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Curi, A.C.; Granda, W.J.V.; Lima, H.M.; Sousa, W.T. |
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Title |
Zeolites and their application in the decontamination of mine waste water |
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2006 |
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Informacion Tecnologica |
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17 |
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6 |
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111-118 |
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adsorption decontamination effluents industrial waste ion exchange metallurgical industries metallurgy mining mining industry porosity wastewater treatment zeolites zeolites decontamination mine waste water genesis porosity adsorption ionic exchange mineral metallurgical effluents mercury pollution artisan mining activities heavy metals removal metal mining effluents mercury vapors ovens fire amalgams Manufacturing and Production |
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Abstract |
This paper describes the genesis, structure and classification of natural zeolites, including their most relevant properties such as porosity, adsorption and ionic exchange. The use of natural zeolites in the treatment of effluents containing heavy metals is reviewed based on current literature. These uses are focused on mineral-metallurgical effluents and mercury pollution related to artisan mining activities. The study shows that natural zeolites are efficient in removal of heavy metals in metal mining effluents, can be produced and improved at a low cost, and can also be used to adsorb mercury vapors from ovens used to fire amalgams. |
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0716-8756 |
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Zeolites and their application in the decontamination of mine waste water; 9532002; Journal Paper; SilverPlatter; Ovid Technologies |
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CBU @ c.wolke @ 16784 |
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409 |
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Davies, G.J.; Holmes, M.; Wireman, M.; King, K.; Gertson, J.N.; Stefanic, J.M. |
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Title |
Water tracing at scales of hours to decades as an aid to estimating hydraulic characteristics of the Leadville Mine drainage tunnel |
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Journal Article |
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2001 |
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acid mine drainage Arkansas River Colorado drainage dye tracers field studies fluorescence ground water Lake County Colorado Leadville Mine Leadville mining district pH quantitative analysis recharge surveys tunnels United States water treatment 30 Engineering geology 21 Hydrogeology |
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The Leadville Mine Drainage Tunnel (LMDT) is a 3.3 kilometer structure that was constructed in the complicated geology of the Leadville mine district in the 1940's. Discharge from the LMDT is impacted by heavy metals and is treated at a plant built in 1992 operated by the United States Bureau of Reclamation. On the surface waste rock and other remnants of the mining operations litter the landscape and this material is exposed to precipitation. As a result of contact with this material, surface water often has pH of less than 3 and its containment and disposal is necessary before it impacts surface drainage and the nearby Arkansas River. Using a borehole drilled into the mine workings the U.S. EPA has devised a plan in which the impacted water is contained on the surface which then can be discharged into the mine workings to discharge from the LMDT and be treated. The percentage of water discharging from the mining district along the drainage tunnel is unknown, and since there is no access, information about the condition of the tunnel with regards to blockages is also relatively obscure. Application of quantitative water tracing using fluorescent dyes was used to model the flow parameters at the scale of hours in the tunnel and evaluate the likelihood of blockages. Because the tunnel has intersected several lithologies and faults, other locations such as discharging shafts, adits and surface streams that could be hydraulically connected to the LMDT were also monitored. An initial tracer experiment was done using an instantaneous injection, which was followed by additional injections of water. Another tracer injection was done when there was a continuous flow of impacted water into the workings. Analysis of the tracer concentration responses at water-filled shafts and at the portal were used to model the flow along the tunnel and estimate several hydraulic parameters. Waters in these settings are mixtures of components with different residence times, so, qualitative tritium data were used to evaluate residence times of decades. The combined injected tracer and tritium data as well as other geochemical data were used to infer the nature of flow and recharge into the tunnel. |
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Abstracts with Programs - Geological Society of America |
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Geological Society of America, 2001 annual meeting |
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2004-013418; Geological Society of America, 2001 annual meeting, Boston, MA, United States, Nov. 1-10, 2001; GeoRef; English |
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CBU @ c.wolke @ 16511 |
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408 |
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Davison, W. |
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Title |
Neutralizing Strategies For Acid Waters – Sodium And Calcium Products Generate Different Acid Neutralizing Capacities |
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1988 |
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Water Res |
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22 |
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5 |
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577-583 |
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mine water treatment |
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Neutralizing Strategies For Acid Waters – Sodium And Calcium Products Generate Different Acid Neutralizing Capacities; Wos:A1988p420900008; Times Cited: 8; ISI Web of Science |
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CBU @ c.wolke @ 9085 |
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90 |
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Demchak, J.; Morrow, T.; Skousen, J.; Donovan, J.J.; Rose, A.W. |
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Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites |
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Journal Article |
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2001 |
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Geochemistry – Exploration, Environment, Analysis |
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1 |
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1 |
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71-80 |
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acid mine drainage alkalinity anaerobic environment Appalachian Plateau Appalachians carbonate rocks Clearfield County Pennsylvania constructed wetlands Eh equilibrium Filson Wetlands ground water Howe Bridge Wetlands hydrology Jefferson County Pennsylvania limestone McKinley Wetlands Mill Creek watershed Moose Creek movement North America passive methods Pennsylvania pH pollution reclamation sedimentary rocks Sommerville Wetlands systems United States water treatment watersheds wetlands 22 Environmental geology 02B Hydrochemistry |
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Acid mine drainage (AMD) is a serious problem in many watersheds where coal is mined. Passive treatments, such as wetlands and anoxic limestone drains (ALDs), have been developed, but these technologies show varying treatment efficiencies. A new passive treatment technique is a vertical flow wetland or successive alkalinity producing system (SAPS). Four SAPS in Pennsylvania were studied to determine changes in water chemistry from inflow to outflow. The Howe Bridge SAPS removed about 130 mg l (super -1) (40%) of the inflow acidity concentration and about 100 mg l (super -1) (60%) iron (Fe). The Filson 1 SAPS removed 68 mg l (super -1) (26%) acidity, 20 mg l (super -1) (83%) Fe and 6 mg l (super -1) (35%) aluminium (Al). The Sommerville SAPS removed 112 mg l (super -1) (31%) acidity, exported Fe, and removed 13 mg l (super -1) (30%) Al. The McKinley SAPS removed 54 mg l (super -1) (91%) acidity and 5 mg l (super -1) (90%) Fe. Acid removal rates at our four sites were 17 (HB), 52 (Filson1), 18 (Sommerville) and 11 (McKinley) g of acid per m (super 2) of surface wetland area per day (g/m (super 2) d (super -1) ). Calcium (Ca) concentrations in the SAPS effluents were increased between 8 and 57 mg l (super -1) at these sites. Equilibrators, which were inserted into compost layers to evaluate redox conditions at our sites, showed that reducing conditions were generally found at 60 cm compost depths and oxidized conditions were found at 30 cm compost depths. Deeply oxidized zones substantiated observations that channel flow was occurring through some parts of the compost. The Howe Bridge site has not declined in treatment efficiency over a six year treatment life. The SAPS construction costs were equal to about seven years of NaOH chemical treatment costs and 30 years of lime treatment costs. So, if the SAPS treatment longevity is seven years or greater and comparable effluent water quality was achieved, the SAPS construction was cost effective compared to NaOH chemical treatment. Construction recommendations for SAPS include a minimum of 50 cm of compost thickness, periodic replacement or addition of fresh compost material, and increasing the number of drainage pipes underlying the limestone. |
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1467-7873 |
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Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites; 2002-008380; References: 15; illus. incl. 5 tables United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 16518 |
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58 |
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Demin, O.A.; Dudeney, A.W.L.; Tarasova, I.I. |
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Title |
Remediation of Ammonia-rich Minewater in Constructed Wetlands |
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Journal Article |
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2002 |
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Environ. Technol. |
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23 |
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5 |
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497-514 |
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constructed wetlands reed beds ammonia removal nitrification woolley colliery horizontal subsurface flow nitrate removal waste-water denitrification nitrification |
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A three-year study of ammonia removal from minewater was carried out employing constructed wetland systems (surface flow wetland and subsurface flow wetland cells) at the former Woolley Mine in West Yorkshire, UK The 1.4 Ha surface flow wetland (constructed in 1995) reduced the ammonia concentration from 3.5 – 4.5 mg l(-1) to < 2 3 mg V during the first half of the study and to essentially zero in the last year (2000 – 2001). About 25 % of contained ammonia was converted to nitrate, about 10 % was consumed by the plants and up to 30 % was converted to nitrogen gas. This maturation effect was attributed to increased depth of sludge from sedimentation of ochre, providing increased surface area for immobilisation of ammonia oxidising bacteria. The surface flow wetland finally removed 23 g m(-2) day(-1) ammonia in comparison with 3.8 g m(-2) day' for the subsurface flow (pea gravel) wetland cells, constructed for the present work and dosed with ammonium salts. Removal of ammonia by both systems was consistent with well-established mechanisms of nitrification and denitrification. It was also consistent with ammonia removal in wastewater wetland systems, although the greater aeration in the minewater systems obviated the need for special aeration cycles. The general role of wetland plants in such aerated conditions was attributed to maintaining hydraulic conditions (such as hydraulic efficiency and hydraulic resistance of substratum in subsurface flow systems) in the wetlands and providing a suspended solids filter for minewater. |
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0959-3330 |
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Remediation of Ammonia-rich Minewater in Constructed Wetlands; Isi:000176238900002; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17328 |
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405 |
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