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Author |
Sasaki, K. |
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Title |
Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs |
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Journal Article |
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2006 |
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Mater. Trans. |
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47 |
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10 |
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2457-2461 |
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mine water treatment |
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A Mn-oxidizing fungus was isolated from a constructed wetland of Hokkaido (Japan), which is receiving the Mn-impacted drainage, and genetically and morphologically identified as Paraconiothyrium sp.-like strain. The optimum pHs were 6.45-6.64, where is more acidic than those of previously reported Mn-oxidizing fungi. Too much nutrient inhibited fungal Mn-oxidation, and too little nutrient also delayed Mn oxidation even at optimum pH. In order to achieve the oxidation of high concentrations of Mn like mine drainage containing several hundreds g-m(-3) of Mn, it is important to find the best mix ratio among the initial Mn concentrations, inocolumn size and nutrient concentration. The strain has still Mn-tolerance with more than 380 g-m(-3) of Mn, but high Mn(II) oxidation was limited by pH control and supplied nutrient amounts. The biogenic Mn deposit was poorly crystallized birnessite. The strain is an unique Mn-oxidizing fungus having a high Mn tolerance and weakly acidic tolerance, since there has been no record about the property of the strain. There is a potentiality to apply the strain to the environmental bioremediation. |
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Immobilization of Mn(II) ions by a Mn-oxidizing fungus – Paraconiothyrium sp.-like strain at neutral pHs; Wos:000242429300002; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16940 |
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103 |
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Morfitt, B.; Brewer, W.; Frobel, R. |
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Title |
Cleaning up the Summitville Mine Superfund Site |
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Journal Article |
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1998 |
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Geotechnical Fabrics Report |
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16 |
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5 |
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38-41 |
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Geomembran Verbundstoff Abdichten Erdaufschüttung Erosion Schutz Bentonit Bergwerk Netz |
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A multi-layered geosynthetic system that includes geosynthetic-clay liners (GCL) and a geonet-composite drain (GNGC) is being used to cap and stabilize a 178000 m(exp 2) heap-leach pad at the Summitville Mine Superfund Site in Colorado. Selected were materials on the basis of design requirements for permeability, strength, extreme site conditions and cost. The Summitville cleanup called for a heap-leach pad cap to provide a barrier that would prevent precipitation from infiltrating the pad material. This long-term remediation prevents the pile from becoming saturated and allowing water to overflow the downslope dike, which could cause instability to dike and pond. Three geosynthetic alternatives were proposed. The contractor, that was awarded the heap leach pad, phase 2 contract, decided for a geosynthetic clay liner cap placed directly on the redesigned slopes. Bentofix NW-8 was used as GCL and TexNet TN was selected as the geocomposite drain. Conformance testing, subgrade preparation review, geosynthetic installation/repair inspection and review of cover material placement, performed by independent construction-quality assurance, showed that GCL is a well-suited cap material for heap leach pads, where high wind, cold temperatures rain and high altitude hinder construction. The robust geosynthetic allowed on-site coarse material to be used in the subgrade and cover layer, which saved the cost of importing more expensive bedding material. |
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US Bureau of Reclamation, Denver, US; Advanced Terra Testing, Lakewood, US; R K Frobel & Associates, Lakewood, US |
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0882-4983 |
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Cleaning up the Summitville Mine Superfund Site; 16974, BERG , 16.09.98; Words: 376; T9808 0249 178; 4 Seiten, 4 Bilder, 1 Tabelle 3TMP *intelligente Textilien, technische Textilien*; BERG, Copyright FIZ Technik e.V.; EN Englisch |
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CBU @ c.wolke @ 17599 |
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294 |
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Jarvis, A.P. |
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Effective remediation of grossly polluted acidic, and metal-rich, spoil heap drainage using a novel, low-cost, permeable reactive barrier in Northumberland, UK |
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Journal Article |
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2006 |
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Environmental Pollution |
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143 |
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2 |
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261-268 |
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mine water treatment |
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A permeable reactive barrier (PRB) for remediation of coal spoil heap drainage in Northumberland, UK, is described. The drainage has typical chemical characteristics of pH < 4, [acidity] > 1400 mg/L as CaCO3, [Fe] > 300 mg/L, [Mn] > 165 mg/L, [Al] > 100 mg/L and IS041 > 6500 mg/L. During 2 years of operation the PRB has typically removed 50% of the iron and 40% of the sulphate from this subsurface spoil drainage. Bacterial sulphate reduction appears to be a key process of this remediation. Treatment of the effluent from the PRB results in further attenuation; overall reductions in iron and sulphate concentrations are 95% and 67% respectively, and acidity concentration is reduced by an order of magnitude. The mechanisms of attenuation of these, and other, contaminants in the drainage are discussed. Future research and operational objectives for this novel, low-cost, treatment system are also outlined. (c) 2005 Elsevier Ltd. All rights reserved. |
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Effective remediation of grossly polluted acidic, and metal-rich, spoil heap drainage using a novel, low-cost, permeable reactive barrier in Northumberland, UK; Wos:000238277500010; Times Cited: 0; ISI Web of Science |
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CBU @ c.wolke @ 16928 |
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109 |
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Herbert, R.B., Jr.; Benner, S.G.; Blowes, D.W. |
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Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation |
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1998 |
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Groundwater Quality: Remediation and Protection |
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451-457 |
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acid mine drainage Canada chemical analysis contaminant plumes Eastern Canada ground water hydraulic conductivity hydrolysis Nickel Rim Mine Ontario pH pollution porosity pyrrhotite remediation sample preparation Sudbury Basin sulfides sulfur tailings water pollution 22, Environmental geology |
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A permeable reactive barrier was installed in August 1995 at the Nickel Rim Mine near Sudbury, Ontario, Canada, for the passive remediation of groundwater contaminated with acid mine drainage. The reactive component of the barrier consists of a mixture of municipal and leaf compost and wood chips: the organic material promotes bacterially-mediated sulphate reduction. Hydrogen sulphide, a product of sulphate reduction, may then complex with aqueous ferrous iron and precipitate as iron sulphide. This study presents the solid phase sulphur chemistry of the reactive wall after two years of operation, and discusses the formation and accumulation of iron sulphide minerals in the reactive material. The results from the solid-phase chemical analysis of core samples indicate that there is an accumulation of reduced inorganic sulphur in the reactive wall, with levels reaching 190 mu mol g (super -1) (dry weight) by July 1997. |
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IAHS-AISH Publication, vol.250 |
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Herbert, M.; Kovar, K. |
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1901502554 |
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Reactive barrier treatment of groundwater contaminated by acid mine drainage; sulphur accumulation and sulphide formation; GeoRef; English; 1999-065115; GQ 98 conference, Tubingen, Federal Republic of Germany, Sept. 21-24, 1998 References: 15; illus. |
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CBU @ c.wolke @ 16621 |
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65 |
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Author |
Benner, S.G. |
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Title |
Geochemistry of a permeable reactive barrier for metals and acid mine drainage |
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Journal Article |
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1999 |
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Environmental Science & Technology |
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33 |
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16 |
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2793-2799 |
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mine water treatment |
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A permeable reactive barrier, designed to remove metals and generate alkalinity by promoting sulfate reduction and metal sulfide precipitation, was installed in August 1995 into an aquifer containing effluent from mine tailings. Passage of groundwater through the barrier results in striking improvement in water quality. Dramatic changes in concentrations of SO4 (decrease of 2000-3000 mg/L), Fe (decrease of 270-1300 mg/L), trace metals (e.g., Ni decreases 30 mg/L), and alkalinity (increase of (800-2700 mg/L) are observed. Populations of sulfate reducing bacteria are 10 000 times greater, and bacterial activity, as measured by dehydrogenase activity, is 10 rimes higher within the barrier compared to the up-gradient aquifer. Dissolved sulfide concentrations increase by 0.2-120 mg/ L, and the isotope S-34 is enriched relative to S-32 in the dissolved phase SO42- within the barrier. Water chemistry, coupled with geochemical speciation modeling, indicates the pore water in the barrier becomes supersaturated with respect to amorphous Fe sulfide. Solid phase analysis of the reactive mixture indicates the accumulation of Fe monosulfide precipitates. Shifts in the saturation states of carbonate, sulfate, and sulfide minerals and most of the observed changes in water chemistry in the barrier and down-gradient aquifer can be attributed, either directly or indirectly, to bacterially mediated sulfate reduction. |
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Geochemistry of a permeable reactive barrier for metals and acid mine drainage; Wos:000082074500017; Times Cited: 57; ISI Web of Science |
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CBU @ c.wolke @ 17115 |
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132 |
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