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Kingham, N. W., Semenak, R., Powell, G., & Way, S. (2002). Reverse osmosis coupled with chemical precipitation treatment of acid mine leachate at the Basin-Luttrell Pit, Ten Mile Creek Site, Lewis and Clark County, Montana Hardrock mining 2002; issues shaping the industry..
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Matlock, M. M., Howerton, B. S., & Atwood, D. A. (2002). Chemical precipitation of heavy metals from acid mine drainage. Water Res, 36(19), 4757–4764.
Abstract: The 1,3-benzenediamidoethanethiol dianion (BDET, known commercially as MetX) has been developed to selectively and irreversibly bind soft heavy metals from aqueous solution. In the present study BDET was found to remove >90% of several toxic or problematic metals from AMD samples taken from an abandoned mine in Pikeville, Kentucky. The concentrations of metals such as iron, may be reduced at pH 4.5 from 194 ppm to below 0.009 ppm. The formation of stoichiomietric BDET-metal precipitates in this process was confirmed using X-ray powder diffraction (XRD), proton nuclear magnetic resonance (1H NMR), and infrared spectroscopy (IR).
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Rammlmair, D., & Grissemann, C. (2000). Natural attenuation in slag heaps versus remediation. In D. Rammlmair, J. Mederer, T. Oberthuer, R. B. Heimann, & H. J. Pentinghaus (Eds.), Applied mineralogy in research, economy, technology, ecology and culture (pp. 645–648).
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Schwartz, M. O., & Ploethner, D. (1999). From mine water to drinking water; heavy-metal removal by carbonate precipitation in the Grootfontein-Omatako Canal, Namibia.. Hanover: Bundesanst. fuer Geowiss. und Rohstoffe.
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Sottnik, P., & Sucha, V. (2001). Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica. Mineralia Slovaca, 33(1), 53–60.
Abstract: A waste dump formed during the exploitation of quartzite deposit in Sobov mine (Slovakia) produces large quantity of acid mine drainage (AMD) which is mainly a product of pyrite oxidation. Sulphuric acid--the most aggressive oxidation product--attacks gangue minerals, mainly clays, as well. This process lead to a sharp decrease of the pH values (2-2.5) and increase of Fe, Al and SO (super 2-) (sub 4) contents (TDS = 20-30 mg/1). Passive treatment system was designed to remediate AMD. Chemical redox reactions along with microbial activity cause a precipitation of mobile contamination into a more stable forms. The sulphides are formed in the anaerobic cell, under reducing conditions. Fe-, Al- oxyhydroxides are precipitated in the aerobic part of the system. Precipitation decreases the Fe and Al contents along with immobilization of some heavy metal closely related to oxyhydroxides. Besides oxidation, the wetland vegetation is an active part of on aerobic cell. The system has been working effectively since September 1999. The pH values of outflowing water are apparently higher (6.2-6.8) and contents of dissolved elements (Fe from 2.260 to 4.1; Al from 900 to 0.18; Mn from 51 to 23; Cu from 4.95 to 0.03 mg/l) is significantly lowers.
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