from the LMDT is impacted by heavy metals and is treated at a plant built in 1992 operated by the United States Bureau of Reclamation. On the surface waste rock and other remnants of the mining operations litter the landscape and this material is exposed to precipitation. As a result of contact with this material, surface water often has pH of less than 3 and its containment and disposal is necessary before it impacts surface drainage and the nearby Arkansas River. Using a borehole drilled into the mine workings the U.S. EPA has devised a plan in which the impacted water is contained on the surface which then can be discharged into the mine workings to discharge from the LMDT and be treated. The percentage of water discharging from the mining district along the drainage tunnel is unknown, and since there is no access, information about the condition of the tunnel with regards to blockages is also relatively obscure. Application of quantitative water tracing using fluorescent dyes was used to model the flow parameters at the scale of hours in the tunnel and evaluate the likelihood of blockages. Because the tunnel has intersected several lithologies and faults, other locations such as discharging shafts, adits and surface streams that could be hydraulically connected to the LMDT were also monitored. An initial tracer experiment was done using an instantaneous injection, which was followed by additional injections of water. Another tracer injection was done when there was a continuous flow of impacted water into the workings. Analysis of the tracer concentration responses at water-filled shafts and at the portal were used to model the flow along the tunnel and estimate several hydraulic parameters. Waters in these settings are mixtures of components with different residence times, so, qualitative tritium data were used to evaluate residence times of decades. The combined injected tracer and tritium data as well as other geochemical data were used to infer the nature of flow and recharge into the tunnel. |
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Abstracts with Programs - Geological Society of America |
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Geological Society of America, 2001 annual meeting |
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2004-013418; Geological Society of America, 2001 annual meeting, Boston, MA, United States, Nov. 1-10, 2001; GeoRef; English |
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CBU @ c.wolke @ 16511 |
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408 |
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Chung, I.J. |
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Immobilization of arsenic in tailing by using iron and hydrogen peroxide |
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2001 |
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Environ. Technol. |
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22 |
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7 |
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831-835 |
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mine water treatment |
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Under environmental conditions, arsenic (As) reveals anionic behavior and is converted into various forms in accordance with the Eh/pH condition. This causes the difficulty of treating As with other heavy metals in tailing. This study was carried out to develop the immobilization method of arsenic in tailing as ferric arsenate (FeAsO4) using hydrogen peroxide. According to experimental results, the extracted concentrations of arsenic and iron (Fe) from tailing were reduced up to 84% and 93%, respectively. In the experiment using pure Pyrite (FeS2) and As solution, As concentration decreased with an increase of hydrogen peroxide dosage. The experimental results of re-extraction showed that only 10% of As and 20% of Fe were extracted in the case of using hydrogen peroxide. As a result, the long-term stability of this method was clarified. |
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Immobilization of arsenic in tailing by using iron and hydrogen peroxide; Wos:000170195000008; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17046 |
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123 |
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Carlson, L.; Kumpulainen, S. |
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Retention of harmful elements by ochreous precipitates of iron |
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2001 |
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Tutkimusraportti Geologian Tutkimuskeskus |
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154 |
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30-33 |
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Surface water quality Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 9) geological abstracts: environmental geology (72 14 2) iron oxide precipitation chemistry sulfate arsenate heavy metal pH water pollution remediation |
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The capability of soil fines to fix harmful elements, e.g. heavy metals and arsenic, depends on specific surface area and other characteristics, such as surface charge. In the pH-range typical of natural waters (pH 5,5-7,5), the surfaces of fine-grained silicate particles and manganese oxides are negatively charged; consequently cations, such as heavy metals, fix effectively to them. The iron oxide surfaces are usually positively charged and typically fix anions, such as sulphate and arsenate. Retention of anions is especially extensive to precipitates formed from acid mine drainage (pH 2,5-5,0). For example, precipitates found at Paroistenjarvi mine, Finland, contain more than 70 g/kg of arsenic (dry matter). Adsorbed anions, e.g. sulphate, enhance the capacity of precipitate to fix heavy metal cations in low-pH environments. |
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L. Carlson, Tehtaankatu 25 A 4, Helsinki FIN-00150, Finland liisa.carlson@kolumbus.fi |
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0781-4240 |
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Retention of harmful elements by ochreous precipitates of iron; 2392974; Oksidiset rautasaostumat haitallisten aineiden pidattajina. Finland 7; Geobase |
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CBU @ c.wolke @ 17533 |
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421 |
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Banks, S.B.; Banks, D. |
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Abandoned mines drainage; impact assessment and mitigation of discharges from coal mines in the UK |
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2001 |
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Geoenvironmental engineering Engineering Geology |
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31-37 |
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abandoned mines coal mines cost discharge drainage England environmental effects Europe feasibility studies Great Britain mine drainage mines mitigation pollution remediation Scotland United Kingdom Western Europe 22, Environmental geology |
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The UK has a legacy of pollution caused by discharges from abandoned coal mines, with the potential for further pollution by new discharges as groundwaters continue to rebound to their natural levels. In 1995, the Coal Authority initiated a scoping study of 30 gravity discharges from abandoned coal mines in England and Scotland. Mining information, geological information and water quality data were collated and interpreted in order to allow a preliminary assessment of the source and nature of each of the discharges. An assessment of the potential for remediation was made on the basis of the feasibility and relative costs of alternative remediation measures. Environmental impacts of the discharges and of the proposed remediation schemes were also assessed. The results, together with previous Coal Authority studies of discharges in Wales, were used by the Coal Authority, in collaboration with the former National Rivers Authority and the former Forth and Clyde River Purification Boards, to rank discharge sites in order of priority for remediation. |
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60 |
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Yong, R.N.; Thomas, H.R. |
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Abandoned mines drainage; impact assessment and mitigation of discharges from coal mines in the UK; GeoRef; English; 2001-052748; British Geotechnical Society, second conference on Geoenvironmental engineering, London, United Kingdom, Sept. 1999 References: 12; illus. incl. 2 tables |
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CBU @ c.wolke @ 16515 |
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31 |
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