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Hart, W. M. (1992). Prediction and amelioration of acid mine drainage. Ph.D. thesis, West Virginia University,, Morgantown.
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Hazen, J. M. (2000). Acid mine drainage characterization and remediation using a combination of hydrometric measurements, isotopes and dissolved solutes. Ph.D. thesis, University of Colorado,, .
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Heal, K. V., & Salt, C. A. (1999). Treatment of acidic metal-rich drainage from reclaimed ironstone mine spoil. Water Sci. Technol., 39(12), 141–148.
Abstract: Ironstone mine spoil leaves a legacy of land contamination and diffuse water pollution with acidic, metal-rich drainage. Reclamation for woodland may exacerbate water pollution due to spoil amendment and disturbance. Constructed wetland systems (CWS) are increasingly used for treating acid mine drainage but their performance is poorly understood. A combined approach was used to reclaim the Benhar ironstone spoil heap in Central Scotland. Trees have been planted in spoil treated with dried pelleted sewage sludge, limestone and peat. Spoil drainage (pH 2.7, 247 mg l-1 total Fe) passes through a CWS. Spoil throughflow, surface water chemistry and CWS performance were monitored for 12 months after reclamation. Acidity, Fe, Mn and Al concentrations declined in throughflow after reclamation, although this effect was not uniform. Soluble reactive P has been mobilised from the sewage sludge in residual areas of spoil acidity, but losses of other nutrients were short-lived. The CWS removes on average 33 % and 20-40 % of acidity and metal inputs but removal rates decrease in winter. Spoil reclamation has been successful in enabling vegetation establishment but has also increased Fe and Mn concentrations in surface drainage from the site, even after passage through the CWS.
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Hellier, W. W., Giovannitti, E. F., & Slack, P. T. (1994). Best professional judgement analysis for constructed wetlands as a best available technology for the treatment of post-mining groundwater seeps. In Special Publication – United States. Bureau of Mines, Report: BUMINES-SP-06A-94 (pp. 60–69). Proceedings of the International land reclamation and mine drainage conference and Third international conference on The abatement of acidic drainage; Volume 1 of 4; Mine drainage.
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Herbert, R. B., Jr., Benner, S. G., & Blowes, D. W. (1998). Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation. In M. Herbert, & K. Kovar (Eds.), Groundwater Quality: Remediation and Protection (pp. 451–457). IAHS-AISH Publication, vol.250.
Abstract: A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997.
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