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LaPointe, F., Fytas, K., & McConchie, D. (2005). Using permeable reactive barriers for the treatment of acid rock drainage. International journal of surface mining, reclamation and environment, 19(1), 57–65.
Abstract: Acid mine drainage (AMD) is the most serious environmental problem facing the Canadian mineral industry today. It results from oxidation of sulphide minerals (e.g. pyrite or pyrrhotite) contained in mine waste or mine tailings and is characterized by acid effluents rich in heavy metals that are released into the environment. A new acid remediation technology is presented, by which metallurgical residues from the aluminium extraction industry are used to construct permeable reactive barriers (PRBs) to treat acid mine effluents. This technology is very promising for treating acid mine effluents in order to decrease their harmful environmental effects
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Niyogi, D. K., McKnight, D. M., Lewis, W. M., Jr., & Kimball, B. A. (1999). Experimental diversion of acid mine drainage and the effects on a headwater stream. Water-Resources Investigations Report, Wri 99-4018-A, 123–130.
Abstract: An experimental diversion of acid mine drainage was set up near an abandoned mine in Saint Kevin Gulch, Colorado. A mass-balance approach using natural tracers was used to estimate flows into Saint Kevin Gulch. The diversion system collected about 85 percent of the mine water during its first year of operation (1994). In the first 2 months after the diversion, benthic algae in an experimental reach (stream reach around which mine drainage was diverted) became more abundant as water quality improved (increase in pH, decrease in zinc concentrations) and substrate quality changed (decrease in rate of metal hydroxide deposition). Further increases in pH to levels above 4.6, however, led to lower algal biomass in subsequent years (1995-97). An increase in deposition of aluminum precipitates at pH greater than 4.6 may account for the suppression of algal biomass. The pH in the experimental reach was lower in 1998 and algal biomass increased. Mine drainage presents a complex, interactive set of stresses on stream ecosystems. These interactions need to be considered in remediation goals and plans.
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Kepler, D. A., & Mc Cleary, E. C. (1994). Successive Alkalinity-Producing Systems (SAPS) for the Treatment of Acid Mine Drainage. Proceedings, International Land Reclamation and Mine Drainage Conference, 1, 195–204.
Abstract: Constructed wetland treatment system effectiveness has been limited by the alkalinity-producing, or acidity-neutralizing, capabilities of systems. Anoxic limestone drains (ALD's) have allowed for the treatment of approximately 300 mg/L net acidic mine drainage, but current design guidance precludes using successive ALD's to generate alkalinity in excess of 300 mg/L because of concerns with dissolved oxygen. “Compost” wetlands designed to promote bacterially mediated sulfate reduction are suggested as a means of generating alkalinity required in excess of that produced by ALD's. Compost wetlands create two basic needs of sulfate reducing bacteria; anoxic conditions resulting from the inherent oxygen demand of the organic substrate, and quasi-circumneutral pH values resulting from the dissolution of the carbonate fraction of the compost. However, sulfate reduction treatment area needs are generally in excess of area availability and/or cost effectiveness. Second generation alkalinity-producing systems demonstrate that a combination of existing treatment mechanisms has the potential to overcome current design concerns and effectively treat acidic waters ad infinitum. Successive alkalinity-producing systems (SAPS) combine ALD technology with sulfate reduction mechanisms. SAPS promote vertical flow through rich organic wetland substrates into limestone beds beneath the organic compost, discharging the pore waters. SAPS allow for conservative wetland treatment sizing calculations to be made as a rate function based on pH and alkalinity values and associated contaminant loadings. SAPS potentially decrease treatment area requirements and have the further potential to generate alkalinity in excess of acidity regardless od acidity concentrations.
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Benzaazoua, M., & Bussiere, B. (1999). Desulphurization of tailings with low neutralizing potential; kinetic study and flotation modeling. In D. Goldsack, N. Belzile, P. Yearwood, & G. Hall (Eds.), Sudbury '99; Mining and the environment II; conference proceedings.
Abstract: Environmental desulphurization is an attractive alternative for acid generating tailings management as demonstrated during the last few years. In fact, such process placed at the end of the primary treatment circuit allows to reduce greatly the amount of problematic tailings by concentrating the sulphidic fraction. Moreover, the desulphurized tailings (non-acid generating) have the geotechnical and environmental properties for being used as fine material in a cover with capillary barrier effects. To produce desulphurized tailings, non selective froth flotation is the most adapted method as shown in many previous works. Desulphurization level is fixed by tailings sulphur content (or sulphide content) and neutralization potential NP. The final residue should have enough NP to compensate for his acid generating potential AP. In this paper, the authors present the results of laboratory tests conducted in Denver cells for studying the sulphide flotation kinetics of four mine tailings which are characterized by a weak neutralization potential (under 37 kg CaCO (sub 3) /t). Tailings 1, 2, 3 and 4 contain respectively 5.27, 10, 4.25 and 16.9 sulphur Wt. %. Tailings 1 and 2 are cyanide free and are well floated at pH around 11 by using amyl xanthate as collector. Collector dosage was optimized for these tailings and the results show that Tailing 2 need more collector. However, Tailings 3 and 4, which come from a gold cyanidation process, could not provide good sulphide recovery with xanthate collector because of the pyrite depression. To overcome this problem, amine acetate was used successfully but induces important entrainment. The consumption of this collector was also optimized. The results of kinetic tests and collector dosage were combined and modeled to establish relationships which allow to estimate the desulphurization performances.
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Arnekleiv, J. V., & Storset, L. (1995). Downstream effects of mine drainage on benthos and fish in a Norwegian river; a comparison of the situation before and after river rehabilitation. Heavy metal aspects of mining pollution and its remediation, 52, 35–43.
Abstract: Parts of the Norwegian river Gaula are strongly polluted from former mining activity in the area. In the most polluted parts of the river the concentration levels of Cu and Zn in 1986-1987 were up to 155 mu g l (super -1) and 186 mu g l (super -1) , respectively. In 1989 the spoil heaps in the mining area were covered with protective layers of moss-covered plastic. In 1991-1992 the concentration levels of Cu and Zn had decreased by 75% and 65%, respectively. Animal life in the polluted area seemed to be strongly affected by the trace metals in 1986-1987. The 1991-1992 results showed a marked increase in the number of species and in the number of individuals of each species of Ephemeroptera and Plecoptera, compared with the results from 1986-87. Good correlations were found between the concentrations of Cu in the water and both the number of species and the number of individuals of Ephemeroptera and Plecoptera. Analysis of the species Baetis rhodani, Diura nanseni and Rhyacophila nubila showed an average total dry weight content of Cu up to 264 mu g g (super -1) , of Zn up to 1930 mu g g (super -1) and of Cd up to 16 mu g g (super -1) . The contents of the three trace metals were significantly different from one species to another and in part between the stations for each species. In 1987 trout died after an exposure of one to two days on three test sites in the river, whereas in 1991-1992 40-75% of the trout survived an exposure period of several weeks at two of the sites. Electrofishing in 1991-1992 indicated recolonization of trout in the lower parts of the former affected and uninhabitable area.
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