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Author (up) Greben, H.A.; Matshusa, M.P.; Maree, J.P.
Title Type Book Whole
Year 2005 Publication Abbreviated Journal
Volume Issue Pages 339-345
Keywords water pollution biological Sulphate removal technology sulphate acidity metals treatment technique
Abstract Mining is implicated as a significant contributor to water pollution, the prime reason being, that pyrites oxidize to sulphuric acid when exposed to air and water. Mine effluents, often containing sulphate, acidity and metals, should be treated to render it suitable for re-use in the mining industry, for irrigation of crops or for discharge in water bodies. This study describes the removal of all three mentioned pollutants in mine effluents, from different origins, containing different concentrations of various metals. The objectives were achieved, applying the biological sulphate removal technology, using ethanol as the carbon and energy source. It was shown that diluting the mine effluent with the effluent from the biological treatment, the pH increased due to the alkalinity in the treated water while the metals precipitated with the produced sulphide. When this treatment regime was changed and the mine water was fed undiluted, it was found that the metals stimulated the methanogenic bacteria (MB) as trace elements. This resulted in a high COD utilization of the MB, such that too little COD was available for the SRB. Metal removal in all three studies was observed and in most instances the metals were eliminated to the required disposal concentration.
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Publisher University of Oviedo Place of Publication Oviedo Editor Loredo, J.; Pendás, F.
Language Summary Language Original Title
Series Editor Series Title Mine Water 2005 – Mine Closure Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 84-689-3415-1 Medium
Area Expedition Conference
Notes The biological Sulphate removal technology; 1; AMD ISI | Wolkersdorfer; FG 'aha' 3 Abb., 9 Tab. Approved no
Call Number CBU @ c.wolke @ 17347 Serial 367
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Author (up) Groudev, S.N.
Title Treatment of acid mine drainage by a natural wetland Type Journal Article
Year 2002 Publication Wetlands and Remediation Ii Abbreviated Journal
Volume Issue Pages 133-139
Keywords mine water treatment
Abstract Acid drainage waters generated in the copper ore deposit Elshitza. Central Bulgaria, were treated by a natural wetland located in the deposit. The waters had a pH in the range of about 2.5 – 3.5 and contained copper, cadmium, arsenic, iron, manganese and sulphates as main pollutants. The watercourse through the wetland covered a distance of about 100 in and the water flow rate varied in the range of about 0.5 – 2.0 1/s. The wetland was characterized by an abundant water and emergent vegetation and a diverse microflora. Phragmites communis was the prevalent plant species in the wetland but species of the genera Scirpus, Typha, Juncus, Carex and Poa as well as different algae were also well present. It was found that an efficient removal of the pollutants was achieved and their residual concentrations in the wetland effluents were decreased below the relevant permissible levels for water intended for use in the agriculture and/or industry. The removal was clue to different processes but the microbial dissimilatory sulphate reduction and the sorption of pollutants by the organic matter and clay minerals present in the wetland played the main role. Negative effects of the pollutants on the growth and activity of the indigenous plant and microbial communities were not observed.
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Notes Treatment of acid mine drainage by a natural wetland; Isip:000175585500017; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 17039 Serial 159
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Author (up) Groudev, S.N.; Georgiev, P.S.; Spasova, I.I.; Nicolova, M.N.
Title In situ treatment of mine waters by means of a permeable barrier Type Journal Article
Year 2000 Publication Groundwater 2000 Abbreviated Journal
Volume Issue Pages 417-418
Keywords mine water treatment
Abstract Acid ground waters contaminated with radioactive elements (U, Ra, Th), toxic heavy metals (Cu, Zn, Cd, Mn, Fe), arsenic and sulphates were treated by means of a permeable barrier. The barrier was filled with a mixture of biodegradable solid organic substrates (spent mushroom compost, sawdust and cow manure) and was inhabited by a mixed microbial community consisting of sulphate-reducing bacteria and other metabolically interdependent microorganisms. An efficient removal of the pollutants was achieved by this barrier during the different climatic seasons, even at ambient temperatures close to degrees C. The microbial dissimilatory sulphate reduction and the sorption of pollutants by the organic matter in the barrier were the main processes involved in this removal.
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Notes In situ treatment of mine waters by means of a permeable barrier; Isip:000088384300185; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 8407 Serial 173
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Author (up) Guay, R.
Title Effect of flooding of oxidized mine tailings on T-ferrooxidans and T-thiooxidans survival and acid mine drainage production: a 4 year restoration-environmental follow-up Type Journal Article
Year 1999 Publication Biohydrometallurgy and the Environment toward the Mining of the 21st Century, Pt B 1999 Abbreviated Journal
Volume 9 Issue Pages 635-643
Keywords mine water treatment
Abstract A pilot-scale study on the effect of flooding unoxidized and oxidized Cu/Zn tailings demonstrated the technical feasability of this technology to remediate a mining site where over 3 million tons of tailings were impounded. Full-scale flooding of the tailing pond with free running water was undertaken after the construction of an impervious dam; approximately 2 million m(3) of surface water at pH 7,4 completely covered the tailings after 16 months. The minimal water column over the tailings was established at 1,20 m and reached 4,5 m, depending on the site topography. Water and tailings samples were collected from 9 different locations from the surface of the man-made lake using a specially designed borer and were analyzed for pH, conductivity, iron- and sulfur-oxidizing bacteria activity and numbers as well as the sulfate reducing bacteria (SRB) population. We showed that over a four year period of flooding, the overall population of iron-oxidizers decreased considerably; their numbers drastically fell from 1 x 10(6) to 1 x 10(2) active cells per g of oxidized tailings while the SRBs increased from 10(1) to 10(5)/g. The pH of the influent, the reservoir and the effluent water remained fairly constant between 6,9 up to 7,4 over the entire period. During this time, interstitial water pH increased from 2,9 to 4,3 in flooded tailings where lime could not be incorporated in the first 20 cm of tailings; elsewhere, the pH of the tailings suspensions remained fairly constant around neutral values (pH 7,0). Dissolved oxygen was measured at fixed intervals and remained also constant between 6 and 7.5 mg/L while water temperatures fluctuated below freezing point to +20C respectively in winter and summer season.
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Notes Effect of flooding of oxidized mine tailings on T-ferrooxidans and T-thiooxidans survival and acid mine drainage production: a 4 year restoration-environmental follow-up; Isip:000086245100066; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 17121 Serial 175
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Author (up) Gusek, J.J.
Title Design challenges for large scale sulfate reducing bioreactors Type Journal Article
Year 2005 Publication Contaminated Soils, Sediments and Water: Science in the Real World, Vol 9 Abbreviated Journal
Volume 9 Issue Pages 33-44
Keywords mine water treatment
Abstract The first large-scale (1,200 gpm capacity), sulfate-reducing; bioreactor (SRBR) was constructed in 1996 to treat water from an underground lead mine in Missouri. Other large-scale SRBR systems have been built elsewhere since then. This technology holds much promise for economically treating heavy metals and has progressed steadily from the laboratory to industrial applications. Scale-up challenges include: designing for seasonal temperature variations, minimizing short circuits, changes in metal loading rate s, storm water impacts, and resistance to vandalism. However, the biggest challenge may be designing for the progressive biological degradation of the organic substrate and its effects on the hydraulics of the SRBR cells.
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Notes Design challenges for large scale sulfate reducing bioreactors; Isip:000225303300004; Times Cited: 0; ISI Web of Science Approved no
Call Number CBU @ c.wolke @ 16959 Serial 156
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