| Records |
Author  |
Totsche, O.; Fyson, A.; Kalin, M.; Steinberg Christian, E.W. |
| Title |
Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters |
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Journal Article |
| Year |
2006 |
Publication |
ESPR Environmental Science and Pollution Research |
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| Volume |
13 |
Issue |
4 |
Pages |
215-224 |
| Keywords |
Abwasseraufbereitung Bergbau Titration Säuregehalt Grundwasser Pufferlösung Neutralisation Titrationskurve Bergbauabwasser |
| Abstract |
The acidification of mine waters is generally caused by metal sulfide oxidation, related to mining activities. These waters are characterized by low pH and high acidity due to strong buffering systems. The standard acidity parameter, the BNC (Base Neutralization Capacity), is determined by endpoint titration, and reflects a cumulative parameter of both hydrogen ions and all buffering systems, but does not give information on the individual buffer systems. It is demonstrated that a detailed interpretation of titration curves can provide information about the strength of the buffering systems. The buffering systems are of importance for environmental studies and treatment of acidic mining waters. Titrations were carried out by means of an automatic titrator using acidic mining waters from Germany and Canada. The curves were interpreted, compared with each other, to endpoint titration results and to elemental concentrations contained therein. The titration curves were highly reproducible, and contained information about the strength of the buffer systems present. Interpretations are given, and the classification and comparison of acidic mining waters, by the nature and strength of their buffering systems derived from titration curves are discussed. The BNC-values calculated from the curves were more precise than the ones determined by the standard endpoint titration method. Due to the complex buffer mechanisms in acidic mining waters, the calculation of major metal concentrations from the shape of the titration curve resulted in estimates, which should not be confused with precise elemental analysis results. Conclusion. Titration curves provide an inexpensive, valuable and versatile tool, by which to obtain sophisticated information of the acidity in acidic water. The information about the strength of the present buffer systems can help to understand and document the complex nature of acidic mining water buffer systems. Finally, the interpretation of titration curves could help to improve treatment measurements and the ecological understanding of these acidic waters. |
| Address |
Leibniz-Institut für Gewässerökologie und Binnenfischerei, Berlin, DE; Boojum Research, Toronto, CA; Humboldt-Universität Berlin, DE |
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0944-1344 |
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Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters; 39481, BERG , 13.11.06; Words: 519; 200610 05282; 10 Seiten, 15 Bilder, 2 Tabellen, 39 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3BX *chemische Grundlagen* 3IFC *Messung und Prüfung chemischer Größen, chemische Analytik* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
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CBU @ c.wolke @ 17580 |
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224 |
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Simmons, J.A.; Andrew, T.; Arnold, A.; Bee, N.; Bennett, J.; Grundman, M.; Johnson, K.; Shepherd, R. |
| Title |
Small-Scale Chemical Changes Caused by In-stream Limestone Sand Additions to Streams |
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Journal Article |
| Year |
2006 |
Publication |
Mine Water Env. |
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25 |
Issue |
4 |
Pages |
241-245 |
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acid mine drainage aluminum calcium limestone sand sediment stream liming West Virginia |
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In-stream limestone sand addition (ILSA) has been employed as the final treatment for acid mine drainage discharges at Swamp Run in central West Virginia for six years. To determine the small-scale longitudinal variation in stream water and sediment chemistry and stream biota, we sampled one to three locations upstream of the ILSA site and six locations downstream. Addition of limestone sand significantly increased calcium and aluminum concentrations in sediment and increased the pH, calcium, and total suspended solids of the stream water. Increases in alkalinity were not significant. The number of benthic macroinvertebrate taxa was significantly reduced but there was no effect on periphyton biomass. Dissolved aluminum concentration in stream water was reduced, apparently by precipitation into the stream sediment. |
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1025-9112 |
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Small-Scale Chemical Changes Caused by In-stream Limestone Sand Additions to Streams; 1; FG 4 Abb., 2 Tab.; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17420 |
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248 |
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Sierra-Alvarez, R. |
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Biological treatment of heavy metals in acid mine drainage using sulfate reducing bioreactors |
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Journal Article |
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2006 |
Publication |
Water Sci. Technol. |
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| Volume |
54 |
Issue |
2 |
Pages |
179-185 |
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mine water treatment |
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The uncontrolled release of acid mine drainage (AMD) from abandoned mines and tailing piles threatens water resources in many sites worldwide. AMD introduces elevated concentrations of sulfate ions and dissolved heavy metals as well as high acidity levels to groundwater and receiving surface water. Anaerobic biological processes relying on the activity of sulfate reducing bacteria are being considered for the treatment of AMD and other heavy metal containing effluents. Biogenic sulfides form insoluble complexes with heavy metals resulting in their precipitation. The objective of this study was to investigate the remediation of AMD in sulfate reducing bioreactors inoculated with anaerobic granular sludge and fed V with an influent containing ethanol. Biological treatment of an acidic (pH 4.0) synthetic AMD containing high concentrations of heavy metals (100 Mg Cu2+vertical bar(-1); 10 mg Ni2+vertical bar(-1), 10 mg Zn2+vertical bar(-1)) increased the effluent pH level to 7.0-7.2 and resulted in metal removal efficiencies exceeding 99.2%. The highest metal precipitation Cn rates attained for Cu, Ni and Zn averaged 92.5, 14.6 and 15.8 mg metal l(-1) of reactor d(-1). The results of this work demonstrate that an ethanol-fed sulfidogenic reactor was highly effective to remove heavy metal contamination and neutralized the acidity of the synthetic wastewater. |
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Biological treatment of heavy metals in acid mine drainage using sulfate reducing bioreactors; Wos:000240449300024; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16943 |
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106 |
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| Author |
Sibrell, P.L. |
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Limestone fluidized bed treatment of acid-impacted water at the Craig Brook National Fish Hatchery, Maine, USA |
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Journal Article |
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2006 |
Publication |
Aquacultural Engineering |
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34 |
Issue |
2 |
Pages |
61-71 |
| Keywords |
mine water treatment |
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Decades of atmospheric acid deposition have resulted in widespread lake and river acidification in the northeastern U.S. Biological effects of acidification include increased mortality of sensitive aquatic species Such as the endangered Atlantic salmon (Salmo salar). The purpose of this paper is to describe the development of a limestone-based fluidized bed system for the treatment of acid-impacted waters. The treatment system was tested at the Craig Brook National Fish Hatchery in East Orland, Maine over a period of 3 years. The product water from the treatment system was diluted with hatchery water to prepare water supplies with three different levels of alkalinity for testing of fish health and Survival. Based on positive results from a prototype system used in the first year of the study, a larger demonstration system was used in the second and third years with the objective of decreasing operating costs. Carbon dioxide was used to accelerate limestone dissolution, and was the major factor in system performance, as evidenced by the model result: Alk = 72.84 X P(CO2)(1/2); R-2 = 0.975. No significant acidic incursions were noted for the control water over the course of the Study. Had these incursions occurred, survivability in the untreated water would likely have been much more severely impacted. Treated water consistently provided elevated alkalinity and pH above that of the hatchery source water. (C) 2005 Elsevier B.V. All rights reserved. |
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Limestone fluidized bed treatment of acid-impacted water at the Craig Brook National Fish Hatchery, Maine, USA; Wos:000235568800001; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16942 |
Serial |
113 |
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| Author |
Sheoran, A.S.; Sheoran, V. |
| Title |
Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review |
Type |
Journal Article |
| Year |
2006 |
Publication |
Minerals Engineering |
Abbreviated Journal |
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| Volume |
19 |
Issue |
2 |
Pages |
105-116 |
| Keywords |
Acid mine drainage Metal removal mechanism Wetlands |
| Abstract |
Acid mine drainage (AMD) is one of the most significant environmental challenges facing the mining industry worldwide. Water infiltrating through the metal sulphide minerals, effluents of mineral processing plants and seepage from tailing dams becomes acidic and this acidic nature of the solution allows the metals to be transported in their most soluble form. The conventional treatment technologies used in the treatment of acid mine drainage are expensive both in terms of operating and capital costs. One of the methods of achieving compliance using passive treatment systems at low cost, producing treated water pollution free, and fostering a community responsibility for acid mine water treatment involves the use of wetland treatment system. These wetlands absorb and bind heavy metals and make them slowly concentrated in the sedimentary deposits to become part of the geological cycle. In this paper a critical review of the heavy metal removal mechanism involving various physical, chemical and biological processes, which govern wetland performance, have been made. This information is important for the siting and use of wetlands for remediation of heavy metals. |
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Heavy metal removal mechanism of acid mine drainage in wetlands: A critical review; Science Direct |
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CBU @ c.wolke @ 17252 |
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41 |
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