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Demchak, J.; Morrow, T.; Skousen, J.; Donovan, J.J.; Rose, A.W. |
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Title |
Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites |
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Journal Article |
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Year |
2001 |
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Geochemistry – Exploration, Environment, Analysis |
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1 |
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1 |
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71-80 |
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Keywords |
acid mine drainage alkalinity anaerobic environment Appalachian Plateau Appalachians carbonate rocks Clearfield County Pennsylvania constructed wetlands Eh equilibrium Filson Wetlands ground water Howe Bridge Wetlands hydrology Jefferson County Pennsylvania limestone McKinley Wetlands Mill Creek watershed Moose Creek movement North America passive methods Pennsylvania pH pollution reclamation sedimentary rocks Sommerville Wetlands systems United States water treatment watersheds wetlands 22 Environmental geology 02B Hydrochemistry |
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Abstract  |
Acid mine drainage (AMD) is a serious problem in many watersheds where coal is mined. Passive treatments, such as wetlands and anoxic limestone drains (ALDs), have been developed, but these technologies show varying treatment efficiencies. A new passive treatment technique is a vertical flow wetland or successive alkalinity producing system (SAPS). Four SAPS in Pennsylvania were studied to determine changes in water chemistry from inflow to outflow. The Howe Bridge SAPS removed about 130 mg l (super -1) (40%) of the inflow acidity concentration and about 100 mg l (super -1) (60%) iron (Fe). The Filson 1 SAPS removed 68 mg l (super -1) (26%) acidity, 20 mg l (super -1) (83%) Fe and 6 mg l (super -1) (35%) aluminium (Al). The Sommerville SAPS removed 112 mg l (super -1) (31%) acidity, exported Fe, and removed 13 mg l (super -1) (30%) Al. The McKinley SAPS removed 54 mg l (super -1) (91%) acidity and 5 mg l (super -1) (90%) Fe. Acid removal rates at our four sites were 17 (HB), 52 (Filson1), 18 (Sommerville) and 11 (McKinley) g of acid per m (super 2) of surface wetland area per day (g/m (super 2) d (super -1) ). Calcium (Ca) concentrations in the SAPS effluents were increased between 8 and 57 mg l (super -1) at these sites. Equilibrators, which were inserted into compost layers to evaluate redox conditions at our sites, showed that reducing conditions were generally found at 60 cm compost depths and oxidized conditions were found at 30 cm compost depths. Deeply oxidized zones substantiated observations that channel flow was occurring through some parts of the compost. The Howe Bridge site has not declined in treatment efficiency over a six year treatment life. The SAPS construction costs were equal to about seven years of NaOH chemical treatment costs and 30 years of lime treatment costs. So, if the SAPS treatment longevity is seven years or greater and comparable effluent water quality was achieved, the SAPS construction was cost effective compared to NaOH chemical treatment. Construction recommendations for SAPS include a minimum of 50 cm of compost thickness, periodic replacement or addition of fresh compost material, and increasing the number of drainage pipes underlying the limestone. |
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1467-7873 |
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Treatment of acid mine drainage by four vertical flow wetlands in Pennsylvania Evolution and remediation of acid-sulfate groundwater systems at reclaimed mine-sites; 2002-008380; References: 15; illus. incl. 5 tables United Kingdom (GBR); GeoRef; English |
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CBU @ c.wolke @ 16518 |
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58 |
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Johnson, D.B.; Hallberg, K.B. |
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Title |
Acid mine drainage remediation options: a review |
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Journal Article |
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2005 |
Publication |
Science of the Total Environment |
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338 |
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1-2 |
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3-14 |
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Wetlands and estuaries Pollution and waste management non radioactive geographical abstracts: physical geography hydrology (71 6 8) geological abstracts: environmental geology (72 14 2) biological method pollutant removal water treatment wastewater bioremediation constructed wetland acid mine drainage Cornwall England England United Kingdom Western Europe Europe Eurasia Eastern Hemisphere World Acid mine drainage Bioreactors Bioremediation Sulfidogenesis Wetlands Wheal Jane |
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Acid mine drainage (AMD) causes environmental pollution that affects many countries having historic or current mining industries. Preventing the formation or the migration of AMD from its source is generally considered to be the preferable option, although this is not feasible in many locations, and in such cases, it is necessary to collect, treat, and discharge mine water. There are various options available for remediating AMD, which may be divided into those that use either chemical or biological mechanisms to neutralise AMD and remove metals from solution. Both abiotic and biological systems include those that are classed as “active” (i.e., require continuous inputs of resources to sustain the process) or “passive” (i.e., require relatively little resource input once in operation). This review describes the current abiotic and bioremediative strategies that are currently used to mitigate AMD and compares the strengths and weaknesses of each. New and emerging technologies are also described. In addition, the factors that currently influence the selection of a remediation system, and how these criteria may change in the future, are discussed. |
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0048-9697 |
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Feb. 01; Acid mine drainage remediation options: a review; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10052.pdf; Science Direct |
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CBU @ c.wolke @ 17464 |
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47 |
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Sottnik, P.; Sucha, V. |
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Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica |
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2001 |
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Mineralia Slovaca |
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33 |
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1 |
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53-60 |
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acid mine drainage aluminum Banska Stiavnica Slovakia Central Europe copper Eh Europe gangue heavy metals iron manganese metals metamorphic rocks oxidation pH pollution precipitation pyrite quartzites reduction remediation Slovakia Sobov Mine sulfides vegetation waste disposal wetlands 22, Environmental geology |
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A waste dump formed during the exploitation of quartzite deposit in Sobov mine (Slovakia) produces large quantity of acid mine drainage (AMD) which is mainly a product of pyrite oxidation. Sulphuric acid--the most aggressive oxidation product--attacks gangue minerals, mainly clays, as well. This process lead to a sharp decrease of the pH values (2-2.5) and increase of Fe, Al and SO (super 2-) (sub 4) contents (TDS = 20-30 mg/1). Passive treatment system was designed to remediate AMD. Chemical redox reactions along with microbial activity cause a precipitation of mobile contamination into a more stable forms. The sulphides are formed in the anaerobic cell, under reducing conditions. Fe-, Al- oxyhydroxides are precipitated in the aerobic part of the system. Precipitation decreases the Fe and Al contents along with immobilization of some heavy metal closely related to oxyhydroxides. Besides oxidation, the wetland vegetation is an active part of on aerobic cell. The system has been working effectively since September 1999. The pH values of outflowing water are apparently higher (6.2-6.8) and contents of dissolved elements (Fe from 2.260 to 4.1; Al from 900 to 0.18; Mn from 51 to 23; Cu from 4.95 to 0.03 mg/l) is significantly lowers. |
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0369-2086 |
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Moznosti upravy kysleho banskeho vytoku loziska Banska Stiavnica-Sobov. Remediation of acid mine drainage from Sobov Mine, Banska Stiavnica; 2004-084366; References: 21; illus. incl. sects. Slovak Republic (SVK); GeoRef; Slovakian |
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CBU @ c.wolke @ 16534 |
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235 |
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Herbert, R.B., Jr.; Benner, S.G.; Blowes, D.W. |
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Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation |
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Book Chapter |
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1998 |
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Groundwater Quality: Remediation and Protection |
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451-457 |
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acid mine drainage Canada chemical analysis contaminant plumes Eastern Canada ground water hydraulic conductivity hydrolysis Nickel Rim Mine Ontario pH pollution porosity pyrrhotite remediation sample preparation Sudbury Basin sulfides sulfur tailings water pollution 22, Environmental geology |
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A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997. |
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IAHS-AISH Publication, vol.250 |
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Herbert, M.; Kovar, K. |
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1901502554 |
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Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation; GeoRef; English; 1999-065115; GQ 98 conference, Tubingen, Federal Republic of Germany, Sept. 21-24, 1998 References: 15; illus. |
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CBU @ c.wolke @ 16621 |
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65 |
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Li, L.; Jiang, Y.; Guo, Y. |
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Research on a comprehensive industrialization technology for the treatment of mining water containing sulfate ions |
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1999 |
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Meitian Dizhi Yu Kantan = Coal Geology & Exploration |
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27 |
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6 |
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51-53 |
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acid mine drainage; coal mines; mines; pollution; purification; sulfate ion; technology; water pollution; water treatment 22, Environmental geology |
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A method using a barium reagent was developed for the purification of the higher-sulphate mine water. |
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1001-1986 |
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Research on a comprehensive industrialization technology for the treatment of mining water containing sulfate ions; 2005-057894; References: 5 China (CHN); GeoRef; Chinese |
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CBU @ c.wolke @ 6097 |
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316 |
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