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| Author |
Goulet, R.R. |
| Title |
Changes in dissolved and total Fe and Mn in a young constructed wetland: Implications for retention performance |
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Journal Article |
| Year |
2001 |
Publication |
Ecological Engineering |
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| Volume |
17 |
Issue |
4 |
Pages |
373-384 |
| Keywords |
mine water treatment |
Abstract  |
Surface-flow wetlands are generally considered sinks for Fe and Mn but they may also export and affect the partitioning of these metals. This study was undertaken to evaluate the effect of a young constructed wetland on the retention and transformation of both dissolved and particulate Fe and Mn. Duplicate water samples were collected every three days at the inlet and outlet structures of the Monahan Wetland, Kanata, Ontario, from spring of 1997 to 1999. While on a yearly basis the wetland showed significant retention of che dissolved phase, the retention of total Fe and Mn was poor. There were strong seasonal differences in retention and, during the winter, the wetland was a source. The wetland transformed dissolved into particulate Fe and Mn from spring to fall whereas during the winter, dissolved Fe and Mn were released. Changes in pH, alkalinity and temperature could explain 11% and 40% of the outlet variation in the ratio of dissolved to total Fe and Mn respectively. Furthermore, from spring to late summer, planktonic algal biomass was negatively related to the ratio of dissolved to total Fe and Mn implying a role in Fe and Mn transformations in young wetlands where emergent and submerged vegetation have yet to dominate the system. (C) 2001 Elsevier Science B.V. All rights reserved. |
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Changes in dissolved and total Fe and Mn in a young constructed wetland: Implications for retention performance; Wos:000169881900004; Times Cited: 5; ISI Web of Science |
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CBU @ c.wolke @ 17050 |
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124 |
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Burt, R.A.; Caruccio, F.T. |
| Title |
The effect of limestone treatments on the rate of acid generation from pyritic mine gangue |
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Journal Article |
| Year |
1986 |
Publication |
Environmental geochemistry and health |
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8 |
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Pages |
8 |
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mine water treatment |
| Abstract |
Surface water enters the Haile Gold Mine, Lancaster County, South Carolina by means of a small stream and is ponded behind a dam and in an abandoned pit. This water is affected by acidic drainage. In spite of the large exposures of potentially acid producing pyritic rock, the flux of acid to the water is relatively low. Nevertheless, the resulting pH values of the mine water are low (around 3.5) due to negligible buffering capacity. In view of the observed low release of acidity, the potential for acid drainage abatement by limestone ameliorants appears feasible. This study investigated the effects of limestone treatment on acid generation rates of the Haile mine pyritic rocks through a series of leaching experiments. Below a critical alkalinity threshold value, solutions of dissolved limestone were found consistently to accelerate the rate of pyrite oxidation by varying degrees. The oxidation rates were further accelerated by admixing solid limestone with the pyritic rock. However, after a period of about a month, the pyrite oxidation rate of the admixed samples declined to a level lower than that of untreated pyrite. Leachates produced by the pyrite and limestone mixtures contained little if any iron. Further, in the mixtures, an alteration of the pyrite surface was apparent. The observed behaviour of the treated pyrite appears to be related to the immersion of the pyrite grains within a high alkalinity/high pH environment. The high pH increases the rate of oxidation of ferrous iron which results in a higher concentration of ferric iron at the pyrite surface. This, in turn, increases the rate of pyrite oxidation. Above a threshold alkalinity value, the precipitation of hydrous iron oxides at the pyrite surface eventually outpaces acid generation and coats the pyrite surface, retarding the rate of pyrite oxidation. |
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0269-4042 |
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Sept; The effect of limestone treatments on the rate of acid generation from pyritic mine gangue; London: Chapman & Hall; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/7021.pdf; Opac |
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CBU @ c.wolke @ 7021 |
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14 |
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Zou, L.H. |
| Title |
Sulfide precipitation flotation for treatment of acidic mine waste water |
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Journal Article |
| Year |
2000 |
Publication |
Transactions of Nonferrous Metals Society of China |
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10 |
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106-109 |
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mine water treatment |
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Sulfide precipitation flotation of copper-iron-bearing acidic waste water from a large copper mine and the stimulated waste water were studied. The pH of the waste water was 2.2, with 130 mg/L Cu2+ and 500 mg/L Fe3+ (Fe2+). Results show that, when Na2S was added as precipitating agent, sodium butylxanthate as collector and at pH 2.0, the removal of copper could be as high as 99.7 % and the residual copper decreased to 0.2 mg/L, however, almost no iron was removed. When the floated solution was neutralized to pH = 8.0, more than 98 % iron was precipitated and the residual iron was less than 10 mg/L. In experiment on actual mine effluents, after the use of precipitate flotation technology to recover copper and pH neutralization to precipitate iron, the treated waste water does meet the emission standards for sewage and valuable floating copper graded 37.12%. The chemical calculation and mechanism of solution were also presented. |
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Sulfide precipitation flotation for treatment of acidic mine waste water; Wos:000088249500025; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17086 |
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128 |
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Tsukamoto, T.K.; Miller, G.C. |
| Title |
Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage |
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Journal Article |
| Year |
1999 |
Publication |
Water Res. |
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33 |
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6 |
Pages |
1365-1370 |
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mine water treatment mining activity sulfate-reducing bacteria microbial activity acid mine drainage methanol passive treatment systems sulfate-reducing bacterium sp-nov |
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Sulfate reducing passive bioreactors are increasingly being used to remove metals and raise the pH of acidic waste streams from abandoned mines. These systems commonly use a variety of organic substrates (i.e. manure, wood chips) for sulfate reduction. The effectiveness of these systems decreases as easily accessible reducing equivalents are consumed in the substrate through microbial activity. Using column studies at room temperature (23-26 degrees C), we investigated the addition of lactate and methanol to a depleted manure substrate as a method to reactivate a bioreactor that had lost >95% of sulfate reduction activity. A preliminary experiment compared sulfate removal in gravity fed, flow through bioreactors in which similar masses of each substrate were added to the influent solution. Addition of 148 mg/l lactate resulted in a 69% reduction in sulfate concentration from 300 to 92 mg/l, while addition of 144 mg/l methanol resulted in an 88% reduction in sulfate concentration from 300 to 36 mg/l. Because methanol was found to be an effective sulfate reducing substrate, it was chosen for further experiments due to its inherent physical properties (cost, low freezing point and low viscosity liquid) that make it a superior substrate for remote, high elevation sites where freezing temperatures would hamper the use of aqueous solutions. In these column studies, water containing sulfate and ferrous iron was gravity-fed through the bioreactor columns, along with predetermined methanol concentrations containing reducing equivalents to remove 54% of the sulfate. Following an acclimation period for the columns, sulfate concentrations were reduced from of 900 mg/l in the influent to 454 mg/l in the effluent, that reflects a 93% efficiency of electrons from the donor to the terminal electron acceptor. Iron concentrations were reduced from 100 to 2 mg/l and the pH increased nearly 2 units. (C) 1999 Elsevier Science Ltd. |
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0043-1354 |
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Apr; Methanol as a Carbon Source for Microbiological Treatment of Acid Mine Drainage; Isi:000079485400004; file:///C:/Dokumente%20und%20Einstellungen/Stefan/Eigene%20Dateien/Artikel/10197.pdf; AMD ISI | Wolkersdorfer |
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CBU @ c.wolke @ 10197 |
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50 |
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Naugle, W.K. |
| Title |
Remediation of the Eagle Mine superfund site: a biological success story |
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Journal Article |
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2003 |
Publication |
Tailings and Mine Waste '03 |
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481-485 |
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mine water treatment |
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Remediation of the Eagle Mine Superfund Site began in 1988. Remedial action included: bulk-heading adits, flooding mine workings; constructing diversion ditches around waste rock; consolidating mine wastes in an on-site tailings pile; capping the tailings pile with a multi-layer, engineered cap; and revegetating disturbed areas with native plants. Flooding the mine workings resulted in unacceptable seepage into the Eagle River in late 1989. A water treatment plant was constructed to collect mine seepage and groundwater at the main tailings pile. In October 2001, construction of the remedy was declared “complete” and the site is now in the operation, maintenance and monitoring phase. A strong downward trend in zinc and cadmium concentrations in the Eagle River has occurred and, trout and macroinvertebrate populations have increased. Biological data are being used to establish water quality standards for the Eagle River. |
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Remediation of the Eagle Mine superfund site: a biological success story; Isip:000186710100058; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 17020 |
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157 |
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