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Wolkersdorfer, C. (2002). Mine water tracing. Geological Society Special Publication, -(198), 47–60.
Abstract: This paper describes how tracer tests can be used in flooded underground mines to evaluate the hydrodynamic conditions or reliability of dams. Mine water tracer tests are conducted in order to evaluate the flow paths of seepage water, connections from the surface to the mine, and to support remediation plans for abandoned and flooded underground mines. There are only a few descriptions of successful tracer tests in the literature, and experience with mine water tracing is limited. Potential tracers are restricted due to the complicated chemical composition or low pH mine waters. A new injection and sampling method ('LydiA'-technique) overcomes some of the problems in mine water tracing. A successful tracer test from the Harz Mountains in Germany with Lycopodium clavatum, microspheres and sodium chloride is described, and the results of 29 mine water tracer tests indicate mean flow velocities of between 0.3 and 1.7 m min-1.
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Younger, P. L. (2000). Holistic remedial strategies for short- and long-term water pollution from abandoned mines. Transactions of the Institution of Mining and Metallurgy Section a-Mining Technology, 109, A210–A218.
Abstract: Where mining proceeds below the water-table-as it has extensively in Britain and elsewhere-water ingress is not only a hindrance during mineral extraction but also a potential liability after abandonment. This is because the cessation of dewatering that commonly follows mine closure leads to a rise in the water-table and associated, often rapid, changes in the chemical regime of the subsurface. Studies over the past two decades have provided insights into the nature and time-scales of these changes and provide a basis for rational planning of mine-water management during and after mine abandonment. The same insights into mine-water chemistry provide hints for the efficient remediation of pollution (typically due to Fe, Mn and Al and, in some cases, Zn, Cd, Pb and other metals). Intensive treatment (by chemical dosing with enhanced sedimentation or alternative processes, such as sulphidization or reverse osmosis) is often necessary only during the first few years following complete flooding of mine voids. Passive treatment (by the use of gravity-flow geochemical reactors and wetlands) may be both more cost-effective and ecologically more responsible in the long term. By the end of 1999 a total of 28 passive systems had been installed at United Kingdom mine sites, including examples of system types currently unique to the United Kingdom. Early performance data for all the systems are summarized and shown to demonstrate the efficacy of passive treatment when appropriately applied.
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Stewart, D., Norman, T., Cordery-Cotter, S., Kleiner, R., Sweeney, E., & Nelson, J. D. (1997). Utilization of a ceramic membrane for acid mine drainage treatment. Tailings and Mine Waste '97, , 453–460.
Abstract: BASX Systems LLC has developed a treatment system based on ceramic membranes for the removal of heavy metals from an acid mine drainage stream. This stream also contained volatile organic compounds that were required to be removed prior to discharge to a Colorado mountain stream. The removal of heavy metals was greater than 99% in most cases. A decrease of 30% in chemicals required for treatment and a reduction by more than 75% in labor over a competing technology were achieved. These decreases were obtained for operating temperatures of less than 5 degrees C. This system of ceramic microfiltration is capable of treating many different types of acid mine waste streams for heavy metals removal.
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Blowes, D. W., Ptacek, C. J., Benner, S. G., McRae, C. W. T., & Puls, R. W. (1998). Treatment of dissolved metals using permeable reactive barriers. Groundwater Quality: Remediation and Protection, (250), 483–490.
Abstract: Permeable reactive barriers are a promising new approach to the treatment of dissolved contaminants in aquifers. This technology has progressed rapidly from laboratory studies to full-scale implementation over the past decade. Laboratory treatability studies indicate the potential for treatment of a large number of inorganic contaminants, including As, Cd, Cr, Cu, Hg, Fe, Mn, Mo, Ni, Pb, Se, Tc, U, V, NO3, PO4, and SO4. Small scale field studies have indicated the potential for treatment of Cd, Cr, Cu, Fe, Ni, Pb, NO3, PO4, and SO4. Permeable reactive barriers have been used in full-scale installations for the treatment of hexavalent chromium, dissolved constituents associated with acid-mine drainage, including SO4, Fe, Ni, Co and Zn, and dissolved nutrients, including nitrate and phosphate. A full-scale barrier designed to prevent the release of contaminants associated with inactive mine tailings impoundment was installed at the Nickel Rim mine site in Canada in August 1995. This reactive barrier removes Fe, SO,, Ni and other metals. The effluent from the barrier is neutral in pH and contains no acid-generating potential, and dissolved metal concentrations are below regulatory guidelines. A full-scale reactive barrier was installed to treat Cr(VI) and halogenated hydrocarbons at the US Coast Guard site in Elizabeth City, North Carolina, USA in June 1996. This barrier removes Cr(VI) from >8 mg l(-1) to <0.01 mg l(-1).
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Blowes, D. W., Bain, J. G., Smyth, D. J., Ptacek, C. J., Jambor, J. L., Blowes, D. W., et al. (2003). Treatment of mine drainage using permeable reactive materials. Environmental Aspects of Mine Wastes, 31, 361–376.
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