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Bamforth, S.M. |
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Title |
Manganese removal from mine waters – investigating the occurrence and importance of manganese carbonates |
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Journal Article |
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Year |
2006 |
Publication |
Appl. Geochem. |
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21 |
Issue |
8 |
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1274-1287 |
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Keywords |
mine water treatment |
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Abstract |
Manganese is a common contaminant of mine water and other waste waters. Due to its high solubility over a wide pH range, it is notoriously difficult to remove from contaminated waters. Previous systems that effectively remove Mn from mine waters have involved oxidising the soluble Mn(II) species at an elevated pH using substrates such as limestone and dolomites. However it is currently unclear what effect the substrate type has upon abiotic Mn removal compared to biotic removal by in situ micro-organisms (biofilms). In order to investigate the relationship between substrate type, Mn precipitation and the biofilm community, net-alkaline Mn-contaminated mine water was treated in reactors containing one of the pure materials: dolomite, limestone, magnesite and quartzite. Mine water chemistry and Mn removal rates were monitored over a 3-month period in continuous-flow reactors. For all substrates except quartzite, Mn was removed from the mine water during this period, and Mn minerals precipitated in all cases. In addition, the plastic from which the reactor was made played a role in Mn removal. Manganese oxyhydroxides were formed in all the reactors; however, Mn carbonates (specifically kutnahorite) were only identified in the reactors containing quartzite and on the reactor plastic. Magnesium-rich calcites were identified in the dolomite and magnesite reactors, suggesting that the Mg from the substrate minerals may have inhibited Mn carbonate formation. Biofilm community development and composition on all the substrates was also monitored over the 3-month period using denaturing gradient gel electrophoresis (DGGE). The DGGE profiles in all reactors showed no change with time and no difference between substrate types, suggesting that any microbiological effects are independent of mineral substrate. The identification of Mn carbonates in these systems has important implications for the design of Mn treatment systems in that the provision of a carbonate-rich substrate may not be necessary for successful Mn precipitation. (c) 2006 Elsevier Ltd. All rights reserved. |
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Manganese removal from mine waters – investigating the occurrence and importance of manganese carbonates; Wos:000240297600004; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16916 |
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107 |
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Bearcock, J.M. |
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Title |
Accelerated precipitation of ochre for mine water remediation |
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Journal Article |
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2006 |
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Geochim. Cosmochim. Acta |
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70 |
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18 |
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A42-A42 |
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mine water treatment |
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Accelerated precipitation of ochre for mine water remediation; Wos:000241374200094; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16919 |
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104 |
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Canty, G.A.; Everett, J.W. |
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Title |
Injection of Fluidized Bed Combustion Ash into Mine Workings for Treatment of Acid Mine Drainage |
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Journal Article |
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2006 |
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Mine Water Env. |
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25 |
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1 |
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45-55 |
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acid mine drainage AMD alkaline injection technology fluidized bed combustion ash Oklahoma |
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A demonstration project was conducted to investigate treating acid mine water by alkaline injection technology (AIT). A total of 379 t of alkaline coal combustion byproduct was injected into in an eastern Oklahoma drift coal mine. AIT increased the pH and alkalinity, and reduced acidity and metal loading. Although large improvements in water quality were only observed for 15 months before the effluent water chemistry appeared to approach pre-injection conditions, a review of the data four years after injection identified statistically significant changes in the mine discharge compared to pre-injection conditions. Decreases in acidity (23%), iron (18%), and aluminium (47%) were observed, while an increase in pH (0.35 units) was noted. Presumably, the mine environment reached quasi-equilibrium with the alkalinity introduced to the system. |
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1025-9112 |
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Injection of Fluidized Bed Combustion Ash into Mine Workings for Treatment of Acid Mine Drainage; 1; FG 6 Abb., 1 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17319 |
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422 |
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Ciftci, H.; Akcil, A. |
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Title |
Asidik maden drenajinin (AMD) giderilmesinde uygulanan biyolojik yontemler. Biological methods applied in the treatment of acid mine drainage (AMD) |
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Journal Article |
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2006 |
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Madencilik = The = Journal of the Chamber of Mining Engineers of Turkey |
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45 |
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1 |
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35-45 |
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acid mine drainage biodegradation methods microorganisms oxidation pollutants pollution remediation sulfides 22, Environmental geology |
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Acidic mine drainage (AMD) is a serious environmental problem in mining areas throughout the world. AMD occurs as a result of the natural oxidation of sulfide minerals when they are exposed to oxygen and water during their disposal and storage at the mining areas. Because it includes low pH and high concentrations of dissolved metals and sulphates, AMD can potentially damage to the environment. If the formation of AMD can't be prevented and controlled, it must be collected and treated to remove acidity and reduce the concentration of heavy metals and suspended solids before its release to the environment. Different types of microorganisms in the treatment of AMD can play a very important role in the development and the application of microbiological prevention, control and treatment technologies. The purpose of this article is to give information about the passive biological methods used in the treatment and the control of AMD and the role of microorganisms in these methods. |
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0024-9416 |
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Asidik maden drenajinin (AMD) giderilmesinde uygulanan biyolojik yontemler. Biological methods applied in the treatment of acid mine drainage (AMD); 2006-075215; References: 58 Turkey (TUR); GeoRef; Turkish |
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CBU @ c.wolke @ 16444 |
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416 |
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Conca, J.L.; Wright, J. |
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An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
Type |
Journal Article |
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Year |
2006 |
Publication |
Appl. Geochem. |
Abbreviated Journal |
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21 |
Issue |
12 |
Pages |
2188-2200 |
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Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
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Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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CBU @ c.wolke @ 17248 |
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44 |
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