Abstract: Pollution by mine drainage is a major problem in many parts of the world. The most frequent contaminants are Fe, Mn, Al and SO (sub 4) with locally important contributions by other metals/metalloids including (in order of decreasing frequency) Zn, Cu, As, Ni, Cd and Pb. Remedial options for such polluted drainage include monitored natural attenuation, physical intervention to minimise pollutant release, and active and passive water treatment technologies. Based on the assessment of the key hydrological and geochemical attributes of mine water discharges, a rational decision-making framework has now been developed for deciding which (or which combinations) of these options to implement in a specific case. Five case studies illustrate the application of this decision-making process in practice: Wheal Jane and South Crofty (Cornwall), Quaking Houses (Co Durham), Hlobane Colliery (South Africa) and Milluni Tin Mine (Bolivia). In many cases, particularly where the socio-environmental stakes are particularly high, the economic, political and ecological issues will prove even more challenging than the technical difficulties involved in implementing remedial interventions which will be robust in the long term. Hence truly “holistic” mine water remediation is a multi-dimensional business, involving teamwork by a range of geoscientific, hydroecological and socio-economic specialists.

Abstract: The reclamation of former mining sites is a major challenge in many parts of the world. In relation to the restoration of spoil heaps (mine waste rock piles) and similar bodies of opencast backfill, key challenges include (i) the establishment of stable slopes and minimization of other geotechnical hazards (ii) developing and maintaining a healthy vegetative cover (iii) managing the hydrological behaviour of the restored ground. Significant advances have been made over the past four decades in relation to all four of these objectives. One of the most recalcitrant problems is the ongoing generation and release of acidic leachates, which typically emerge at the toes of (otherwise restored) spoil heaps in the form of springs and seepage areas. Such features are testament to the presence of a “perched” groundwater circulation system within the spoil, and their acidity reflects the continued penetration of oxygen to zones within the heaps which contain reactive pyrite (and other iron sulphide minerals). Two obvious strategies for dealing with this problem are disruption of the perched groundwater system and/or exclusion of oxygen entry. These strategies are now being pursued with considerable success where spoil is being reclaimed for the first time, by the installation of two types of physical barrier (dry covers and water covers). However, where a spoil heap has already been revegetated some decades ago, the destruction of an established sward or woodland in order to retro-fit a dry cover or water cover is rarely an attractive option for dealing with the “secondary dereliction” represented by ongoing toe seepages of acidic leachates. More attractive by far are passive treatment techniques, in which the polluted water is forced to flow through reactive media which serve to neutralize its acidity and remove toxic metals from solution. A brief historical review of the development of such systems reveals a general progression from using limestone as the key neutralizing agent, through a combined use of limestone and compost, to systems in which almost all of the neutralization is achieved by means of bacterial sulphate reduction in the saturated compost media of subsurface-flow bioreactors. In almost all cases, these passive treatment systems include an aerobic, surface flow wetland as the final “polishing” step in the treatment process. Such wetlands combine treatment functions (efficient removal of metals from the now-neutralized waters down to low residual concentrations, and re-oxygenating the water prior to discharge to receiving watercourses) with amenity value (attractive areas for recreational walking, bird-watching etc) and ecological value.