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Matlock, M.M.; Howerton, B.S.; Atwood, D.A. |
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Chemical precipitation of heavy metals from acid mine drainage |
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Journal Article |
Year |
2002 |
Publication |
Water Res |
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Volume |
36 |
Issue |
19 |
Pages |
4757-4764 |
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mine water treatment BDET Acid mine drainage Water treatment Remediation Heavy metals Chemical precipitation Mercury Iron |
Abstract |
The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR). |
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0043-1354 |
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Nov.; Chemical precipitation of heavy metals from acid mine drainage; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/15005.pdf; Science Direct |
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CBU @ c.wolke @ 15005 |
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48 |
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Tsukamoto, T.K.; Miller, G.C. |
Title |
Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage |
Type |
Journal Article |
Year |
1999 |
Publication |
Water Res. |
Abbreviated Journal |
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Volume |
33 |
Issue |
6 |
Pages |
1365-1370 |
Keywords |
mine water treatment mining activity sulfate-reducing bacteria microbial activity acid mine drainage methanol passive treatment systems sulfate-reducing bacterium sp-nov |
Abstract |
Sulfate reducing passive bioreactors are increasingly being used to remove metals and raise the pH of acidic waste streams from abandoned mines. These systems commonly use a variety of organic substrates (i.e. manure, wood chips) for sulfate reduction. The effectiveness of these systems decreases as easily accessible reducing equivalents are consumed in the substrate through microbial activity. Using column studies at room temperature (23-26 degrees C), we investigated the addition of lactate and methanol to a depleted manure substrate as a method to reactivate a bioreactor that had lost >95% of sulfate reduction activity. A preliminary experiment compared sulfate removal in gravity fed, flow through bioreactors in which similar masses of each substrate were added to the influent solution. Addition of 148 mg/l lactate resulted in a 69% reduction in sulfate concentration from 300 to 92 mg/l, while addition of 144 mg/l methanol resulted in an 88% reduction in sulfate concentration from 300 to 36 mg/l. Because methanol was found to be an effective sulfate reducing substrate, it was chosen for further experiments due to its inherent physical properties (cost, low freezing point and low viscosity liquid) that make it a superior substrate for remote, high elevation sites where freezing temperatures would hamper the use of aqueous solutions. In these column studies, water containing sulfate and ferrous iron was gravity-fed through the bioreactor columns, along with predetermined methanol concentrations containing reducing equivalents to remove 54% of the sulfate. Following an acclimation period for the columns, sulfate concentrations were reduced from of 900 mg/l in the influent to 454 mg/l in the effluent, that reflects a 93% efficiency of electrons from the donor to the terminal electron acceptor. Iron concentrations were reduced from 100 to 2 mg/l and the pH increased nearly 2 units. (C) 1999 Elsevier Science Ltd. |
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0043-1354 |
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Apr; Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage; Isi:000079485400004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10197.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 10197 |
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50 |
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Yeon, K.-M.; Park, J.-S.; Lee, C.-H.; Kim, S.-M. |
Title |
Membrane coupled high-performance compact reactor: A new MBR system for advanced wastewater treatment |
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Journal Article |
Year |
2005 |
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Water Res |
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39 |
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10 |
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1954-1961 |
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0043-1354 |
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Membrane coupled high-performance compact reactor: A new MBR system for advanced wastewater treatment; 1674274289; UB Bayreuth <703> TU Berlin <83> UB Braunschweig <84> SUB Bremen <46> UB Cottbus <Co 1> SLUB Dresden <14> SUB Goettingen <7> SUB+Uni Hamburg <18> TUB Hamburg <830> TIB/UB Hannover <89> UB Ilmenau <Ilm 1> UB Karlsruhe <90> ULB + FH Merseburg <3/55> BSB München <12> Österreichische ZB Physik, Wie; OLC-SSG Technik – Online Contents-Sondersammelgebiete |
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CBU @ c.wolke @ 2188 |
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201 |
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