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Kepler, D.A.; Mc Cleary, E.C. |
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Title |
Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage |
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Journal Article |
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1994 |
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Proceedings, International Land Reclamation and Mine Drainage Conference |
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1 |
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195-204 |
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acid mine drainage; alkalinity; anaerobic environment; calcium carbonate; chemical reactions; experimental studies; pH; pollutants; pollution; remediation; water quality SAPS mine water RAPS |
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Abstract  |
Constructed wetland treatment system effectiveness has been limited by the alkalinity-producing, or acidity-neutralizing, capabilities of systems. Anoxic limestone drains (ALD's) have allowed for the treatment of approximately 300 mg/L net acidic mine drainage, but current design guidance precludes using successive ALD's to generate alkalinity in excess of 300 mg/L because of concerns with dissolved oxygen. “Compost” wetlands designed to promote bacterially mediated sulfate reduction are suggested as a means of generating alkalinity required in excess of that produced by ALD's. Compost wetlands create two basic needs of sulfate reducing bacteria; anoxic conditions resulting from the inherent oxygen demand of the organic substrate, and quasi-circumneutral pH values resulting from the dissolution of the carbonate fraction of the compost. However, sulfate reduction treatment area needs are generally in excess of area availability and/or cost effectiveness. Second generation alkalinity-producing systems demonstrate that a combination of existing treatment mechanisms has the potential to overcome current design concerns and effectively treat acidic waters ad infinitum. Successive alkalinity-producing systems (SAPS) combine ALD technology with sulfate reduction mechanisms. SAPS promote vertical flow through rich organic wetland substrates into limestone beds beneath the organic compost, discharging the pore waters. SAPS allow for conservative wetland treatment sizing calculations to be made as a rate function based on pH and alkalinity values and associated contaminant loadings. SAPS potentially decrease treatment area requirements and have the further potential to generate alkalinity in excess of acidity regardless od acidity concentrations. |
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Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage; Cn, Kj, Aj; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/9722.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 9722 |
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55 |
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Author |
Cram, J.C. |
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Title |
Diversion well treatment of acid water, Lick Creek, Tioga County, PA |
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1996 |
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acid mine drainage acid rain atmospheric precipitation carbonate rocks diversion wells Lick Creek limestone Pennsylvania pH pollution rain sedimentary rocks surface water Tioga County Pennsylvania United States water quality water treatment wells 22, Environmental geology |
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Diversion wells implement a fluidized bed of limestone for the treatment of acid water resulting from acid mine drainage or acid precipitation. This study was undertaken to better understand the operation of diversion wells and to define the physical and chemical factors having the greatest impact on the neutralization performance of the system. The study site was located near Lick Creek, a tributary stream of Babb Creek, near the Village of Arnot in Tioga County, Pennsylvania. Investigative methods included collection and analysis of site water quality and limestone data and field study of this as well as other diversion well sites. Analysis of data led to these general conclusions: The site received surface water influenced by three primary sources 1) precipitation, 2) mine drainage baseflow, and 3) melted snow. Water mostly influenced by precipitation events and mine drainage baseflow was more acidic than water influenced by melting snow conditions. The diversion wells were generally able to treat only half or less of the total stream flow of Lick Creek and under extremely high flow conditions the treatment provided was minimal. A range of flow conditions were identified which produced the best performance for the two diversion wells. Treatment produced by the system decreased through the loading cycle and increases to a maximum value after each weekly refilling of limestone. Fine grained sediment in the stream was found to be limestone of the same general composition as the material placed within the wells. Neutralization of acid water was largely due to microscopic particles rather than the limestone sediment discharged to the stream. Additional downstream buffering due to the limestone sediment physically discharged from the vessels was not apparent. Diversion well systems are inexpensive and simple to construct. In addition, the systems were found to be highly reliable and able to effectively treat acid water resulting from mine drainage and acid precipitation. Diversion wells provide better treatment when the treatment site is located at the source of the acidity (such as a mine discharge), rather than at the receiving stream. Systems should be designed with 15 to 20 feet of hydraulic head and the site must have year-round access. Diversion well systems require weekly addition of limestone gravel to the vessels to facilitate continual treatment. A great deal of commitment is necessary to maintain a diversion well system for long periods of time. These systems are more economical and require less attention that conventional chemical treatment of acid water. However, these systems require more attention that traditional passive treatment methods for treatment of acid, including mine drainage. |
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Ph.D. thesis |
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Pennsylvania State University at University Park, |
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University Park |
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Diversion well treatment of acid water, Lick Creek, Tioga County, PA; GeoRef; English; References: 49; illus. |
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CBU @ c.wolke @ 16652 |
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411 |
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Wolkersdorfer, C.; Younger, P.L. |
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Passive mine water treatment as an alternative to active systems |
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2002 |
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Grundwasser |
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7 |
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2 |
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67-77 |
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Groundwater quality geographical abstracts: physical geography hydrology (71 6 11) water treatment groundwater pollution water quality mine |
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For the treatment of contaminated mine waters reliable treatment methods with low investment and operational costs are essential. Therefore, passive treatment systems recently have been installed in Great Britain and in Germany (e.g. anoxic limestone drains, constructed wetlands, reactive barriers, roughing filters) and during the last eight years such systems successfully treated mine waters, using up to 6 ha of space. In some cases with highly contaminated mine water, a combination of active and passive systems should be applied, as in any case the water quality has to reach the limits. Because not all the processes of passive treatment systems are understood in detail, current research projects (e.g. EU-project PIRAMID) were established to clarify open questions. |
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Dr. Ch. Wolkersdorfer, TU Bergakademie Freiberg, Lehrstuhl fur Hydrogeologie, Gustav-Zeuner-Str. 12, Freiberg/Saichen 09596, Germany c.wolke@tu-freiberg.de |
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1430-483x |
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Passive mine water treatment as an alternative to active systems; 2428851; Passive Grubenwasserreinigung als Alternative zu aktiven Systemen. Germany 51; Geobase |
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CBU @ c.wolke @ 17530 |
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202 |
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Schoeman, J.J.; Steyn, A. |
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Investigation into alternative water treatment technologies for the treatment of underground mine water discharged by Grootvlei Proprietary Mines Ltd into the Blesbokspruit in South Africa |
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2001 |
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Desalination |
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133 |
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1 |
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13-30 |
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underground mine water treatment technologies reverse osmosis electrodialysis reversal ion-exchange water quality brine disposal treatment costs |
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Grootvlei Proprietary Mines Ltd is discharging between 80 and 100 Ml/d underground water into the Blesbokspruit. This water is pumped out of the mine to keep the underground water at such a level as to make mining possible. The water is of poor quality because it contains high TDS levels (2700-3800 mg/l) including high concentrations of iron, manganese, sulphate, calcium, magnesium, sodium and chloride. This water will adversely affect the water ecology in the Blesbokspruit, and it will significantly increase the TDS concentration of one of the major water resources if not treated prior to disposal into the stream. Therefore, alternative water desalination technologies were evaluated to estimate performance and the economics of the processes for treatment of the mine water. It was predicted that water of potable quality should be produced from the mine water with spiral reverse osmosis (SRO). It was demonstrated that it should be possible to reduce the TDS of the mine water (2000-2700-3400-4500 mg/l) to potable standards with SRO (85% water recovery). The capital costs (pretreatment and desalination) for a 80 Ml/d plant (worst-case water) were estimated at US$35M. Total operating costs were estimated at 88.1c/kl. Brine disposal costs were estimated at US$18M. Therefore, the total capital costs are estimated at US$53M. It was predicted that it should be possible to produce potable water from the worst-case feed water (80 Ml/d) with the EDR process. It was demonstrated that the TDS in the feed could be reduced from 4178 to 246 mg/l in the EDR product (65% water recovery). The capital costs (pretreatment plus desalination) to desalinate the worst-case feed water to potable quality with EDR is estimated at US$53.3M. The operational costs are estimated at 47.6 c/kl. Brine disposal costs were estimated at US$42M. Therefore, the total capital costs are estimated at US$95.3 M. It was predicted that it should be possible to produce potable water from the mine water with the GYP-CIX ion- exchange process. It was demonstrated that the feed TDS (2000- 4500 mg/l) could be reduced to less than 240 mg/l (54% water recovery for the worst-case water). The capital cost for an 80 Ml/d ion-exchange plant (worst-case water) was estimated at US$26.7M (no pretreatment). Operational costs were estimated at 60.4 c/kl. Brine disposal costs were estimated at US$55.1M. Therefore, the total desalination costs were estimated at US$81.8M. The capital outlay for a SRO plant will be significantly less than that for either an EDR or a GYP-CIX plant. The operating costs, however, of the RO plant are significantly higher than for the other two processes. Potable water sales, however, will bring more in for the RO process than for the other two processes because a higher water recovery can be obtained with RO. The operating costs minus the savings in water sales were estimated at 17.2; 6.7 and US$8.6M/y for the RO, EDR and GYP-CIX processes, respectively (worst case). Therefore, the operational costs of the EDR and GYP-CIX processes are the lowest if the sale of water is taken into consideration. This may favour the EDR and GYP-CIX processes for the desalination of the mine water. |
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0011-9164 |
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Feb. 10; Investigation into alternative water treatment technologies for the treatment of underground mine water discharged by Grootvlei Proprietary Mines Ltd into the Blesbokspruit in South Africa; Isi:000167087500002; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10184.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 17480 |
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23 |
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Author |
Swoboda-Colberg, N.; Colberg, P.; Smith, J.L. |
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Title |
Constructed vertical flow aerated wetlands |
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RPT |
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1994 |
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acid mine drainage; aeration; Butte Montana; carbonate rocks; case studies; clastic sediments; Clear Creek County Colorado; Colorado; construction; controls; fluid dynamics; gravel; heavy metals; Idaho Springs Colorado; limestone; Montana; pollution; rates; sedimentary rocks; sediments; Silver Bow County Montana; substrates; tailings; United States; waste water; water; water management; water quality; water treatment; wetlands 22, Environmental geology |
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In the report, wetland technology is described in which the main reactive layer is limestone gravel (rather than organic material) which is overlain by a fine gravel filter and soil. The three-year project included laboratory and field studies. Vertical aerated wetlands, simulated by columns, constructed in the field and in the laboratory, were operated during the project. The report presents a summary of results given in previous reports and summaries of results obtained using water from Butte, MT, and field studies at the Rockford Tunnel, near Idaho Springs, CO. |
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University of Wyoming, L.W.Y.U.S. performer |
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Constructed vertical flow aerated wetlands; 1998-003373; GeoRef; English; Final report. Grant DI-196561 National Technical Information Service, (703)605-6000, order number PB96-196811NEG, Springfield, VA, United States |
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CBU @ c.wolke @ 6506 |
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226 |
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