| Records |
| Author |
Totsche, O.; Fyson, A.; Kalin, M.; Steinberg Christian, E.W. |
| Title |
Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters |
Type |
Journal Article |
| Year |
2006 |
Publication |
ESPR Environmental Science and Pollution Research |
Abbreviated Journal |
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| Volume |
13 |
Issue |
4 |
Pages |
215-224 |
| Keywords |
Abwasseraufbereitung Bergbau Titration Säuregehalt Grundwasser Pufferlösung Neutralisation Titrationskurve Bergbauabwasser |
| Abstract |
The acidification of mine waters is generally caused by metal sulfide oxidation, related to mining activities. These waters are characterized by low pH and high acidity due to strong buffering systems. The standard acidity parameter, the BNC (Base Neutralization Capacity), is determined by endpoint titration, and reflects a cumulative parameter of both hydrogen ions and all buffering systems, but does not give information on the individual buffer systems. It is demonstrated that a detailed interpretation of titration curves can provide information about the strength of the buffering systems. The buffering systems are of importance for environmental studies and treatment of acidic mining waters. Titrations were carried out by means of an automatic titrator using acidic mining waters from Germany and Canada. The curves were interpreted, compared with each other, to endpoint titration results and to elemental concentrations contained therein. The titration curves were highly reproducible, and contained information about the strength of the buffer systems present. Interpretations are given, and the classification and comparison of acidic mining waters, by the nature and strength of their buffering systems derived from titration curves are discussed. The BNC-values calculated from the curves were more precise than the ones determined by the standard endpoint titration method. Due to the complex buffer mechanisms in acidic mining waters, the calculation of major metal concentrations from the shape of the titration curve resulted in estimates, which should not be confused with precise elemental analysis results. Conclusion. Titration curves provide an inexpensive, valuable and versatile tool, by which to obtain sophisticated information of the acidity in acidic water. The information about the strength of the present buffer systems can help to understand and document the complex nature of acidic mining water buffer systems. Finally, the interpretation of titration curves could help to improve treatment measurements and the ecological understanding of these acidic waters. |
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Leibniz-Institut für Gewässerökologie und Binnenfischerei, Berlin, DE; Boojum Research, Toronto, CA; Humboldt-Universität Berlin, DE |
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0944-1344 |
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Titration curves: A useful instrument for assessing the buffer systems of acidic mining waters; 39481, BERG , 13.11.06; Words: 519; 200610 05282; 10 Seiten, 15 Bilder, 2 Tabellen, 39 Quellen 3UXX *Belastung von Wasser, Wasserreinhaltung, Abwasser* 3BX *chemische Grundlagen* 3IFC *Messung und Prüfung chemischer Größen, chemische Analytik* 3MZ *Bergbau, Tunnelbau, Erdöl /Erdgasförderung, Bohrtechnik*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
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CBU @ c.wolke @ 17580 |
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224 |
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| Author |
Rukin, N. |
| Title |
Whittle mine water treatment system: In-river attenuation of manganese |
Type |
Journal Article |
| Year |
2003 |
Publication |
Land Contam. Reclam. |
Abbreviated Journal |
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| Volume |
11 |
Issue |
2 |
Pages |
137-144 |
| Keywords |
Pollution and waste management non radioactive Groundwater problems and environmental effects geological abstracts: environmental geology (72 14 2) geomechanics abstracts: excavations (77 10 10) river water natural attenuation manganese water treatment mine drainage coal mine |
| Abstract |
Much work has been undertaken on the design of treatment systems to remove iron from ochreous mine water discharges. Unlike iron, manganese removal is far more difficult and generally requires active chemical dosing rather than passive treatment. The need for manganese removal can therefore significantly change the economics, management attention and sustainability of a site. Understanding natural attenuation of manganese in river systems is therefore key to deciding whether (active) manganese treatment is needed to protect downstream receptors. Nuttall (2002, this volume) describes the effectiveness of the passive treatment system at Whittle in reducing both iron and manganese concentrations in ochreous mine waters. This paper discusses the results of in-river monitoring and provides evidence for manganese removal downstream of the discharge point. In addition to dilution, attenuation appears to be in the order of 20 to 50%, depending on relative rates of mine water discharge and river flows. Such attenuation means that active treatment may not be needed for the long-term operation of the Whittle scheme. Operation of the scheme commenced in July 2002, with monitoring to further examine evidence for manganese attenuation and any impact on the ecology of the recipient watercourses. |
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N. Rukin, Entec UK Ltd., 160-162 Abbey Foregate, Shrewsbury SY2 6BZ, United Kingdom |
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0967-0513 |
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Whittle mine water treatment system: In-river attenuation of manganese; 2530418; United-Kingdom 2; Geobase |
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CBU @ c.wolke @ 17521 |
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257 |
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| Author |
Beck, P. |
| Title |
CL:AIRE – Providing support for remediation research |
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Journal Article |
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2003 |
Publication |
Land Contam. Reclam. |
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| Volume |
11 |
Issue |
2 |
Pages |
99-104 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) contaminated land remediation guideline acid mine drainage hydrochemistry |
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CL:AIRE (Contaminated Land: Applications in Real Environments) is a public-private partnership which was established in 1999 to encourage the demonstration of remediation research and technologies on contaminated sites throughout the UK. Project proposals are submitted to CL:AIRE and reviewed and approved by the CL:AIRE Technology & Research Group. CL:AIRE provides independent verification of its projects and plays a crucial role in the dissemination of project information. During the course of the project, progress is reported through the newsletter, CL:AIRE view, which is mailed free of charge to a database of more than 4500 stakeholders with an interest in contaminated land. Progress is also tracked on the CL:AIRE website at www.claire.co.uk. On completion of the project, a project report is published and a one page summary fact sheet is prepared. The fact sheet is distributed to our database subscribers and posted on the website. The project is also presented at the CL:AIRE Annual Project Conference. In addition, aspects of the research which have practical application will be published as CL:AIRE Research Bulletins. Acid mine waters discharging from abandoned mines represent a significant environmental problem in many parts of the UK. Considerable research has been carried out to understand the geochemical process involved, and the knowledge has been used to manage groundwater discharge through physical/chemical treatment and constructed wetlands. CL:AIRE supports the development of a national site for wetland research managed by the University of Newcastle and will encourage collaborative research projects to be submitted through CL:AIRE. CL:AIRE is currently supporting two projects which demonstrate remediation of acid mine drainage and is disseminating the results of this and other research to improve confidence in the use of these techniques. |
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P. Beck, CL:AIRE, 1 Great Cumberland Place, London W1H 7AL, United Kingdom |
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0967-0513 |
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CL:AIRE – Providing support for remediation research; 2530414; United-Kingdom 2; Geobase |
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no |
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CBU @ c.wolke @ 17524 |
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461 |
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Eger, P.; Melchert, G.; Wagner, J. |
| Title |
Using passive treatment systems for mine closure – A good approach or a risky alternative? |
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Journal Article |
| Year |
2000 |
Publication |
Min. Eng. |
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52 |
Issue |
9 |
Pages |
78-83 |
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Pollution and waste management non radioactive Groundwater problems and environmental effects geological abstracts: environmental geology (72 14 2) geomechanics abstracts: excavations (77 10 10) acid mine drainage decommissioning mine waste open pit mine pH remediation |
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In 1991, LTV Steel Mining decided to close an open-pit taconite mine in northeastern Minnesota using a passive-treatment approach consisting of limiting infiltration into the stockpiles and wetland treatment to remove metals. More than 50 Mt (55 million st) of sulfide-containing waste had been stockpiled adjacent to the mine during its 30 years of operation. Drainage from the stockpiles contained elevated levels of copper, nickel, cobalt and zinc. Nickel is the major trace metal in the drainages. Before the closure, the annual median concentrations ranged from 1.5 to 50 mg/L. Copper, cobalt and zinc are also present but they are generally less than 5% of the nickel values. Median pH levels range from 5 to 7.5, but most of the stockpile drainages have pH levels greater than 6.5. Based on the chemical composition of each stockpile, a cover material was selected. The higher the potential that a stockpile had to produce acid drainage, the lower the permeability of the capping material required. Covers ranged from overburden soil removed at the mine to a flexible plastic liner. Predictions of the reduction in infiltration ranged from 40% for the native soil to more than 90% for the plastic liner. Five constructed wetlands have been installed since 1992. They have removed 60% to 90% of the nickel in the drainages. Total capital costs for all the infiltration reduction and wetlands exceeded $6.5 million, but maintenance costs are less than 1% of those for an active treatment plant. Because mine-drainage problems can continue for more than 100 years, the lower annual operating costs should pay for the construction of the wetland-treatment systems within seven years. |
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P. Eger, Minnesota Dept. of Natural Rsrces., St. Paul, MN, United States |
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0026-5187 |
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Using passive treatment systems for mine closure – A good approach or a risky alternative?; 2285715; United-States 19; Geobase |
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CBU @ c.wolke @ 17539 |
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392 |
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Srivastave, A.; Chhonkar, P.K. |
| Title |
Amelioration of coal mine spoils through fly ash application as liming material |
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Journal Article |
| Year |
2000 |
Publication |
J. Ind. Res. |
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59 |
Issue |
4 |
Pages |
309-313 |
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Groundwater problems and environmental effects Pollution and waste management non radioactive geomechanics abstracts: excavations (77 10 10) geological abstracts: environmental geology (72 14 2) mitigation fly ash feasibility study acid mine drainage lime |
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The feasibility of fly ash as compared to lime to ameliorate the low pH of acidic coal mine spoils under controlled pot culture conditions are reported using Sudan grass (Sorghum studanens) and Oats (Avena sativa) as indicator crops. It is observed that at all levels of applications, fly ash and lime significantly increase the pH of mine spoils, available phosphorus, exchangeable potassium, available sulphur and also uptake of phosphorus, potassium, sulphur and oven-dried biomass of both these test crops. The fly ash significantly decreases the bulk density of coal mine spoils, but, there is no effect on bulk density due to lime application. However, when the spoils are amended with either fly ash or lime, the root growth occurs throughout the material. Fly ash and lime do not cause elemental toxicities to the plants as evidenced from the dry matter production by the test crops. The results indicate that fly ash to be a potential alternative to lime for treating acidic coal mine spoils. |
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P.K. Chhonkar, Div. of Soil Sci. and Agr. Chem., Indian Agricultural Research Inst., New Delhi 110 012, India |
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0022-4456 |
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Amelioration of coal mine spoils through fly ash application as liming material; 2364216; India 18; Geobase |
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CBU @ c.wolke @ 17535 |
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234 |
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