| Records |
Author  |
Carlson, L.; Kumpulainen, S. |
| Title |
Retention of harmful elements by ochreous precipitates of iron |
Type |
Journal Article |
| Year |
2001 |
Publication |
Tutkimusraportti Geologian Tutkimuskeskus |
Abbreviated Journal |
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| Volume |
- |
Issue |
154 |
Pages |
30-33 |
| Keywords |
Surface water quality Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 9) geological abstracts: environmental geology (72 14 2) iron oxide precipitation chemistry sulfate arsenate heavy metal pH water pollution remediation |
| Abstract |
The capability of soil fines to fix harmful elements, e.g. heavy metals and arsenic, depends on specific surface area and other characteristics, such as surface charge. In the pH-range typical of natural waters (pH 5,5-7,5), the surfaces of fine-grained silicate particles and manganese oxides are negatively charged; consequently cations, such as heavy metals, fix effectively to them. The iron oxide surfaces are usually positively charged and typically fix anions, such as sulphate and arsenate. Retention of anions is especially extensive to precipitates formed from acid mine drainage (pH 2,5-5,0). For example, precipitates found at Paroistenjarvi mine, Finland, contain more than 70 g/kg of arsenic (dry matter). Adsorbed anions, e.g. sulphate, enhance the capacity of precipitate to fix heavy metal cations in low-pH environments. |
| Address |
L. Carlson, Tehtaankatu 25 A 4, Helsinki FIN-00150, Finland liisa.carlson@kolumbus.fi |
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0781-4240 |
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Retention of harmful elements by ochreous precipitates of iron; 2392974; Oksidiset rautasaostumat haitallisten aineiden pidattajina. Finland 7; Geobase |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 17533 |
Serial |
421 |
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| Author |
Conca, J.L.; Wright, J. |
| Title |
An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd |
Type |
Journal Article |
| Year |
2006 |
Publication |
Appl. Geochem. |
Abbreviated Journal |
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| Volume |
21 |
Issue |
12 |
Pages |
2188-2200 |
| Keywords |
Pollution and waste management non radioactive Groundwater quality apatite groundwater remediation zinc lead cadmium acid mine drainage copper sulfate nitrate permeability water treatment precipitation chemistry |
| Abstract |
Phosphate-induced metal stabilization involving the reactive medium Apatite II(TM) [Ca10-xNax(PO4)6-x(CO3)x(OH)2], where x < 1, was used in a subsurface permeable reactive barrier (PRB) to treat acid mine drainage in a shallow alluvial groundwater containing elevated concentrations of Zn, Pb, Cd, Cu, SO4 and NO3. The groundwater is treated in situ before it enters the East Fork of Ninemile Creek, a tributary to the Coeur d'Alene River, Idaho. Microbially mediated SO4 reduction and the subsequent precipitation of sphalerite [ZnS] is the primary mechanism occurring for immobilization of Zn and Cd. Precipitation of pyromorphite [Pb10(PO4)6(OH,Cl)2] is the most likely mechanism for immobilization of Pb. Precipitation is occurring directly on the original Apatite II. The emplaced PRB has been operating successfully since January of 2001, and has reduced the concentrations of Cd and Pb to below detection (2 μg L-1), has reduced Zn to near background in this region (about 100 μg L-1), and has reduced SO4 by between 100 and 200 mg L-1 and NO3 to below detection (50 μg L-1). The PRB, filled with 90 tonnes of Apatite II, has removed about 4550 kg of Zn, 91 kg of Pb and 45 kg of Cd, but 90% of the immobilization is occurring in the first 20% of the barrier, wherein the reactive media now contain up to 25 wt% Zn. Field observations indicate that about 30% of the Apatite II material is spent (consumed). |
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0883-2927 |
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Dec.; An Apatite II permeable reactive barrier to remediate groundwater containing Zn, Pb and Cd; Science Direct |
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no |
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CBU @ c.wolke @ 17248 |
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44 |
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| Author |
Coulton, R.; Bullen, C.; Hallett, C. |
| Title |
The design and optimisation of active mine water treatment plants |
Type |
Journal Article |
| Year |
2003 |
Publication |
Land Contam. Reclam. |
Abbreviated Journal |
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| Volume |
11 |
Issue |
2 |
Pages |
273-280 |
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sludge mine water treatment mine water active treatment precipitation iron manganese high density sludge sulphide Groundwater problems and environmental effects Pollution and waste management non radioactive manganese sulfide pollutant removal iron water treatment mine drainage |
| Abstract |
This paper provides a 'state of the art' overview of active mine water treatment. The paper discusses the process and reagent selection options commonly available to the designer of an active mine water treatment plant. Comparisons are made between each of these options, based on technical and financial criteria. The various different treatment technologies available are reviewed and comparisons made between conventional precipitation (using hydroxides, sulphides and carbonates), high density sludge processes and super-saturation precipitation. The selection of reagents (quick lime, slaked lime, sodium hydroxide, sodium carbonate, magnesium hydroxide, and proprietary chemicals) is considered and a comparison made on the basis of reagent cost, ease of use, final effluent quality and sludge settling criteria. The choice of oxidising agent (air, pure oxygen, peroxide, etc.) for conversion of ferrous to ferric iron is also considered. Whole life costs comparisons (capital, operational and decommissioning) are made between conventional hydroxide precipitation and the high density sludge process, based on the actual treatment requirements for four different mine waters. |
| Address |
R. Coulton, Unipure Europe Ltd., Wonastow Road, Monmouth NP25 5JA, United Kingdom |
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0967-0513 |
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| Notes |
The design and optimisation of active mine water treatment plants; 2530436; United-Kingdom 4; Geobase |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 17513 |
Serial |
59 |
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| Author |
Cram, J.C. |
| Title |
Diversion well treatment of acid water, Lick Creek, Tioga County, PA |
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Book Whole |
| Year |
1996 |
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acid mine drainage acid rain atmospheric precipitation carbonate rocks diversion wells Lick Creek limestone Pennsylvania pH pollution rain sedimentary rocks surface water Tioga County Pennsylvania United States water quality water treatment wells 22, Environmental geology |
| Abstract |
Diversion wells implement a fluidized bed of limestone for the treatment of acid water resulting from acid mine drainage or acid precipitation. This study was undertaken to better understand the operation of diversion wells and to define the physical and chemical factors having the greatest impact on the neutralization performance of the system. The study site was located near Lick Creek, a tributary stream of Babb Creek, near the Village of Arnot in Tioga County, Pennsylvania. Investigative methods included collection and analysis of site water quality and limestone data and field study of this as well as other diversion well sites. Analysis of data led to these general conclusions: The site received surface water influenced by three primary sources 1) precipitation, 2) mine drainage baseflow, and 3) melted snow. Water mostly influenced by precipitation events and mine drainage baseflow was more acidic than water influenced by melting snow conditions. The diversion wells were generally able to treat only half or less of the total stream flow of Lick Creek and under extremely high flow conditions the treatment provided was minimal. A range of flow conditions were identified which produced the best performance for the two diversion wells. Treatment produced by the system decreased through the loading cycle and increases to a maximum value after each weekly refilling of limestone. Fine grained sediment in the stream was found to be limestone of the same general composition as the material placed within the wells. Neutralization of acid water was largely due to microscopic particles rather than the limestone sediment discharged to the stream. Additional downstream buffering due to the limestone sediment physically discharged from the vessels was not apparent. Diversion well systems are inexpensive and simple to construct. In addition, the systems were found to be highly reliable and able to effectively treat acid water resulting from mine drainage and acid precipitation. Diversion wells provide better treatment when the treatment site is located at the source of the acidity (such as a mine discharge), rather than at the receiving stream. Systems should be designed with 15 to 20 feet of hydraulic head and the site must have year-round access. Diversion well systems require weekly addition of limestone gravel to the vessels to facilitate continual treatment. A great deal of commitment is necessary to maintain a diversion well system for long periods of time. These systems are more economical and require less attention that conventional chemical treatment of acid water. However, these systems require more attention that traditional passive treatment methods for treatment of acid, including mine drainage. |
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Thesis |
Ph.D. thesis |
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Pennsylvania State University at University Park, |
Place of Publication |
University Park |
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Diversion well treatment of acid water, Lick Creek, Tioga County, PA; GeoRef; English; References: 49; illus. |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 16652 |
Serial |
411 |
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| Author |
Cravotta, C.A., III; Watzlaf, G.R.; Naftz, D.L.; Morrison, S.J.; Fuller, C.C.; Davis, J.A. |
| Title |
Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients |
Type |
Book Chapter |
| Year |
2002 |
Publication |
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acid mine drainage; alkaline earth metals; aquatic environment; aquifers; calcium; carbonate rocks; chemical properties; construction; construction materials; crushed stone; dissolved materials; drainage; effluents; ground water; limestone; magnesium; metals; pH; pollution; porous materials; precipitation; retention; saturation; sedimentary rocks; sulfate ion; suspended materials 22, Environmental geology |
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Academic Press |
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Amsterdam |
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0125135637 |
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Design and performance of limestone drains to increase pH and remove metals from acidic mine drainage Handbook of groundwater remediation using permeable reactive barriers; applications to radionuclides, trace metals, and nutrients; GeoRef; English; 2004-040518; References: 66; illus. incl. 4 tables |
Approved |
no |
| Call Number |
CBU @ c.wolke @ 5686 |
Serial |
81 |
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